Anthony Thuault

Ultrastructure of cellulose crystallites in flax textile fibres

Seven varieties of flax (Linum usitatissimum) fibres were analyzed in order to gain a deeper insight into the morphological features of the crystalline assembly. Different spectroscopic techniques and a chemical bleaching process were used to provide an accurate description of the lateral arrangement of the polysaccharide chains within the fibre cell wall. The flax fibres were analyzed in their natural state and after an extraction treatment of the non-crystalline components such as hemicelluloses, pectins and phenolics. The chemical bleaching process consisted of a Soxhlet extraction in toluene, a sodium chlorite treatment and an alkaline extraction of the residual hemicelluloses. Solid-state 13C nuclear magnetic resonance (NMR) confirmed the sequential removal of the non-cellulosic components from the flax cell wall. Both wide-angle X-ray diffraction (WAXD) and solid-state 13C NMR provided measures of the crystallite thicknesses and overall crystallinities before and after treatment. The existence of non-cellulosic highly ordered paracrystalline domains was also evidenced by proton spin relaxation time calculation. Whereas the overall crystallinity determined by WAXD decreased after treatment, the cellulose crystallinity calculated with the help of the solid-state 13C NMR slightly increased. This is explained by the difference in chemical selectivity between these two techniques and by the paracrystalline state of both hemicelluloses and pectins. Strong adhesion between cellulose crystallites, hemicelluloses and pectins in the fibres was evidenced by low spin–spin relaxation times and by an increase in crystallite thickness after bleaching. A simple model is proposed that describes the rearrangement of the macromolecules during the bleaching process.

Effects of the hygrothermal environment on the mechanical properties of flax fibres

Since flax is the most promising plant for the reinforcement of polymer-based composites in structural applications, we have chosen to investigate its hygrothermal characteristics which can be useful for the understanding of the behaviour of other plant fibres. The flax fibres were exposed to different hygrothermal conditions: in an oven at various controlled temperatures (–40 to 140℃) and measured relative humidity, in a climate chamber at 50% relative humidity for define temperatures between 25℃ and 85℃, or different determined aging conditions. The correlation of these hygrothermal conditions to the evolution of the mechanical properties gives evidence of the prominent influence of water over temperature on the microstructural changes of flax fibres. The mechanical parameters drastically decrease in usually prescribed hygrothermal aging conditions for organic matrix composite materials, the strength being particularly sensitive to the presence of water. These evolutions were correlated to the fibre microstructure modifications induced by water absorption as revealed by electron microscopy analyses. These findings could be useful for understanding the behaviour of polymer matrix biocomposites in severe hygrothermal conditions.

Numerical study of the influence of structural and mechanical parameters on the tensile mechanical behaviour of flax fibres

This paper presents the results of a numerical simulation of the ultimate flax fibre (Linum usitatissimum) tensile mechanical behaviour using finite element analysis. Experimental data were used to develop a numerical multilayer model of the flax fibre. Thus, the influence of some parameters, such as cell wall thicknesses, microfibrils angles (MFAs), biochemical composition and mechanical properties of the biochemical components, on the flax fibre tensile mechanical behaviour has been investigated. Results show that the typical stress–strain curve profile of the flax fibre could be due to the mechanical properties of hydrophilic components (hemicelluloses) and thus to the environmental conditions. A parameter sensitivity study reveals that ultrastructural parameters (hemicelluloses and cellulose Young’s modulus) strongly influence the flax fibre mechanical behaviour and structural parameters (S2 cell wall layer MFA and thickness) significantly influence the fibre longitudinal Young’s modulus. Thus, the knowledge of the fibre ultrastructure seems to be the key of the understanding of the flax fibre mechanical behaviour.

Synchrotron X-Ray Tomographic Investigation of Internal Structure of Individual Flax Fibres

The structure of natural flax fibres is complex and hierarchical, consisting of multiple concentric layers that differ in composition and function. Naturally grown fibres show significant variation in structure that is likely to be responsible for the observed scatter in mechanical properties, most notably strength and stiffness. As flax fibres are being considered as an alternative reinforcement in composite materials to replace synthetic fibres, understanding the origins of property variability is a major objective of their study.