Anne Lelarge

Crack propagation through phase-separated glasses: effect of the characteristic size of disorder.

We perform fracture experiments on nanoscale phase-separated glasses and measure crack surface roughness by atomic force microscopy. The ability of tuning the phase domain size by thermal treatment allows us to test thoroughly the predictions of crack front depinning models about the scaling properties of crack surface roughness. It appears that, in the range of validity of these depinning models developed for the fracture of brittle materials, our experimental results show a quantitative agreement with theoretical predictions: Beyond the characteristic size of disorder, the roughness of crack surfaces obeys the logarithmic scaling early predicted by Ramanathan, Ertaş, and Fisher [Phys. Rev. Lett. 79, 873 (1997)].

Frozen capillary waves on glass surfaces: an AFM study

Abstract.Using atomic force microscopy on silica and float glass surfaces, we give evidence that the roughness of melted glass surfaces can be quantitatively accounted for by frozen capillary waves. In this framework the height spatial correlations are shown to obey a logarithmic scaling law; the identification of this behaviour allows to estimate the ratio kTF/πγ where k is the Boltzmann constant, γ the interface tension and TF the temperature corresponding to the “freezing” of the capillary waves. Variations of interface tension and (to a lesser extent) temperatures of annealing treatments are shown to be directly measurable from a statistical analysis of the roughness spectrum of the glass surfaces.

A Giant Reconstruction of α-quartz (0001) Interpreted as Three Domains of Nano Dauphine Twins.

Silica (SiO2) is one of the most common materials on Earth. The crystalline form α-quartz is the stable silica polymorph at ambient conditions although metastable forms exist. α-quartz is a piezoelectric material, it can be produced artificially and is widely used for example in electronics and the biosciences. Despite the many application areas, the atomic surface structures of silica polymorphs are neither well understood nor well characterized. Here we present measurements of α-quartz (0001). Helium Atom Scattering combined with Atomic Force Microscopy reveals a giant reconstruction consisting of 5.55 ± 0.07 nm wide ribbons, oriented 10.4° ± 0.8° relative to the bulk unit cell. The ribbons, with the aid of atomistic modelling, can be explained as a self-organised pattern of nano Dauphine twins (nano electrical twins).

Quantitative AFM analysis of phase separated borosilicate glass surfaces

Phase separated borosilicate glass samples were prepared by applying various heat treatments. Using selective chemical etching we performed AFM measurement on the phase separated glass surfaces. A quantitative roughness analysis allowed us to measure precisely the dependence of the characteristic size of the phase domains on heating time and temperature. The experimental measurements are very well described by the theoretically expected scaling laws. Interdiffusion coefficients and activation energy are estimated from this analysis and are consistent with literature data.