Andrea Zappettini

Progress in the Development of CdTe and CdZnTe Semiconductor Radiation Detectors for Astrophysical and Medical Applications

Over the last decade, cadmium telluride (CdTe) and cadmium zinc telluride (CdZnTe) wide band gap semiconductors have attracted increasing interest as X-ray and gamma ray detectors. Among the traditional high performance spectrometers based on silicon (Si) and germanium (Ge), CdTe and CdZnTe detectors show high detection efficiency and good room temperature performance and are well suited for the development of compact and reliable detection systems. In this paper, we review the current status of research in the development of CdTe and CdZnTe detectors by a comprehensive survey on the material properties, the device characteristics, the different techniques for improving the overall detector performance and some major applications. Astrophysical and medical applications are discussed, pointing out the ongoing Italian research activities on the development of these detectors.

Aldehyde detection by ZnO tetrapod-based gas sensors

Zinc oxide (ZnO) tetrapods have been synthesized and prototypal gas sensors for volatile organic compounds (VOCs) have been realized with this sensing nanomaterial. Sensor characterization has been focused on aldehydes, such as acetaldehyde (or ethanal) and propionaldehyde (or propanal), whose detection at ppb levels is extremely important for monitoring environmental, domestic and food pollution, as well as for some sickness diagnosis and other medical applications. The response of gas sensor prototypes has been measured as a function of concentration, temperature, relative humidity and time. Good response values at ppb levels and some peculiar behaviours have been pointed out.

Study of Surface Treatment Effects on the Metal-CdZnTe Interface

The quality of a CdZnTe-based X-ray detector is highly related to the interface between semiconductor and metal contact. One of the factors that increase leakage currents in CdZnTe based X-ray detectors is the presence of a conductive surface layer. In this paper the result of the passivation of the CdZnTe surface by means of an aqueous solution of NH4F/H2O2 is studied by optical ellipsometry and by the current-voltage characteristics of gold contacts deposited on the oxidized surface. Collected data show that leakage currents can be reduced and contact stability improved by the combined use of the passivation layer and a guard ring.

Unpredicted Nucleation of Extended Zinc Blende Phases in Wurtzite ZnO Nanotetrapod Arms

Tailoring the structural and electronic properties of 3D nanostructures via bottom-up techniques would pave the way for novel low-cost applications. One of such possibilities is offered by ZnO branched nanostructures like tetrapods, that have recently attracted attention for nanodevice applications from nanoelectronics to drug delivery. The conventional picture is that ZnO arms are thermodynamically stable only in the wurtzite phase. Here, we provide the first experimental evidence of unpredicted extended zinc blend phases (50-60 nm long) embedded in the arms of ZnO wurtzite tetrapods. In particular, decisive evidence is obtained from the one-to-one correlation between high lateral resolution cathodoluminescence spectroscopy, monochromatic contrast maps, and atomic resolution transmission electron microscopy images of ZnO single TPs. This observation is not specific to ZnO and can have a general validity for the understanding of the nucleation mechanisms in semiconducting 3D nanostructures for device applications.

A single cotton fiber organic electrochemical transistor for liquid electrolyte saline sensing

A single natural cotton fiber has been functionalized with poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) conductive polymer by a simple soaking process and used as a channel of an organic electrochemical transistor (OECT), directly interfaced with a liquid electrolyte in contact with an Ag wire gate. The device shows a stable and reproducible current modulation and has been demonstrated to be very effective for electrochemical sensing of NaCl concentration in water. The single wire cotton fiber OECT results to be a simple and low cost device, which is very attractive for wearable electronics in fitness and healthcare.

Growth and Characterization of CZT Crystals by the Vertical Bridgman Method for X-Ray Detector Applications

CdZnTe crystals were grown by the vertical Bridgman method in closed quartz ampoules. The crystalline quality and the impurity content of these crystals were studied. Several X-ray detectors were cut out of these crystals. The resistivity, emission spectra, μτ product, and spectroscopic characteristics of these detectors were extensively measured and compared with the characteristics of detectors obtained from CdZnTe crystals grown by the boron oxide encapsulated vertical Bridgman technique. The detectors prepared from crystals grown without boron oxide show good μτ value, spectroscopic resolution, and higher reproducibility. The influence of growth method on impurity content and on detector response was discussed.

Extended functionality of ZnO nanotetrapods by solution-based coupling with CdS nanoparticles

Coupled nanostructures with “spotted” and “core–shell” morphologies have been obtained by a controlled heterogeneous nucleation of cadmium sulfide nanoparticles (CdS-NPs) onto the surface of zinc oxide nanotetrapods (ZnO-TPs). This result has been obtained by means of a modified chemical bath deposition reaction, without the need of any surfactant and surface passivating agents. The coupled nanostructure has been demonstrated to form an active p–n type-II heterojunction, clearly affecting the functional properties of ZnO nanostructures, as in gas-sensing or photocatalysis applications.

Characterization of Bulk and Surface Transport Mechanisms by Means of the Photocurrent Technique

The transport properties of ternary alloys, as CdZnTe, affect heavily the features required in X and Gamma spectroscopic detectors. The density and the nature of bulk defects and the lacking quality of contacts, characterized by high recombination center densities near the surface, damage strongly the quality of these materials. The photocurrent technique is a powerful tool to study the bulk properties and to investigate contact and surface quality. From steady-state photocurrent spectra information about the bulk trap defects and about the kinds of surface states far and near the contacts, has been obtained. By varying the bias at fixed wavelength, instead, it can be calculated the transport parameters like the product mobility-lifetime ¿¿ and the ratio s/¿, this last one related to the surface underneath the metal contacts. This paper gives some contribution in the interpretation of high energy region of the spectra. The authors correlate the response of samples illuminated with energies above the band gap to the surface states and show the different effects of this states on the electron and the hole transport case. Moreover in this work the authors compare the photocurrent measurement with the X ray spectroscopy and also discuss several phenomena like the shape difference between the spectra taken at different photon flux and bias polarities. Also the band edge shift and the modification of S/¿ parameter observed on varying the bias polarity have been discussed giving new a possible interpretations.

The LAUE project and its main results

We will describe the LAUE project, supported by the Italian Space Agency, whose aim is to demonstrate the capability to build a focusing optics in the hard X-/soft gamma-ray domain (80{600 keV). To show the lens feasibility, the assembling of a Laue lens petal prototype with 20 m focal length is ongoing. Indeed, a feasibility study, within the LAUE project, has demonstrated that a Laue lens made of petals is feasible. Our goal is a lens in the 80-600 keV energy band. In addition to a detailed description of the new LARIX facility, in which the lens is being assembled, we will report the results of the project obtained so far.

Charge transport properties in CdZnTe detectors grown by the vertical Bridgman technique

Great efforts are being presently devoted to the development of CdTe and CdZnTe detectors for a large variety of applications, such as medical, industrial, and space research. We present the spectroscopic properties of some CZT crystals grown by the standard vertical Bridgman method and by the boron oxide encapsulated vertical Bridgman method, which has been recently implemented at IMEM-CNR (Parma, Italy). By this technique the crystal is grown in an open quartz crucible fully encapsulated by a thin layer of liquid boron oxide. This method prevents contact between the crystal and the crucible thereby allowing larger single grains with a lower dislocation density to be obtained. Several mono-electrode detectors were realized each with two planar gold contacts. The samples are characterized by an active area of about 7 mm × 7 mm and thicknesses ranging from 1 to 2 mm. The charge transport properties of the detectors have been studied by mobility-lifetime (μt) product measurements, carried out at the European Synchrotron Radiation Facility (Grenoble) in the PTF configuration, where the impinging beam direction is orthogonal to the collecting electric field. We have performed several fine scans between the electrodes with a beam spot of 10 μm × 10 μm at various energies from 60 keV to 400 keV. In this work we present the test results in terms of μt product of both charge carriers.