Antonio Delfino

Critical compressive stress for continuous fiber unidirectional composites

Dow and Rosen’s work in 1965 formed an intellectual framework for compressive strength of unidirectional composites. Compressive strength was explained in terms of micro-buckling, in which filaments are beams on an elastic foundation. While groundbreaking, the discrepancy between model predictions and observed compressive strength is well known. This study builds on Dow and Rosen’s model specifically with respect to the dominant shear mode instability. A new method that accounts for matrix thermal residual strain, matrix compressive and shear stresses, with associated reductions in tangent modulus due to matrix non-linearity, is proposed. The method is validated using a specific test case, which is conducted to precisely account for microscopic fiber alignment and matrix non-linearity. Accordingly, a method of measuring and accounting for a continuum of fiber misalignment is developed. Predictions are compared to literature values, with variations in fiber modulus, matrix modulus, and volume fraction. Good agreement is shown, both in terms of trend and magnitude. The approach successfully preserves initial in-plane shear stiffness, while showing that in-plane shear stiffness decreases significantly as compressive stress increases.

Solar-hydrogen generation and solar concentration (Conference Presentation)

We successfully demonstrated and reported the highest solar-to-hydrogen efficiency with crystalline silicon cells and Earth-abundant electrocatalysts under unconcentrated solar radiation. The combination of hetero-junction silicon cells and a 3D printed Platinum/Iridium-Oxide electrolyzer has been proven to work continuously for more than 24 hours in neutral environment, with a stable 13.5% solar-to-fuel efficiency. Since the hydrogen economy is expected to expand to a global scale, we demonstrated the same efficiency with an Earth-abundant electrolyzer based on Nickel in a basic medium. In both cases, electrolyzer and photovoltaic cells have been specifically sized for their characteristic curves to intersect at a stable operating point. This is foreseen to guarantee constant operation over the device lifetime without performance degradation. The next step is to lower the production cost of hydrogen by making use of medium range solar concentration. It permits to limit the photoabsorbing area, shown to be the cost-driver component. We have recently modeled a self-tracking solar concentrator, able to capture sunlight within the acceptance angle range +/-45°, implementing 3 custom lenses. The design allows a fully static device, avoiding the external tracker that was necessary in a previously demonstrated +/-16° angular range concentrator. We will show two self-tracking methods. The first one relies on thermal expansion whereas the second method relies on microfluidics.

Theoretical and experimental compressive strength of a glass fiber – vinyl ester pultruded composite

A simple method of compressive strength measurement of a continuously pultruded unidirectional glass-vinyl ester rod is developed. Measured compressive strength was quite high. Compared to a unidirectional composite laminate of the same composition, compressive strength values were doubled. The study shows that glass fiber composites have the potential for high compressive strength. This potential is reached with excellent fiber alignment and suitable matrix characteristics. Results of both laminate and pultruded composites are shown to be consistent with model predictions, with the primary delineating factor being fiber alignment.