Arlete Cassanho

Review of the properties of up-conversion phosphors for new emissive displays

In this paper, we review the properties of up-conversion (UC) materials and assess their potential for a new display technology. UC materials absorb near infrared light and re-emit in the visible. Some of their most appealing characteristics for displays are: a wide color gamut with very saturated colors, very high brightness operation without damage to the emitters, long lifetimes and efficiencies comparable to those of existing technologies. Other advantages include simplicity of fabrication, versatility of operation modes, and the potential for greatly reduced display weight and depth.

High-brightness white-light source based on up-conversion phosphors

We report the implementation of a new, high brightness, high efficiency white-light source based on up-conversion phosphors. Up-conversion materials absorb near infrared light and re-emit in red, green, and blue. It is possible to combine these colors to create a white-light source. Such a source has the same appealing characteristics as those reported for up-conversion displays: very high brightness operation without damage to the emitters, long lifetimes, and efficiencies comparable to those of existing technologies. In addition, they offer simplicity of fabrication and a variety of operating modes. Here we demonstrate a 7-lm/W D65 white light emitter yielding 2 kcd/m 2 on a simple diffuser

Investigation of diode-pumped 2.8-µm laser performance in Er:BaY2F8

Laser operation at 2.8 mm in BaY2F8 with erbium concentrations of 7.5% and 20% is investigated under laser-diode pumping at 967 nm. Output powers as high as 250 mW and slope efficiencies as high as 24% are obtained. Results are comparable with those of Er3+:LiYF4 under the same pump conditions. Slope efficiencies above 30% are predicted for optimized erbium concentrations.

Investigation of diode-pumped 2.8-{bold {mu}}m laser performance in Er:BaY{sub 2}F{sub 8}

Laser operation at 2.8 mm in BaY2F8 with erbium concentrations of 7.5% and 20% is investigated under laser-diode pumping at 967 nm. Output powers as high as 250 mW and slope efficiencies as high as 24% are obtained. Results are comparable with those of Er3+:LiYF4 under the same pump conditions. Slope efficiencies above 30% are predicted for optimized erbium concentrations.

Kerr-lens mode-locked diode-pumped Cr:LiSGAF laser.

We have demonstrated stable and self-sustaining Kerr-lens mode locking of a Cr:LiSGAF laser pumped by AlGaInP laser diodes. A hard aperture near one end of the laser provides the necessary amplitude modulation. This allsolid- state system generates transform-limited 100-fs pulses, tunable from 810 to 860 nm. The average power at 830 nm is 35 mW, with fluctuations of much less than 1%. The thermal properties of Cr:LiSGAF will permit scaling of these results to higher power.

Fluorescence quantum efficiency measurements in the presence of Auger upconversion by the thermal lens method

Mode-mismatched thermal lens (TL) measurements in Cr3+-doped fluoride crystals (LiSrAIF6 and LiSrGaF6) are reported. A nonlinear increase of the TL signal, and decrease of quantum efficiency, with increasing excitation power was observed and attributed to energy-transfer upconversion (ETU). Assuming an upconversion rate that is proportional to the excited-state population, Wup = gammaN(e), the theoretical model developed fits the experimental data well. The ETU parameters (gamma) were determined with unprecedented accuracy for low Cr concentrations. Thermo-optical parameters (K, ds/dT) were also obtained.

Properties of a new, efficient, blue-emitting material for applications in upconversion displays: Yb, Tm:KY3F10.

The properties of Yb, Tm:KY3F1o, a cubic fluoride crystal, are described that make it attractive as the blue emitter in two-dimensional photonic displays. Its peak excitation wavelength for blue upconversion emission is 974.7 nm, where efficient diode laser pump sources are available. The maximum upconversion efficiency measured thus far is 4.4%.

Thermal quenching of the fluorescence quantum efficiency in colquiriite crystals measured by thermal lens spectrometry

The dual-beam mode-mismatched thermal lens technique was used to study the temperature dependence of the absolute fluorescence quantum efficiency (η) of a thermal-quenching fluorescence (TQF) process in Cr3+-doped colquiriite crystals (LiSAF and LiSGaF), from 300 to 450 K. The research was developed at a low excitation-power level in order to eliminate the energy-transfer upconversion effect. The results showed that TQF is the main loss mechanism involved. The thermal diffusivity, the thermal conductivity, and the specific heat of the samples were also measured in the same temperature range.

Role of pump duration on temperature and efficiency of up-conversion in fluoride crystals co-doped with ytterbium and thulium

Pump pulse duration is shown to determine the maximum efficiency of the up conversion process in ytterbium, thulium co-doped fluoride crystals through its role in determining the emitter temperature reached. We show that up-conversion efficiencies should only be measured when using the same pumping conditions as would be used in a proposed application and that thermal management of the up converting material is critical to optimized performance.

Femtosecond diode-pumped Cr:LiSGAF lasers

The design and performance of diode-pumped Cr:LiSrGaAlF/sub 6/ lasers mode-locked by Kerr-lens mode-locking and a solid-state saturable absorber are described. The different regimes of operation of the laser mode-locked by the saturable absorber are discussed. Both lasers generate 100-fs pulses with average powers of 40 mW and low fluctuations.