Arnico K. Panday

Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE): Emissions of particulate matter from wood and dung cooking fires, garbage and crop residue burning, brick kilns, and other sources

The Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE) characterized widespread and under-sampled combustion sources common to South Asia, including brick kilns, garbage burning, diesel and gasoline generators, diesel groundwater pumps, idling motorcycles, traditional and modern cooking stoves and fires, crop residue burning, and heating fire. Fuel-based emission factors (EFs; with units of pollutant mass emitted per kilogram of fuel combusted) were determined for fine particulate matter (PM2.5), organic carbon (OC), elemental carbon (EC), inorganic ions, trace metals, and organic species. For the forced-draft zigzag brick kiln, EFPM2.5 ranged from 12 to 19 g kg−1 with major contributions from OC (7 %), sulfate expected to be in the form of sulfuric acid (31.9 %), and other chemicals not measured (e.g., particle-bound water). For the clamp kiln, EFPM2.5 ranged from 8 to 13 g kg −1, with major contributions from OC (63.2 %), sulfate (23.4 %), and ammonium (16 %). Our brick kiln EFPM2.5 values may exceed those previously reported, partly because we sampled emissions at ambient temperature after emission from the stack or kiln allowing some particle-phase OC and sulfate to form from gaseous precursors. The combustion of mixed household garbage under dry conditions had an EFPM2.5 of 7.4± 1.2 g kg−1, whereas damp conditions generated the highest EFPM2.5 of all combustion sources in this study, reaching up to 125± 23 g kg−1. Garbage burning emissions contained triphenylbenzene and relatively high concentrations of heavy metals (Cu, Pb, Sb), making these useful markers of this source. A variety of cooking stoves and fires fueled with dung, hardwood, twigs, and/or other biofuels were studied. The use of dung for cooking and heating produced higher EFPM2.5 than other biofuel sources and consistently emitted more PM2.5 and OC than burning hardwood and/or twigs; this trend was consistent across traditional mud stoves, chimney stoves, and three-stone cooking fires. The comparisons of different cooking stoves and cooking fires revealed the highest PM emissions from threestone cooking fires (7.6–73 g kg−1), followed by traditional mud stoves (5.3–19.7 g kg−1), mud stoves with a chimney for exhaust (3.0–6.8 g kg−1), rocket stoves (1.5–7.2 g kg−1), induced-draft stoves (1.2–5.7 g kg−1), and the bhuse chulo stove (3.2 g kg−1), while biogas had no detectable PM emisPublished by Copernicus Publications on behalf of the European Geosciences Union. 2260 T. Jayarathne et al.: Emissions of particulate matter sions. Idling motorcycle emissions were evaluated before and after routine servicing at a local shop, which decreased EFPM2.5 from 8.8± 1.3 to 0.71± 0.45 g kg −1 when averaged across five motorcycles. Organic species analysis indicated that this reduction in PM2.5 was largely due to a decrease in emission of motor oil, probably from the crankcase. The EF and chemical emissions profiles developed in this study may be used for source apportionment and to update regional emission inventories.

Characterizations of atmospheric particulate-bound mercury in the Kathmandu Valley of Nepal, South Asia

The Kathmandu Valley, located in the Himalayan foothills in Nepal, is heavily polluted. In order to investigate ambient particulate-bound mercury (Hg) in the Kathmandu Valley, a total 64 total suspended particulates (TSP) samples were collected from a sub-urban site in the Kathmandu Valley, the capital region of Nepal during a sampling period of an entire year (April 2013-April 2014). They were analyzed for ambient particulate-bound Hg (PBM) using thermal desorption combined with cold vapor atomic spectroscopy. In our knowledge, it is the first study of ambient PMB in the Kathmandu Valley and the surrounding broader Himalayan foothill region. The average concentration of PBM over the entire sampling period of a year was found to be 850.5 (±962.8) pg m-3 in the Kathmandu Valley. This is comparable to those values reported in the polluted cities of China and significantly higher than those observed in most of urban areas in Asia and other regions of world. The daily average Hg contents in TSP (PBM/TSP) ranges from 269.7 to 7613.0ngg-1 with an average of 2586.0 (±2072.1) ng g-1, indicating the high enrichment of Hg in TSP. The average concentrations of PBM were higher in the winter and pre-monsoon season than in the monsoon and post-monsoon season. The temporal variations in the strength of anthropogenic emission sources combined with other influencing factors, such as ambient temperature and the removal of atmospheric aerosols by wet scavenging are attributable to the seasonal variations of PBM. The considerably high dry deposition flux of PBM estimated by using a theoretical model was 135μgm-2yr-1 at the Kathmandu Valley. This calls for an immediate attention to addressing ambient particulate Hg in the Kathmandu Valley, including considering it as a key component of future air quality monitoring activities and mitigation measures.

Speciated On-line PM 1 from South Asian Combustion Sources: Part I, Fuel-based Emission Factors and Size Distributions

Combustion of biomass, garbage, and fossil fuels in South Asia has led to poor air quality in the region and has uncertain climate forcing impacts. Online measurements of submicron aerosol (PM1) emissions were conducted as part of the Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE) to investigate and report emission factors (EFs) and vacuum aerodynamic diameter (dva) size distributions from prevalent but poorly characterized combustion sources. The online aerosol instrumentation included a “mini” aerosol mass spectrometer (mAMS) and a dual-spot eight-channel aethalometer (AE33). The mAMS measured non-refractory PM1 mass, composition, and size. The AE33-measured black carbon (BC) mass and estimated light absorption at 370 nm due to organic aerosol or brown carbon. Complementary gas-phase measurements of carbon dioxide (CO2), carbon monoxide (CO), and methane (CH4) were collected using a Picarro Inc. cavity ring-down spectrometer (CRDS) to calculate fuel-based EFs using the carbon mass balance approach. The investigated emission sources include open garbage burning, diesel-powered irrigation pumps, idling motorcycles, traditional cookstoves fueled with dung and wood, agricultural residue fires, and coal-fired brick-making kilns, all of which were tested in the field. Open-garbage-burning emissions, which included mixed refuse and segregated plastics, were found to have some of the largest PM1 EFs (3.77–19.8 g kg−1) and the highest variability of the investigated emission sources. Nonrefractory organic aerosol (OA) size distributions measured by the mAMS from garbage-burning emissions were observed to have lognormal mode dva values ranging from 145 to 380 nm. Particle-phase hydrogen chloride (HCl) was observed from open garbage burning and was attributed to the burning of chlorinated plastics. Emissions from two diesel-powered irrigation pumps with different operational ages were tested during NAMaSTE. Organic aerosol and BC were the primary components of the emissions and the OA size distributions were centered at ∼ 80 nm dva. The older pump was observed to have significantly larger EFOA than the newer pump (5.18 g kg−1 compared to 0.45 g kg−1) and similar EFBC. Emissions from two distinct types of coal-fired brick-making kilns were investigated. The less advanced, intermittently fired clamp kiln was observed to Published by Copernicus Publications on behalf of the European Geosciences Union. 14654 J. D. Goetz et al.: PM1 from South Asian combustion sources have relatively large EFs of inorganic aerosol, including sulfate (0.48 g kg−1) and ammonium (0.17 g kg−1), compared to the other investigated emission sources. The clamp kiln was also observed to have the largest absorption Ångström exponent (AAE= 4) and organic carbon (OC) to BC ratio (OC :BC= 52). The continuously fired zigzag kiln was observed to have the largest fraction of sulfate emissions with an EFSO4 of 0.96 g kg −1. Non-refractory aerosol size distributions for the brick kilns were centered at ∼ 400 nm dva. The biomass burning samples were all observed to have significant fractions of OA and non-refractory chloride; based on the size distribution results, the chloride was mostly externally mixed from the OA. The dung-fueled traditional cookstoves were observed to emit ammonium, suggesting that the chloride emissions were partially neutralized. In addition to reporting EFs and size distributions, aerosol optical properties and mass ratios of OC to BC were investigated to make comparisons with other NAMaSTE results (i.e., online photoacoustic extinctiometer (PAX) and off-line filter based) and the existing literature. This work provides critical field measurements of aerosol emissions from important yet undercharacterized combustion sources common to South Asia and the developing world.