Annette Hahn

New insights into paleoenvironmental changes in Laguna Potrok Aike, southern Patagonia, since the Late Pleistocene: The PASADO multiproxy record

A series of long sediment cores was retrieved from Laguna Potrok Aike, Southern Patagonia, within the framework of PASADO (Potrok Aike Maar Lake Sediment Archive Drilling Project), an ICDP (International Continental Scientific Drilling Program) lake drilling project. This maar lake, located at 52°S, 70°W in the Province of Santa Cruz (Argentina), in the southernmost continental area of the world, is one of the few permanent lakes in the region, providing a unique continuous paleoclimatic and paleoecological lacustrine record for the last glacial cycle. Previous multiproxy studies of this site have characterized the environmental history of these dry lands in the Patagonian Steppe for the last 16 cal. ka BP. This new series of sediment cores provides a much longer record of climate variability in Southern Patagonia since 51.3 cal. ka BP. Using a multiproxy strategy, a set of samples (mostly from core catcher material) was analyzed for physical properties, rock magnetism, geochemistry, CNS elemental analysis, stable isotopes, pollen and diatoms. This preliminary multiproxy limnogeological interpretation sheds new light on the regional Pleistocene and Holocene environmental history, revealing lake-level variations through time and identifying time windows of interest where higher resolution analyses will be carried out.

Universally Applicable Model for the Quantitative Determination of Lake Sediment Composition Using Fourier Transform Infrared Spectroscopy

Fourier transform infrared spectroscopy (FTIRS) can provide detailed information on organic and minerogenic constituents of sediment records. Based on a large number of sediment samples of varying age (0-340,000 yrs) and from very diverse lake settings in Antarctica, Argentina, Canada, Macedonia/Albania, Siberia, and Sweden, we have developed universally applicable calibration models for the quantitative determination of biogenic silica (BSi; n = 816), total inorganic carbon (TIC; n = 879), and total organic carbon (TOC; n = 3164) using FTIRS. These models are based on the differential absorbance of infrared radiation at specific wavelengths with varying concentrations of individual parameters, due to molecular vibrations associated with each parameter. The calibration models have low prediction errors and the predicted values are highly correlated with conventionally measured values (R = 0.94-0.99). Robustness tests indicate the accuracy of the newly developed FTIRS calibration models is similar to that of conventional geochemical analyses. Consequently FTIRS offers a useful and rapid alternative to conventional analyses for the quantitative determination of BSi, TIC, and TOC. The rapidity, cost-effectiveness, and small sample size required enables FTIRS determination of geochemical properties to be undertaken at higher resolutions than would otherwise be possible with the same resource allocation, thus providing crucial sedimentological information for climatic and environmental reconstructions.

Holocene vegetation and climate variability in the winter and summer rainfall zones of South Africa

To better understand Holocene vegetation and hydrological changes in South Africa, we analyzed pollen and microcharcoal records of two marine sites GeoB8331 and GeoB8323 from the Namaqualand mudbelt offshore the west coast of South Africa covering the last 9900 and 2200 years, respectively. Our data corroborate findings from literature that climate developments apparently contrast between the summer rainfall zone (SRZ) and winter rainfall zone (WRZ) over the last 9900 years, especially during the early and middle Holocene. During the early Holocene (9900–7800 cal. yr BP), a minimum of grass pollen suggests low summer rainfall in the SRZ, and the initial presence of Renosterveld vegetation indicates relatively wet conditions in the WRZ. Toward the middle Holocene (7800–2400 cal. yr BP), a rather moist savanna/grassland rich in grasses suggests higher summer rainfall in the SRZ resulting from increased austral summer insolation and a decline of fynbos vegetation accompanied by an increasing Succulent Karoo vegetation in the WRZ, which possibly suggests a southward shift of the Southern Hemisphere westerlies. During the last 2200 years, a trend toward higher aridity was observed for the SRZ, while the climate in the WRZ remained relatively stable. The ‘Little Ice Age’ (ca. 700–200 cal. yr BP) was rather cool in both rainfall zones and drier in the SRZ while it was wetter in the WRZ.

Comparative study of infrared techniques for fast biogeochemical sediment analyses

Analysis of sediment samples in the visible to mid infrared (IR) region requires small amounts of sample material and enables rapid and cost efficient geochemical analysis of mineral and organic sediment components. Here we use geochemical properties (total organic and inorganic carbon, biogenic silica, total nitrogen) from the ICDP deep drilling project PASADO to compare three different IR spectroscopy techniques: Diffuse Reflectance Fourier Transform IR Spectrometry (DRIFTS), Attenuated Total Reflectance Fourier Transform IR Spectroscopy (ATR-FTIRS) and Visible Near IR Spectroscopy (VNIRS). ATR-FTIRS and VNIRS are more rapid techniques compared to DRIFTS. Results show that calibration models developed using DRIFTS are most robust (correlation coefficient: R = 0.92 for TIC, R = 0.84 for BSi, R = 0.97 for TOC, R = 0.95 for TN). However, good statistical performance was also obtained by using ATR-FTIRS and VNIRS. When time and costs are limiting factors, these tools may be given preference for rapid biogeochemical screening.

First evidence of denitrification vis-à-vis monsoon in the Arabian Sea since Late Miocene

In the Arabian Sea, South Asian monsoon (SAM)-induced high surface water productivity coupled with poor ventilation of intermediate water results in strong denitrification within the oxygen minimum zone (OMZ). Despite the significance of denitrification in the Arabian Sea, we have no long-term record of its evolution spanning the past several million years. Here, we present the first record of denitrification evolution since Late Miocene (~10.2 Ma) in the Eastern Arabian Sea, where the SAM generates moderate surface water productivity, based on the samples retrieved during the International Ocean Discovery Program (IODP) Expedition 355. We find that (i) the SAM was persistently weaker from ~10.2 to 3.1 Ma; it did not intensify at ~8 Ma in contrast to a few previous studies, (ii) on tectonic timescale, both the SAM and the East Asian Monsoon (EAM) varied synchronously, (iii) the first evidence of denitrification and productivity/SAM intensification was at ~3.2–2.8 Ma that coincided with Mid-Pliocene Warm Period (MPWP), and (iv) the modern strength of the OMZ where denitrification is a permanent feature was attained at ~1.0 Ma.

Late-Holocene dynamics of sea-surface temperature and terrestrial hydrology in southwestern Africa

Southwest Africa is an important region for paleo-climatic studies, being influenced by both tropical and temperate climate systems and thus reflecting the interplay of variable controls. The aim of this study was to unravel the interaction of sea-surface temperature (SST) changes in the southernmost Benguela upwelling system with precipitation changes in South Africa’s winter rainfall zone (WRZ) during the late Holocene. Therefore, a marine sediment core from the southernmost Benguela upwelling system was investigated to reconstruct climate changes in this region for the past ~2000 years. Grain size and geochemical analyses were conducted to reconstruct changes in fluvial sediment discharge and weathering intensity, while SST changes were estimated using alkenone paleo-thermometry. Results show that the southernmost Benguela behaves distinctly in comparison with the rest of the Benguela system reflecting amplified SST changes. Decreasing SSTs accompanied increasing river discharge during times of increased precipitation in the WRZ, reflecting northerly shifted westerly winds during austral winter. We infer a control of past SST changes by processes not analogous to modern processes driving seasonal SST changes by changes through upwelling intensity. The findings suggest that late-Holocene SST changes in the southernmost Benguela upwelling system and the precipitation in the WRZ were both driven by latitudinal shifts of the austral westerly wind belt and associated changes in advection of cold sub-Antarctic waters and/or changes in Agulhas leakage of warm Indian Ocean waters.