Ari Jokilaakso

Modelling gas injection of a Peirce–Smith-converter

Abstract A commercial CFD-code PHOENICS was used to solve isothermal flow field of gas and liquid in a Peirce–Smith-converter. An Euler–Euler based algorithm was chosen for modelling fluid dynamics and evaluating controlling forces of a submerged gas injection. Predictions were made with a k – e turbulence model in the body fitted coordinate system. The model has been verified with a 1/4 scale water model, and a parametric study with the mathematical model of submerged gas injection was made for the PS-process and the ladle injection processes. Limits of the modelling technique used were recognised, but calculated results indicate that the present model predicts the general flow field with reasonable accuracy. Predicted bubble distribution, pattern of the flow field and magnitude of flow velocities were used to evaluate scaling factors of physical models and general flow conditions of an industrial PS-converter.

Experimental and Computational-Fluid-Dynamics Simulation of the Outokumpu Flash Smelting Process

The Outokumpu flash smelting process has been developed for the production of copper, nickel and lead from their sulphidic concentrates by Outokumpu Oy. To date, there are 38 flash smelting licences sold for copper, nickel and sulphur production world-wide. At present the use of complex concentrates in large amounts in the flash smelting process is not possible, due to the accumulation of impurities in the present plant practice where flue dust is circulated. If it were technically possible to smelt complex concentrates in the flash smelting furnace, it would make vast resources of relatively low-cost raw materials available to flash smelters. However, different practices for treating complex copper and nickel concentrates in the flash smelting furnace can be studied with combined laboratory studies and computer simulations. Computer simulation of flash smelting requires a substantial knowledge of the behavior of particles during their flight in the particle-gas suspension. The reactions taking place in t...

Behavior of Co, Ni and Precious Metals in Copper Converting Process: Experimental Study

This study is focused on distribution of Co, Ni, Ag, Au, and Pd between molten copper and molten copper sulfide (‘white metal’) phases in copper converting conditions. The behavior of the elements selected was studied experimentally at 1300 °C and at various sulfur dioxide partial pressures (0.01, 0.05, 0.1, 0.5, and 1 atm). The experimental technique employed involves a high temperature equilibration followed by rapid quenching in ice water, with subsequent quantitative elemental analysis of the equilibrium phases with an electron micro probe analyzer. The distribution coefficients \( {\text{L}}_{\text{Me}}^{{{\text{Cu}}/{\text{wm}}}} \) determined in this work can be arranged in the following sequence: Co < Ag < Ni < (Au, Pd).

Trace Metal Distributions in Nickel Slag Cleaning

To capture efficiently the valuable trace metals from nickel slag using electric furnace, it is important to study their distributions between the slag and metallic phases in the furnace. It is impossible to calculate accurately these distributions without experimental measurements. Therefore, in this work, selected trace metal distributions and phase equilibria between K2O containing iron-silicate slags and a metallic Ni-Fe-Cu alloy in nickel slag cleaning furnace conditions were studied. The experimental method developed and applied during the work, involved a modified quenching technique that included equilibration of the samples in semi-sealed quartz ampoules in an inert atmosphere and metallic Fe saturation. The use of the semi-sealed quartz ampoule prevents the escape of volatile elements from the sample during equilibration. Chemical compositions of the phases and the trace elements were analysed by EPMA. From the measured compositions, the trace metal distribution coefficients between the molten Ni-Fe-Cu alloy and slag were calculated.

Experimental Investigation of Pyrometallurgical Treatment of Zinc Residue

Iron containing leach residues like jarosite and goethite from electrolytic zinc production contain many valuable metals and harmful substances. These metals and substances should be removed in order to obtain an acceptable, stable and reusable product, and maximize economic feasibility as well as minimize environmental footprint. In this work, the processing of jarosite leach residue was studied in laboratory scale experiments under oxidizing and reducing conditions at high temperatures. First, the pretreated material was melted and oxidized to produce a melt of metal oxides. Second, the oxide melt was reduced in CO–CO2 atmosphere. Target after the reduction step was to obtain a clean slag and a liquid metal or speiss phase that collects the valuable metals, such as silver. The kinetics of the thermal processing were studied for determining optimal times and conditions for the aforementioned process steps. The preliminary results show that the process is thermodynamically feasible, and the desired phases can be obtained in the experimental conditions investigated.

Behavior of Nickel as a Trace Element and Time-Dependent Formation of Spinels in WEEE Smelting

For better understanding and maximal value utilization of the WEEE smelting process, the behavior and distribution of different trace elements must be known. In this study, the behavior of nickel as a trace element was studied in an equilibrium system with metallic copper—spinel saturated iron silicate slag (with 3 wt-% K2O)—iron aluminous spinel—gas. The experiments were conducted in alumina crucibles at 1300 °C, in oxygen pressure range of 10−10–10−5 atm. A time series of 15–60 min experiments was also conducted for investigating the formation rate of the primary spinel phase in the system. The results show that the distribution coefficient of nickel between metallic copper and liquid slag changes from approximately 70 to 0.4 along the increasing oxygen pressure range. In addition, a significant part of the nickel deports into the spinel phase. The spinel formation was investigated based on composition analysis results and visual observations from SEM-images.

Dynamic Modelling of Molten Slag-Matte Interactions in an Industrial Flash Smelting Furnace Settler

Depleting copper resources and advancing technologies have challenged industries to develop more viable, adaptable and cost efficient processes using also secondary raw materials in copper production. This study is targeting to that goal by dynamic modelling of flow and heat transfer coupled with chemical kinetics in an industrial scale flash smelting furnace settler using commercial CFD software ANSYS Fluent. First, different physical phenomena occurring inside the settler, for example, settling and separation of the matte/slag phases, and heat transfer between slag/matte phases and settler walls are studied. Secondly, reaction kinetics between matte and slag, and between slag/matte and settler walls, and impurity element distribution will be studied. This would also include phase changes phenomena due to these reactions and the flow of the reaction gases inside the settler. Settling of polydispersed droplets, their coagulation, breakage, and WEEE particle behavior are further targets of the modelling work.

A New Pyrometallurgical Recycling Technique for Lead Battery Paste Without SO 2 Generation—A Thermodynamic and Experimental Investigation

An innovative lead recycling process from scrap lead-acid battery paste is presented. The novelty in the process is avoiding SO2 generation and emission by using reductive sulfur-fixing technique. Iron-bearing secondary wastes produced from metallurgical industry were utilized as sulfur-fixing agent to capture sulfur in the form of FeS (s) instead of generation of SO2 (g). Na2CO3 molten salt was added to the smelting system to speed the reactions and improve valuable metals’ recovery and sulfur-fixation efficiency. Furthermore, this process can simultaneously co-treat various lead and iron-bearing wastes. At the same time, some precious metals, such as Au and Ag, contained in iron-bearing wastes can be recovered. The feasibility and reliability of this process was investigated thermodynamically and experimentally with the help of HSC 9.0 database and XRD and SEM-EDS analysis. A possible reaction mechanism and path in PbSO4–Fe2O3–Na2CO3–C smelting system was also clarified.

Matte converting in copper smelting

ABSTRACT Copper matte converting is the key step to ensure high primary copper recovery in the smelting chain. Its development and the fundamental research carried out over the past decades will be reviewed. The operational challenges and environmental concern of batch-wise Peirce-Smith Converting vessel have induced more than 50 years ago attempts to continuous converting process which have materialised in the last two decades in the flash converting technology, utilised currently in one smelter in USA and three smelters in China. Their annual copper production is in excess of 1.5 Mt, and selected fundamental studies behind this major technological invention will be examined.