Andreas Dechant

All-optical nanomechanical heat engine.

We propose and theoretically investigate a nanomechanical heat engine. We show how a levitated nanoparticle in an optical trap inside a cavity can be used to realize a Stirling cycle in the underdamped regime. The all-optical approach enables fast and flexible control of all thermodynamical parameters and the efficient optimization of the performance of the engine. We develop a systematic optimization procedure to determine optimal driving protocols. Further, we perform numerical simulations with realistic parameters and evaluate the maximum power and the corresponding efficiency.

Fluctuations of Time Averages for Langevin Dynamics in a Binding Force Field

We derive a simple formula for the fluctuations of the time average x(t) around the thermal mean (eq) for overdamped brownian motion in a binding potential U(x). Using a backward Fokker-Planck equation, introduced by Szabo, Schulten, and Schulten in the context of reaction kinetics, we show that for ergodic processes these finite measurement time fluctuations are determined by the Boltzmann measure. For the widely applicable logarithmic potential, ergodicity is broken. We quantify the large nonergodic fluctuations and show how they are related to a superaging correlation function.

Superaging correlation function and ergodicity breaking for Brownian motion in logarithmic potentials.

We consider an overdamped Brownian particle moving in a confining asymptotically logarithmic potential, which supports a normalized Boltzmann equilibrium density. We derive analytical expressions for the two-time correlation function and the fluctuations of the time-averaged position of the particle for large but finite times. We characterize the occurrence of aging and nonergodic behavior as a function of the depth of the potential, and we support our predictions with extensive Langevin simulations. While the Boltzmann measure is used to obtain stationary correlation functions, we show how the non-normalizable infinite covariant density is related to the superaging behavior.

Wiener-Khinchin Theorem for Nonstationary Scale-Invariant Processes.

We derive a generalization of the Wiener-Khinchin theorem for nonstationary processes by introducing a time-dependent spectral density that is related to the time-averaged power. We use the nonstationary theorem to investigate aging processes with asymptotically scale-invariant correlation functions. As an application, we analyze the power spectrum of three paradigmatic models of anomalous diffusion: scaled Brownian motion, fractional Brownian motion, and diffusion in a logarithmic potential. We moreover elucidate how the nonstationarity of generic subdiffusive processes is related to the infrared catastrophe of 1/f noise.

Anomalous spatial diffusion and multifractality in optical lattices.

The transport of cold atoms in shallow optical lattices is characterized by slow, nonstationary momentum relaxation. We develop a projector operator method able to derive, in this case, a generalized Smoluchowski equation for the position variable. We show that this explicitly non-markovian equation can be written as a systematic expansion involving higher-order derivatives. We use the latter to compute arbitrary moments of the spatial distribution and analyze their multifractal properties.

Nonergodic diffusion of single atoms in a periodic potential

Drawing microscopic information out of the diffusive dynamics of complex processes often requires an assumption of ergodicity. Precision experiments on a single atom in a periodic potential suggest that this may be too simplistic in many cases. Diffusion can be used to infer the microscopic features of a system from the observation of its macroscopic dynamics. Brownian motion accurately describes many diffusive systems, but non-Brownian and nonergodic features are often observed on short timescales. Here, we trap a single ultracold caesium atom in a periodic potential and measure its diffusion1,2,3. We engineer the particle–environment interaction to fully control motion over a broad range of diffusion constants and timescales. We use a powerful stroboscopic imaging method to detect single-particle trajectories and analyse both non-equilibrium diffusion properties and the approach to ergodicity4. Whereas the variance and two-time correlation function exhibit apparent Brownian motion at all times, higher-order correlations reveal strong non-Brownian behaviour. We additionally observe the slow convergence of the exponential displacement distribution to a Gaussian and—unexpectedly—a much slower approach to ergodicity5, in perfect agreement with an analytical continuous-time random-walk model6,7,8. Our experimental system offers an ideal testbed for the detailed investigation of complex diffusion processes.

Underdamped stochastic heat engine at maximum efficiency

We investigate the performance of an underdamped stochastic heat engine for a time-dependent harmonic oscillator. We analytically determine the optimal protocol that maximizes the efficiency at fixed power. The maximum efficiency reduces to the Curzon-Ahlborn formula at maximum power and the Carnot formula at zero power. We further establish that the efficiency at maximum power is universally given by the Curzon-Ahlborn efficiency in the weakly damped regime. Finally, we show that even small deviations from operation at maximum power may result in a significantly increased efficiency.

Heavy-tailed phase-space distributions beyond Boltzmann-Gibbs: Confined laser-cooled atoms in a nonthermal state.

The Boltzmann-Gibbs density, a central result of equilibrium statistical mechanics, relates the energy of a system in contact with a thermal bath to its equilibrium statistics. This relation is lost for non-thermal systems such as cold atoms in optical lattices, where the heat bath is replaced by the laser beams of the lattice. We investigate in detail the stationary phase-space probability for Sisyphus cooling under harmonic confinement. In particular, we elucidate whether the total energy of the system still describes its stationary state statistics. We find that this is true for the center part of the phase-space density for deep lattices, where the Boltzmann-Gibbs density provides an approximate description. The relation between energy and statistics also persists for strong confinement and in the limit of high energies, where the system becomes underdamped. However, the phase-space density now exhibits heavy power-law tails. In all three cases we find expressions for the leading order phase-space density and corrections which break the equivalence of probability and energy and violate energy equipartition. The non-equilibrium nature of the steady state is confounded by explicit violations of detailed balance. We complement these analytical results with numerical simulations to map out the intricate structure of the phase-space density.The Boltzmann-Gibbs density, a central result of equilibrium statistical mechanics, relates the energy of a system in contact with a thermal bath to its equilibrium statistics. This relation is lost for nonthermal systems such as cold atoms in optical lattices, where the heat bath is replaced with the laser beams of the lattice. We investigate in detail the stationary phase-space probability for Sisyphus cooling under harmonic confinement. In particular, we elucidate whether the total energy of the system still describes its stationary state statistics. We find that this is true for the center part of the phase-space density for deep lattices, where the Boltzmann-Gibbs density provides an approximate description. The relation between energy and statistics also persists for strong confinement and in the limit of high energies, where the system becomes underdamped. However, the phase-space density now exhibits heavy power-law tails. In all three cases we find expressions for the leading-order phase-space density and corrections which break the equivalence of probability and energy and violate energy equipartition. The nonequilibrium nature of the steady state is corroborated by explicit violations of detailed balance. We complement these analytical results with numerical simulations to map out the intricate structure of the phase-space density.

Current fluctuations and transport efficiency for general Langevin systems

We derive a universal bound on generalized currents in Langevin systems in terms of the mean-square fluctuations of the current and the total entropy production. This bound generalizes a relation previously found by Barato et al. to arbitrary times and transient states. Using the bound, we define a new efficiency for stochastic transport, which measures how close a given system comes to saturating the bound. The existence of such a bounded efficiency implies that stochastic transport is unavoidably accompanied by a fluctuations and dissipation, which cannot be reduced arbitrarily. We apply the definition of transport efficiency to steady state particle transport and heat engines and show that the transport efficiency may approach unity at finite current, in contrast to the thermodynamic efficiency. Finally, we derive a bound on purely diffusive transport in terms of the Shannon entropy.

Deviations from Boltzmann-Gibbs Statistics in Confined Optical Lattices.

We investigate the semiclassical phase-space probability distribution P(x,p) of cold atoms in a Sisyphus cooling lattice with an additional harmonic confinement. We pose the question of whether this nonequilibrium steady state satisfies the equivalence of energy and probability. This equivalence is the foundation of Boltzmann-Gibbs and generalized thermostatic statistics, and a prerequisite for the description in terms of a temperature. At large energies, P(x,p) depends only on the Hamiltonian H(x,p) and the answer to the question is yes. In distinction to the Boltzmann-Gibbs state, the large-energy tails are power laws P(x,p)∝H(x,p)(-1/D), where D is related to the depth of the optical lattice. At intermediate energies, however, P(x,p) cannot be expressed as a function of the Hamiltonian and the equivalence between energy and probability breaks down. As a consequence the average potential and kinetic energy differ and no well-defined temperature can be assigned. The Boltzmann-Gibbs state is regained only in the limit of deep optical lattices. For strong confinement relative to the damping, we derive an explicit expression for the stationary phase-space distribution.