Anna J. Mukherjee

Direct chemical evidence for widespread dairying in prehistoric Britain

Domesticated animals formed an important element of farming practices in prehistoric Britain, a fact revealed through the quantity and variety of animal bone typically found at archaeological sites. However, it is not known whether the ruminant animals were raised purely for their tissues (e.g., meat) or alternatively were exploited principally for their milk. Absorbed organic residues from pottery from 14 British prehistoric sites were investigated for evidence of the processing of dairy products. Our ability to detect dairy fats rests on the observation that the δ13C values of the C18:0 fatty acids in ruminant dairy fats are ≈2.3‰ lower than in ruminant adipose fats. This difference can be ascribed to (i) the inability of the mammary gland to biosynthesize C18:0; (ii) the biohydrogenation of dietary unsaturated fatty acids in the rumen; and (iii) differences (i.e., 8.1‰) in the δ13C values of the plant dietary fatty acids and carbohydrates. The lipids from a total of 958 archaeological pottery vessels were extracted, and the compound-specific δ13C values of preserved fatty acids (C16:0 and C18:0) were determined via gas chromatography-combustion-isotope ratio mass spectrometry. The results provide direct evidence for the exploitation of domesticated ruminant animals for dairy products at all Neolithic, Bronze Age, and Iron Age settlements in Britain. Most significantly, studies of pottery from a range of key early Neolithic sites confirmed that dairying was a widespread activity in this period and therefore probably well developed when farming was introduced into Britain in the fifth millennium B.C.

Compound-specific stable carbon isotopic detection of pig product processing in British Late Neolithic pottery

By extracting lipids from potsherds and determining the d13C of the most abundant fatty acids, degraded fats from ruminant animals, such as cattle, and non-ruminant animals, such as pigs, can be distinguished. The authors use this phenomenon to investigate Late Neolithic pig exploitation and find that the pig �signature� was more frequently found among residues from Grooved Ware than other prehistoric pottery types.

The Qatna lion: scientific confirmation of Baltic amber in late Bronze Age Syria

Using pyrolysis-gas chromatography/mass spectrometry and Fourier transform infrared spectroscopy, the authors show that amber was imported into Late Bronze Age Syria and used for making the prestige artefacts found in a Royal tomb of c. 1340 BC. The objects included beads and a unique vessel in the form of a lion, likely fashioned in Syria from raw amber imported from the Baltic via the Aegean.

High prestige Royal Purple dyed textiles from the Bronze Age royal tomb at Qatna, Syria

During the ongoing excavations in the palace of the famous Qatna complex, the excavators noted patches of brown staining on the floor of a high status tomb. Chemical extraction revealed the presence of brominated derivatives of indigo and indirubin, and more detailed characterisation showed that it likely came from Hexaplex trunculus. In short, this was none other than the renowned Tyrian or Royal Purple mentioned by Pliny, which was to have such an influential career colouring the clothing of the powerful. Furthermore, it was associated in the tomb with ghosts of high quality textiles preserved in gypsum.