Arianna Trentini

Characteristics and major sources of carbonaceous aerosols in PM2.5 in Emilia Romagna Region (Northern Italy) from four-year observations

The concentrations of organic and elemental carbon in PM2.5 aerosol samples were measured in two sites of Emilia Romagna (Po Valley, Northern Italy) in eight campaigns during different seasons from 2011 to 2014. Strong seasonality was observed with the highest OC concentrations during the cold periods (≈ 5.5 μg m(-3)) and the lowest in the warm months (≈ 2.7 μg m(-3)) as well as with higher EC levels in fall/winter (≈ 1.4 μg m(-3)) in comparison with spring/summer (≈ 0.6 μg m(-3)). Concerning spatial variability, there were no statistically significant difference (p<0.05) between OC concentrations at the two sampling sites in each campaign, while the EC values were nearly twofold higher levels at the urban site than those at the rural one. Specific molecular markers were investigated to attempt the basic apportionment of OC by discriminating between the main emission sources of primary OC, such as fossil fuels burning - including traffic vehicle emission - residential wood burning, and bio-aerosol released from plants and microorganisms, and the atmospheric photo-oxidation processes generating OCsec. The investigated markers were low-molecular-weight carboxylic acids - to describe the contribution of secondary organic aerosol - anhydrosugars - to quantify primary emissions from biomass burning - bio-sugars - to qualitatively estimate biogenic sources - and Polycyclic Aromatic Hydrocarbons - to differentiate among different combustion emissions. Using the levoglucosan tracer method, contribution of wood smoke to atmospheric OC concentration was computed. Wood burning accounts for 33% of OC in fall/winter and for 3% in spring/summer. A clear seasonal trend is also observed for the impact of secondary processes with higher contribution in the warm seasons (≈ 63%) in comparison with that in colder months (≈ 33%), that is consistent with enhanced solar radiation in spring/summer.

Preliminary Results Of The Project “Supersito” Concerning The Atmospheric Aerosol Composition In Emilia-Romagna Region, Italy: PM Source Apportionment And Aerosol Size Distribution

The Emilia-Romagna region and its Agency for Prevention and Environment are running a project – called Supersito – the purpose of which is to gain further knowledge about the components of fine and ultrafine particles in the atmosphere. Supersito began the measurements at the end of 2011, in this paper we summarize the preliminary results observed for the aerosol size distribution and source apportionment of PM2.5 in Bologna’s urban background. Results show that nitrates, sulphates and ammonium accounts for more than 40% of the mass of PM2.5 in the cold season and for about 30% in the summer. The carbonaceous fraction (organic aerosol plus elemental carbon) is about 40% in both seasons. PMF analysis of the data coming from the results of the mass composition shows that important fractions of PM2.5 during the cold season come from

Higher health effects of ambient particles during the warm season: The role of infiltration factors

A large number of studies have shown much higher health effects of particulate matter (PM) during the warm compared to the cold season. In this paper we present the results of an experimental study carried out in an unoccupied test apartment with the aim of understanding the reasons behind the seasonal variations of the health effects due to ambient PM2.5 exposure. Measurements included indoor and outdoor PM2.5 mass and chemical composition as well as particle size distribution of ultrafine particles. Monitoring campaigns were carried out during summer and winter following a ventilation protocol developed to replicate typical occupant behaviour according to a questionnaire-based survey. Our findings showed that seasonal variation of the relationship between ambient and indoor mass concentrations cannot entirely explain the apparent difference in PM toxicity between seasons and size distribution and chemical composition of particles were identified as other possible causes of changes in the apparent PM toxicity. A marked decrease of ultrafine particles (<100 nm) passing from outdoors to indoors was observed during winter; this resulted in higher indoor exposure to nanoparticles (<50 nm) during summer. With regards to the chemical composition, a pooled analysis showed infiltration factors of chemical species similar to that obtained for PM2.5 mass with values increasing from 0.73 during winter to 0.90 during summer and few deviations from the pooled estimates. In particular, significantly lower infiltration factors and sink effect were found for nitrates and ammonium during winter. In addition, a marked increase in the contribution of indoor and outdoor sulfates to the total mass was observed during summer.

Vertical variation of PM2.5 mass and chemical composition, particle size distribution, NO2, and BTEX at a high rise building

Substantial efforts have been made in recent years to investigate the horizontal variability of air pollutants at regional and urban scales and epidemiological studies have taken advantage of resulting improvements in exposure assessment. On the contrary, only a few studies have investigated the vertical variability and their results are not consistent. In this study, a field experiment has been conducted to evaluate the variation of concentrations of different particle metrics and gaseous pollutants on the basis of floor height at a high rise building. Two 15-day monitoring campaigns were conducted in the urban area of Bologna, Northern Italy, one of the most polluted areas in Europe. Measurements sites were operated simultaneously at 2, 15, 26, 44 and 65 m a.g.l. Several particulate matter metrics including PM2.5 mass and chemical composition, particle number concentration and size distribution were measured. Time integrated measurement of NO2 and BTEX were also included in the monitoring campaigns. Measurements showed relevant vertical gradients for most traffic related pollutants. A monotonic gradient of PM2.5 was found with ground-to-top differences of 4% during the warm period and 11% during the cold period. Larger gradients were found for UFP (∼30% during both seasons) with a substantial loss of particles from ground to top in the sub-50 nm size range. The largest drops in concentrations for chemical components were found for Elemental Carbon (-27%), iron (-11%) and tin (-36%) during winter. The ground-to-top decline of concentrations for NO2 and benzene during winter was equal to 74% and 35%, respectively. In conclusion, our findings emphasize the need to include vertical variations of urban air pollutants when evaluating population exposure and associated health effects, especially in relation to some traffic related pollutants and particle metrics.