Anxin Ding

A comparison of process-induced residual stresses and distortions in composite structures with different constitutive laws

The popular analytical and numerical models to residual stresses and distortions in composite structures during curing are reviewed with emphases being placed on the numerical models with viscoelastic, path-dependent, CHILE constitutive laws, and corresponding numerical implementation into finite element analyses in this paper. A simple C-section composite part made of AS4/8552 prepreg, which has been investigated previously, was taken as an example to compare the difference in residual stresses and distortions with analytical model and numerical method with different constitutive laws. This paper mainly focuses on the effects of residual stresses generated at the different stages during curing on the finial distortions of composite structures for different constitutive laws, especially for effects of residual stresses generated in the rubbery stage on the final distortions. The results show that there is insignificant difference in the calculated residual stresses and distortions in C-section composite part induced during curing with different constitutive laws except the CHILE(α) law.

The Effects of a Macromolecular Charring Agent with Gas Phase and Condense Phase Synergistic Flame Retardant Capability on the Properties of PP/IFR Composites

In order to improve the efficiency of intumescent flame retardants (IFRs), a novel macromolecular charring agent named poly(ethanediamine-1,3,5-triazine-p-4-amino-2,2,6,6-tetramethylpiperidine) (PETAT) with gas phase and condense phase synergistic flame-retardant capability was synthesized and subsequently dispersed into polypropylene (PP) in combination with ammonium polyphosphate (APP) via a melt blending method. The chemical structure of PETAT was investigated by Fourier transform infrared spectroscopy (FTIR), and 1H nuclear magnetic resonance (NMR) spectroscopy. Thermal properties of the PETAT and IFR systems were tested by thermogravimetric-derivative thermogravimetric analysis (TGA-DTG) and thermogravimetry–Fourier transform infrared spectroscopy (TG-FTIR). The mechanical properties, thermal stability, flame-retardant properties, water resistance, and structures of char residue in flame-retardant composites were characterized using tensile and flexural strength property tests, TGA, limiting oxygen index (LOI) values before and after soaking, underwritten laboratory-94 (UL-94) vertical burning test, cone calorimetric test (CCT), scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDXS), and FTIR. The results indicated that PETAT was successfully synthesized, and when the ratio of APP to PETAT was 2:1 with 25 wt % loading, the novel IFR system could reduce the deterioration of tensile strength and enhance the flexural strength of composites. Meanwhile, the flame-retardant composite was able to pass the UL-94 V-0 rating with an LOI value of 30.3%, and the peak of heat release rate (PHRR), total heat release (THR), and material fire hazard values were considerably decreased compared with others. In addition, composites also exhibited excellent water resistance properties compared with traditional IFR composites. SEM-EDXS and FTIR analyses of the char residues, as well as TG-FTIR analyses of IFR were used to investigate the flame-retardant mechanism of the APP/PETAT IFR system. The results indicated that the efficient flame retardancy of PP/IFR composites could be attributed to the synergism of the free radical-quenching and char layer-protecting mechanisms in the gas phase and condense phase, respectively.

High temperature behaviour of glass-vinyl ester stack liner

High temperature behaviour of glass-vinyl ester stack liner at the operation temperature (20–121°C) was experimentally investigated by measurements on the small specimens and full scale specimens in this paper. Based on the stacking sequences of a typical glass-vinyl ester stack liner, three groups of small specimens were produced to evaluate the degradation of their tensile and compressive strength, the tensile modulus, and the flexural strength and modulus with increasing temperature, and one group of full scale specimens was prepared to measure their properties at room temperature. Furthermore, the ultimate axial tensile stress of a suspended glass-vinyl ester stack liner at various temperatures was derived according to the experimental results from the small specimens and full scale specimens. The high temperature behaviour of composites stack liner from the tests can be used as reference for determining the extreme operation temperature in coal-fired power plants.