Arnaud Dapoigny

Quantifying sediment sources in a lowland agricultural catchment pond using (137)Cs activities and radiogenic (87)Sr/(86)Sr ratios.

Soil erosion often supplies high sediment loads to rivers, degrading water quality and contributing to the siltation of reservoirs and lowland river channels. These impacts are exacerbated in agricultural catchments where modifications in land management and agricultural practices were shown to accelerate sediment supply. In this study, sediment sources were identified with a novel tracing approach combining cesium ((137)Cs) and strontium isotopes ((87)Sr/(86)Sr) in the Louroux pond, at the outlet of a lowland cultivated catchment (24km(2), Loire River basin, France) representative of drained agricultural areas of Northwestern Europe. Surface soil (n=36) and subsurface channel bank (n=17) samples were collected to characterize potential sources. Deposited sediment (n=41) was sampled across the entire surface of the pond to examine spatial variation in sediment deposits. In addition, a 1.10m sediment core was sampled in the middle of the pond to reconstruct source variations throughout time. (137)Cs was used to discriminate between surface and subsurface sources, whereas (87)Sr/(86)Sr ratios discriminated between lithological sources. A distribution modeling approach quantified the relative contribution of these sources to the sampled sediment. Results indicate that surface sources contributed to the majority of pond (μ 82%, σ 1%) and core (μ 88%, σ 2%) sediment with elevated subsurface contributions modeled near specific sites close to the banks of the Louroux pond. Contributions of the lithological sources were well mixed in surface sediment across the pond (i.e., carbonate sediment contribution, μ 48%, σ 1% and non-carbonate sediment contribution, μ 52%, σ 3%) although there were significant variations of these source contributions modeled for the sediment core between 1955 and 2013. These fluctuations reflect both the progressive implementation of land consolidation schemes in the catchment and the eutrophication of the pond. This original sediment fingerprinting study demonstrates the potential of combining radionuclide and strontium isotopic geochemistry measurements to quantify sediment sources in cultivated catchments.

Surface ocean pH variations since 1689 CE and recent ocean acidification in the tropical South Pacific

Increasing atmospheric CO2 from man-made climate change is reducing surface ocean pH. Due to limited instrumental measurements and historical pH records in the world’s oceans, seawater pH variability at the decadal and centennial scale remains largely unknown and requires documentation. Here we present evidence of striking secular trends of decreasing pH since the late nineteenth century with pronounced interannual to decadal–interdecadal pH variability in the South Pacific Ocean from 1689 to 2011 CE. High-amplitude oceanic pH changes, likely related to atmospheric CO2 uptake and seawater dissolved inorganic carbon fluctuations, reveal a coupled relationship to sea surface temperature variations and highlight the marked influence of El Niño/Southern Oscillation and Interdecadal Pacific Oscillation. We suggest changing surface winds strength and zonal advection processes as the main drivers responsible for regional pH variability up to 1881 CE, followed by the prominent role of anthropogenic CO2 in accelerating the process of ocean acidification.Ocean acidification due to the industrial era is a major marine environmental concern, yet little is known on the historical ocean pH changes prior to human influence. Here, Wu et al. show that tropical South Pacific seawater pH is linked to ENSO pacing and has recently been decreasing rapidly.

Link between Indian monsoon rainfall and physical erosion in the Himalayan system during the Holocene

Mineralogical and geochemical analyses conducted on cores located on the active channel-levee system of the northern Bengal Fan are used to establish changes in the weathering pattern and the sediment transport of the Himalayan system, and evaluate the effect of Indian summer monsoon rainfall during the Holocene. Our data indicate that during the Holocene, sediments from the northern Bengal Fan originate mainly from the G-B river system without any significant changes in the relative contribution of these rivers. From 9.8 to around 6 ka, relatively low smectite/(illite+chlorite) ratios and relatively high K/Si* ratios indicate high physical denudation rates of the Himalayan highlands together with a rapid transfer of the detrital material to the Bengal Fan. The period between 9.2 and 7 ka is associated to lower values of K/Si* and corresponds to the maximum of Indian monsoon rainfall which indicates a more important chemical weathering material that rapidly transits by the G-B river system without a long storage in the Indo-Gangetic plain. From 6.0 ka to present day, higher smectite/(illite+chlorite) ratio and lower K/Si* ratio document a gradual increase of sediments originated from the Indo-Gangetic plain, characterized by higher degree of chemical weathering. During the last 2.5 ka, the drastic increase in the smectite/(illite+chlorite) ratio could be associated to enhanced alteration of the plain soils due to anthropogenic activity. The comparison of mineralogical and geochemical data with previous reconstructions of the Indian monsoon dynamic indicates a rapid response of erosion and sediment transfer of the G-B river system to changes of monsoon rainfall intensity.