Anton Khrustalyov

The Application of External Fields to the Manufacturing of Novel Dense Composite Master Alloys and Aluminum-Based Nanocomposites

The possibility of producing dense and concentrated master alloys containing nanosized Al2O3 by shock-wave compacting is demonstrated. Different conditions of shock-wave process are discussed. The data of master alloys characterization are presented. The nanostructured master alloys have high density and are convenient for metallurgical handling. It is found that the use of such a master alloy with nanoceramic particles facilitates the particle introduction into the aluminum melt. The ultrasonic treatment performed during and after the introduction of the master alloy into the melt further leads to uniform distribution of strengthening nanoparticles and improvement of alloy strength and ductility. Experimental results are shown and discussed.

Ultrasonic effect on the penetration of the metallic melt into submicron particles and their agglomerates

Deagglomeration and wetting of submicron particles in a metal melt under ultrasonic exposure are considered based on the theory of acoustic cavitation and capillary phenomena. Basic dependences linking the exposure time with physicochemical properties of the particles and the melt, as well as with acoustic radiation characteristics, are found. The experimental and calculated times of ultrasonic treatment of the aluminum melt containing submicron aluminum oxide particles are compared, and a satisfactory agreement of results is found.

Ultrasonic impact on a metal melt containing electrostatically charged nanoparticles

Ultrasonic processing is applied to modify nanopowders of metals for the creation of composition alloys. The introduction of particles to metal is prevented by their low wettability in the metal melt. We use electrostatic charging of particles to increase the wettability of particles and to prevent their agglomeration. Mechanisms of the ultrasonic impact on melts of metals containing charged nanoparticles are considered. We find that an electric charge of the surface leads to a decrease in the contact angle. Expressions for the time of ultrasonic processing depending on physical and chemical characteristics of particles and the melt are found.

Ultrasonic dispersion of agglomerated particles in metal melt

This work considers the deagglomeration and wettability of particles by metal melt and proposes a mechanism of particle agglomerate dispersion by ultrasonic cavitation. The main dependences connecting the processing time and intensity with the physical and chemical properties of particles and the melt as well as acoustic parameters are obtained. For the first time found that melt during ultrasonic treatment, inclusive the particles agglomerates proportional to melt viscosity and the size of the agglomerates. It has been established that time ultrasonic treatment melt containing the particles agglomerates is proportional to melt viscosity and the size of the agglomerates. The required time for successful melt infiltration in the agglomerates, wettability and their introduction into the melt takes ten minutes. The suggested equation allows estimating the intensity of ultrasonic radiation, required to destroy the agglomerates of particles in the melt. It was found that intensity of the ultrasound must be inv...

Regularities in the structure and properties formation of aluminum-based composites during hot pressing

The purpose of this study is to investigate the phase composition, parameters of fine crystalline structure and mechanical properties of aluminum-based composites, produced by hot pressing with different synthesis temperatures and isothermal times. For synthesis of composites we used powder mixture of aluminum (particles size 700 nm) and carbon powder in a form of nanodiamonds (size 4 nm). It has been shown that after hot press processing a nanophase (crystallites size 25 nm) of aluminum carbide was formed. Regardless of the synthesis temperature for the maximum holding time of powder mixtures, the density of hot-pressed compacts is about 2.2-2.37 g/cm3. In particular, the value of bending strength of composite samples with a density of 2.37 g/cm3 ranges from 350 to 480 MPa. In the nonporous state, the bending strength of the composites may reach 920 MPa.

Structure and deformation characteristics in magnesium alloy ZK51A reinforced with AlN nanoparticles

The aim of this work was to study the influence of nanoparticles of aluminum nitride on the structure and mechanical properties of magnesium alloy. We examine the resulting magnesium alloys. The experiment consisted in the introduction into the melt of magnesium aluminum nitride powder in an amount of 0.75 and 1.5%. Introduction of nanoparticles into the molten metal was carried out by external vibration exposure. Studies were carried out of aluminum nitride powder, comprising X-ray diffraction analysis to study the morphology using electron microscopy. Introduction of nanoparticles in the alloy increases the pore volume space from 5 to 15% and increased average pore size from 8 to 30 µm. It was shown that the presence of the nanoparticles in an amount of 1.5% increases the alloy properties by more than 30% compared with the reference (non-particulate) alloy. We were obtained diagrams such as stress - strain. It was also carried out studies of the structure and X-ray analysis of the alloys obtained.

Synthesis and properties of aluminum-based composite materials for high operating temperatures

Aluminum-based composite materials reinforced with ceramic particles are of great practical interest due to their potentially high physical and mechanical properties. In this work, Al–Al4C3 composites are obtained by a hot-pressing method. Introduction of nanodiamonds into aluminum nanopowder in the amount 10 wt % leads to the formation of 15 wt % of aluminum carbide during hot pressing. It is found that composite materials with the diamond content of 10 wt % in the initial powder mixture have the microhardness 150 HV whilst the similarly hot-pressed aluminum powder without reinforcing particles shows a hardness of 75 HV. The mechanical properties of an Al–Al4C3 composite material at elevated test temperatures exceed those of commercial casting aluminum alloys.