Artem Kulachenko

The Link Between the Fiber Contact Zone and the Physical Properties of Paper : A Way to Control Paper Properties

Paper is a composite of fibers, air and additives where the fiber/fiber joints keep the network structure together. A study was undertaken to establish the link between the properties of the contact zone between fibers and paper performance under mechanical loading. The contact zone between fibers was investigated using light microscopy. A staining technique was developed for evaluating the influence of surface charge on fiber/fiber joint strength. The joint strength was linearly correlated with paper tensile strength and with the average amplitude of the acoustic events measured by acoustic emission testing. The fiber surface conformability was improved by changing the surface charge. This resulted in increased fiber/fiber joint strength as the relative contact area became larger. Increasing the molecular adhesion in the contact zone with the aid of strength additives also improved the fiber/fiber joint strength.

Fiber/Fiber Crosses: Finite Element Modeling and Comparison with Experiment

Fiber/fiber joints were analyzed using finite element analysis in order to characterize the influence of fiber and contact region properties on the stress— strain behavior of a single fiber/fiber cross. The output of the models was validated by comparison with experimental load—deformation curves. The contact zone of the fiber/fiber joint was studied with respect to the appearance of the contact zone, the contact area, and the contact pattern; the work of adhesion of the contact areas was also considered. It was shown that the two-dimensional appearance of the contact zone had little influence on the stress—strain behavior of the fiber/fiber cross under tensile loading. The maximum stress and hence the fiber/fiber joint strength was, however, affected by the degree of contact. It was concluded that knowledge of the material behavior of the contact zone (such as local plastic behavior), and of chemical effects (such as work of adhesion) are needed to predict the fiber/fiber joint strength.

Finite-strain, finite-size mechanics of rigidly cross-linked biopolymer networks

The network geometries of rigidly cross-linked fibrin and collagen type I networks are imaged using confocal microscopy and characterized statistically. This statistical representation allows for the regeneration of large, three-dimensional biopolymer networks using an inverse method. Finite element analyses with beam networks are then used to investigate the large deformation, nonlinear elastic response of these artificial networks in isotropic stretching and simple shear. For simple shear, we investigate the differential bulk modulus, which displays three regimes: a linear elastic regime dominated by filament bending, a regime of strain-stiffening associated with a transition from filament bending to stretching, and a regime of weaker strain-stiffening at large deformations, governed by filament stretching convolved with the geometrical nonlinearity of the simple shear strain tensor. The differential bulk modulus exhibits a corresponding strain-stiffening, but reaches a distinct plateau at about 5% strain under isotropic stretch conditions. The small-strain moduli, the bulk modulus in particular, show a significant size-dependence up to a network size of about 100 mesh sizes. The large-strain differential shear modulus and bulk modulus show very little size-dependence.

Mechanosorptive creep in nanocellulose materials

The creep behavior of nanocellulose films and aerogels are studied in a dynamic moisture environment, which is crucial to their performance in packaging applications. For these materials, the creep rate under cyclic humidity conditions exceeds any constant humidity creep rate within the cycling range, a phenomenon known as mechanosorptive creep. By varying the sample thickness and relative humidity ramp rate, it is shown that mechanosorptive creep is not significantly affected by the through-thickness moisture gradient. It is also shown that cellulose nanofibril aerogels with high porosity display the same accelerated creep as films. Microstructures larger than the fibril diameter thus appear to be of secondary importance to mechanosorptive creep in nanocellulose materials, suggesting that the governing mechanism is found between molecular scales and the length-scales of the fibril diameter.

Modelling of cross-linked actin networks - Influence of geometrical parameters and cross-link compliance

A major structural component of the cell is the actin cytoskeleton, in which actin subunits are polymerised into actin filaments. These networks can be cross-linked by various types of ABPs (Actin Binding Proteins), such as Filamin A. In this paper, the passive response of cross-linked actin filament networks is evaluated, by use of a numerical and continuum network model. For the numerical model, the influence of filament length, statistical dispersion, cross-link compliance (including that representative of Filamin A) and boundary conditions on the mechanical response is evaluated and compared to experimental results. It is found that the introduction of statistical dispersion of filament lengths has a significant influence on the computed results, reducing the network stiffness by several orders of magnitude. Actin networks have previously been shown to have a characteristic transition from an initial bending-dominated to a stretching-dominated regime at larger strains, and the cross-link compliance is shown to shift this transition. The continuum network model, a modified eight-chain polymer model, is evaluated and shown to predict experimental results reasonably well, although a single set of parameters cannot be found to predict the characteristic dependence of filament length for different types of cross-links. Given the vast diversity of cross-linking proteins, the dependence of mechanical response on cross-link compliance signifies the importance of incorporating it properly in models to understand the roles of different types of actin networks and their respective tasks in the cell.

Material properties of the cell walls in nanofibrillar cellulose foams from finite element modelling of tomography scans

The mechanical properties of the nanofibrillar cellulose foam depend on the microstructure of the foam and on the constituent solid properties. The latter are hard to extract experimentally due to difficulties in performing the experiments on the micro-scale. The aim of this work is to provide methodology for doing it indirectly using extracted geometry of the microstructure. X-ray computed tomography scans are used to reconstruct the microstructure of a nanofibrillar cellulose foam sample. By varying the levels of thresholding, structure of differing porosities of the same foam structure are obtained and their macroscopic properties of the uni-axial compression are computed by finite element simulations. A power law relation, equivalent to classical foam scaling laws, are fit to the data obtained from simulation at different relative densities for the same structure. The relation thus obtained, is used to determine the cell wall material properties, viz. elastic modulus and yield strength, by extrapolating it to the experimental porosity and using the measured response at this porosity. The simulations also provide qualitative insights into the nature of irreversible deformations, not only corroborating the experimental results, but also providing possible explanation to the mechanisms responsible for crushable behaviour of the nanofibrillar cellulose foams in compression.

Extracting fiber and network connectivity data using microtomography images of paper

We apply image analysis methods based on micro-computed tomography (μCT) to extract the parameters that characterize the structure and bonding parameters in the fiber network of paper. The scaling ...

A three-dimensional numerical model for large strain compression of nanofibrillar cellulose foams

Abstract We investigate the suitability of three-dimensional Voronoi structures in representing a large strain macroscopic compressive response of nanofibrillar cellulose foams and understanding the connection between the features of the response and details of the microstructure. We utilise Lloyd’s algorithm to generate centroidal tessellations to relax the Voronoi structures and have reduced polydispersity. We begin by validating these structures against simulations of structures recreated from microtomography scans. We show that by controlling the cell face curvature, it is possible to match the compressive response for a 96.02 % porous structure. For the structures of higher porosity (98.41 %), the compressive response can only be matched up to strain levels of 0.4 with the densification stresses being overestimated. We then ascertain the representative volume element (RVE) size based on the measures of relative elastic modulus and relative yield strength. The effects of cell face curvature and partially closed cells on the elastic modulus and plateau stress is then estimated. Finally, the large strain response is compared against the two-dimensional Voronoi model and available experimental data for NFC foams. The results show that compared to the two-dimensional model, the three-dimensional analysis provides a stiffer response at a given porosity due to earlier self-contact.

Effect of some printing nip variables on web tension

Good runnability of paper web is an important factor for improving performance of printing process. Printing nips cause web tension variations which are known to affect web runnability. However, ra ...

Cross-link debonding in actin networks : influence on mechanical properties

The actin cytoskeleton is essential for the continued function and survival of the cell. A peculiar mechanical characteristic of actin networks is their remodelling ability, providing them with a time-dependent response to mechanical forces. In cross-linked actin networks, this behaviour is typically tuned by the binding affinity of the cross-link. We propose that the debonding of a cross-link between filaments can be modelled using a stochastic approach, in which the activation energy for a bond is modified by a term to account for mechanical strain energy. By use of a finite element model, we perform numerical analyses in which we first compare the model behaviour to experimental results. The computed and experimental results are in good agreement for short time scales, but over longer time scales the stress is overestimated. However, it does provide a possible explanation for experimentally observed strain-rate dependence as well as strain-softening at longer time scales.