Armin Keller

Spatial Differentiation of Arable Land and Permanent Grassland to Improve a Land Management Model for Nutrient Balancing

Agroecosystems play an important role in providing economic and ecosystem services, which directly impact society. Inappropriate land use and unsustainable agricultural management with associated nutrient cycles can jeopardize important soil functions such as food production, livestock feeding, and conservation of biodiversity. The objective of this study was to integrate remotely sensed land cover information into a regional land management model (LMM) to improve the assessment of spatially explicit nutrient balances for agroecosystems. Remotely sensed data and an optimized parameter set contributed to an improved LMM output, allowing for a better land allocation within the model. The best input parameter combination was based on two different land cover classifications with overall accuracies of 98%, improving the land allocation performance compared with using nonspatially explicit input. We conclude that the combined use of remote sensing data and the LMM has the potential to provide valuable guidance for farm practices. It further helps to generate a spatial description of farm-level nutrient balance, a crucial ability when choosing policy options related to sustainable management of agricultural soils.

Polycyclic aromatic hydrocarbons and polychlorinated biphenyls in soils of Mayabeque, Cuba

Cuba is a country in transition with a considerable potential for economic growth. Soils are recipients and integrators of chemical pollution, a frequent negative side effect of increasing industrial activities. Therefore, we established a soil monitoring network to monitor polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in soils of Mayabeque, a Cuban province southeast of Havana. Concentrations of the sum of the 16 US EPA PAHs and of the seven IRMM PCBs in soils from 39 locations ranged from 20 to 106xa0μgxa0kg−1 and from 1.1 to 7.6xa0μgxa0kg−1, respectively. While such concentrations can be considered as low overall, they were in several cases correlated with the distance of sampling sites to presumed major emission sources, with some of the concomitantly investigated source diagnostic PAH ratios, and with black carbon content. The presented data adds to the limited information on soil pollution in the Caribbean region and serves as a reference time point before the onset of a possible further industrial development in Cuba. It also forms the basis to set up and adapt national environmental standards.

Polycyclic aromatic hydrocarbons and polychlorinated biphenyls in urban and semi-urban soils of Havana, Cuba

PurposePolycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in Havana were quantified and analyzed in relation to possible emission sources to assess metropolitan soil contaminations in a highly dynamic, urban environment. The results of this study will serve Cuban legislators as a basis to develop environmental quality standards for organic pollutants in soils.Materials and methodsPossible emission sources as, e.g., the vicinity to roads or industrial plants and the influence of the land use were related to the organic contaminants concentrations. Therefore, 28 topsoils in the Havana urban and semi-urban area were sampled at agricultural (nu2009=u200912), organoponic (urban gardens in the capital, nu2009=u20098), public park (nu2009=u20097), and remediation (on-site bioremediation of an oil refinery, nu2009=u20091) sites. Their PAH and PCB concentrations were measured with gas chromatography mass spectroscopy and the total organic carbon (TOC) and black carbon (BC) concentrations with the chemo-thermal oxidation.Results and discussionThe sum of the 16 PAH concentrations ranged from 0.04xa0mg/kg in agricultural and organoponic soils to up to 72xa0mg/kg in a public park at about 1.5xa0km distance from an oil refinery. The lowest sum of the seven PCB congener concentrations was also measured in organoponic soils (0.002xa0mg/kg) and the highest in an arable patch of land between the rail roads and a main road (0.1xa0mg/kg). Both, PAH as well as PCB soil concentrations in Havana were almost up to two orders of magnitudes higher compared to a soil monitoring in the neighboring province of Mayabeque, but overall in the typical range of urban soils reported by other studies. The pollutants showed no relationship between TOC and BC except for PAHs with BC. For PAHs, combustion was the main source.ConclusionsA comparison of the pollutant concentrations with regulatory guidance values (RGV) of other countries revealed PCB concentrations in Havana soils far below these RGV. In contrast, some concentrations of benzo[a]pyrene, the most carcinogenic PAH, in agricultural and park soils in Havana exceeded some RGV. Thus, some public parks pose a risk according to the Canadian quality guidelines when people have direct contact with these soils but not if they were consuming products thereof.