Anna Kropidłowska

μ-trans-1,2-Di-4-pyridylethene-κ2N:N′-bis­[(dimethyl­formamide-κO)bis­(tri-tert-butoxy­silanethiol­ato-κS)cadmium(II)]

In the centrosymmetric title complex, [Cd2(C12H27O3SSi)4(C3H7NO)2(C12H10N2)], the Cd atom is four-coordinated in a CdNOS2 core.

Tetra-n-butyl­ammonium iodido(pyrrolidine-1-carbodithio­ato-κ2S,S′)(tris-tert-butoxy­silanethiol­ato-κS)cadmate(II)

In the anion of the title compound, (C16H36N)[Cd(C5H8NS2)(C12H27O3SSi)I], the Cd atom is four-coordinated by S,S′-chelating dithiocarbamate, S–donating silanethiolate and iodide ligands in a distorted tetrahedral environment . Intermolecular C—H⋯ S and C—H⋯I interactions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.

Chlorido(ethyl­diphenyl­phosphine-κP)(1-pyrrolidinecarbodithio­ato-κ2 S,S′)nickel(II)

In the crystal structure of the title complex, [Ni(C5H8NS2)Cl(C14H15P)], the Ni atom is coordinated by an S,S′-chelating dithiocarbamate, a chloride and a diphenylethylphosphine ligand in a distorted square-planar arrangement.

Chlorido(4-morpholinecarbodithioato-κ2S,S′)(triphenylphosphine)nickel(II)

The title complex, [Ni(C5H8NOS2)Cl(C18H15P)], exhibits a four-coordinate Ni atom in a slightly distorted square-planar geometry.

1,3‐Diethyl‐1,1,3,3‐tetra­phenyl­disiloxane

Molecules of the title compound, C28H30OSi2, are centrosymmetric, with the O atom lying on an inversion centre. The ethyl substituents are placed trans along the strictly linear Si—O—Si fragment.