Aurélie Colomb

Screening volatile organic compounds (VOCs) emissions from five marine phytoplankton species by head space gas chromatography/mass spectrometry (HS-GC/MS)

Five marine cosmopolitan phytoplankton species namely; Calcidiscus leptoporus, Emiliania huxleyi, Phaeodactylum tricornutum, Chaetoceros neogracilis and Dunaliella tertiolecta were screened for emissions of selected VOCs using head space gas chromatography/mass spectrometry (HS-GC/MS) in single ion mode. The VOCs investigated included isoprene and various halogenated compounds. Among the different algae groups, the two diatoms Ch. neogracilis and P. tricornutum were the strongest emitters of methyl bromide (CH3Br), and Ch. neogracilis was the strongest emitter of isoprene. Furthermore, we present evidence that several chlorinated organic compounds, normally considered as anthropogenic, can be produced from marine phytoplankton (namely chloroform, dichloromethane, trichloroethylene, tetrachloroethylene, chlorobenzene and dichlorobenzene).

Airborne Measurements of Trace Organic Species in the Upper Troposphere Over Europe: the Impact of Deep Convection

Environmental Context. In the upper troposphere, sources of HOx such as acetone, peroxides, and aldehydes can play an important role in governing the production and destruction of ozone. Convection (over both land and sea) carries gases that can contribute to increased levels of HOx to the upper troposphere. The chemical impact of convection on the continental upper troposphere over Europe is studied by sampling the upper troposphere. Mass spectrometry techniques are used to analyze the collected samples. Such a study should aid in understanding the impact meteorological events have on atmospheric chemistry. Abstract. The volume mixing ratios of several organic trace gases and ozone (O3) were measured in the upper troposphere over Europe during the UTOPIHAN-ACT aircraft campaign in July 2003. The organic trace gases included alkanes, isoprene, aromatics, iodomethane, and trichloroethylene, oxygenates such as acetone, methanol, formaldehyde, carbon monoxide, and longer-lived tracer species such as chlorofluorocarbons and halochloroflurocarbons. The aim of the UTOPIHAN-ACT project was to study the chemical impact of deep convection on the continental upper troposphere. A Lear Jet aircraft, based in Germany, was flown at heights between 6 and 13 km in the region 59°N–42°N to 7°W–13°E during July 2003. Overall, the convectively influenced measurements presented here show a weaker variability lifetime dependence of trace gases than similar measurements collected over the Mediterranean region under more stable high-pressure conditions. Several cases of convective outflow are identified by the elevated mixing ratios of organic species relative to quiescent background conditions, with both biogenic and anthropogenic influences detectable in the upper troposphere. Enhancement at higher altitudes, notably of species with relatively short chemical lifetimes such as benzene, toluene, and even isoprene indicates deep convection over short timescales during summertime. The impact of deep convection on the local upper tropospheric formaldehyde and HOx budgets is assessed.

Variation of atmospheric volatile organic compounds over the Southern Indian Ocean (30°S-49°S)

Environmental context. Oceans represent 70% of the blue planet, and surprisingly, ocean emission in term of volatile organic compounds is poorly understood. The potential climate impacts on a global scale of various trace organic gases have been established, and the terrestrial inputs are well studied, but little is known about which of these can be emitted from oceanic sources. In the present study, atmospheric samples were taken over the Southern Indian Ocean, while crossing some oceanic fronts and different phytoplankton species. Such a study should aid in understanding oceanic emission, especially from phytoplankton, and will help modellers to determine concentrations of organic traces in the remote marine troposphere. Abstract. Considering its size and potential importance, the ocean is poorly characterised in terms of volatile organic compounds (VOC) that play important roles in global atmospheric chemistry. In order to better understand their potential sources and sinks over the Southern Indian Austral Ocean, shipborne measurements of selected species were made during the MANCHOT campaign during December 2004, on board the research vessel Marion Dufresne. Along the transect La Reunion to Kerguelen Island, air measurements of selected VOC (including dimethylsulfide (DMS) isoprene, carbonyls and organohalogens), carbon monoxide and ozone were performed, crossing subtropical, temperate and sub-Antarctic waters as well as pronounced subtropical and sub-Antarctic oceanic fronts. The remote marine boundary layer was characterised at latitudes 45–50°S. Oceanic fronts were associated with enhanced chlorophyll and biological activity in the seawater and elevated DMS and organohalogens in the atmosphere. These were compared with a satellite-derived phytoplankton distribution (PHYSAT). Diurnal variation for isoprene, terpenes, acetone and acetaldehyde was observed, analogously to recent results observed in mesocosm experiments.

Assessing the effect of marine isoprene and ship emissions on ozone, using modelling and measurements from the South Atlantic Ocean

Environmental context. Air over the remote Southern Atlantic Ocean is amongst the cleanest anywhere on the planet. Yet in summer a large-scale natural phytoplankton bloom emits numerous natural reactive compounds into the overlying air. The productive waters also support a large squid fishing fleet, which emits significant amounts of NO and NO2. The combination of these natural and man-made emissions can efficiently produce ozone, an important atmospheric oxidant. Abstract. Ship-borne measurements have been made in air over the remote South Atlantic and Southern Oceans in January–March 2007. This cruise encountered a large-scale natural phytoplankton bloom emitting reactive hydrocarbons (e.g. isoprene); and a high seas squid fishing fleet emitting NOx (NO and NO2). Using an atmospheric chemistry box model constrained by in-situ measurements, it is shown that enhanced ozone production ensues from such juxtaposed marine biogenic and anthropogenic emissions. The relative impact of shipping and phytoplankton emissions on ozone was examined on a global scale using the EMAC model. Ozone in the marine boundary layer was found to be over ten times more sensitive to NOx emissions from ships, than to marine isoprene in the region south of 45°. Although marine isoprene emissions make little impact on the global ozone budget, co-located ship and phytoplankton emissions may explain the increasing ozone reported for the 40–60°S southern Atlantic region.

The Dynamics–Aerosol–Chemistry–Cloud Interactions in West Africa Field Campaign: Overview and Research Highlights

Unprecedented ground-based and aircraft measurements in June-July 2016 in southern West Africa characterize atmospheric composition and dynamics, low-level cloud properties, the diurnal cycle, and air pollution impacts on health. The EU-funded project DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) investigates the relationship between weather, climate, and air pollution in southern West Africa, an area with rapid population growth, urbanisation, and increase in anthropogenic aerosol emissions. The air over this region contains a unique mixture of natural and anthropogenic gases, liquid droplets and particles, emitted in an environment, in which multi-layer clouds frequently form. These exert a large influence on the local weather and climate, mainly due to their impact on radiation, the surface energy balance, and thus the diurnal cycle of the atmospheric boundary layer. In June and July 2016, DACCIWA organized a major international field campaign in Ivory Coast, Ghana, Togo, Benin, and Nigeria. Three supersites in Kumasi, Save, and Ile-Ife conducted permanent measurements and 15 Intensive observation periods. Three European aircraft together flew 50 research flights between 27 June and 16 July 2016 for a total of 155 hours. DACCIWA scientists launched weather balloons several times a day across the region (772 in total), measured urban emissions, and evaluated health data. The main objective was to build robust statistics of atmospheric composition, dynamics, and low-level cloud properties in various chemical landscapes to investigate their mutual interactions. This article presents an overview of the DACCIWA field campaign activities as well as some first research highlights. The rich data obtained during the campaign will be made available to the scientific community and help to advance scientific understanding, modeling, and monitoring the atmosphere over southern West Africa.

NitroMAC: An instrument for the measurement of HONO and intercomparison with a long-path absorption photometer

NitroMAC (French acronym for continuous atmospheric measurements of nitrogenous compounds) is an instrument which has been developed for the semi-continuous measurement of atmospheric nitrous acid (HONO). This instrument relies on wet chemical sampling and detection using high performance liquid chromatography (HPLC)-visible absorption at 540 nm. Sampling proceeds by dissolution of gaseous HONO in a phosphate buffer solution followed by derivatization with sulfanilamide/N-(1-naphthyl)-ethylenediamine. The performance of this instrument was found to be as follows: a detection limit of around 3 ppt with measurement uncertainty of 10% over an analysis time of 10 min. Intercomparison was made between the instrument and a long-path absorption photometer (LOPAP) during two experiments in different environments. First, air was sampled in a smog chamber with concentrations up to 18 ppb of nitrous acid. NitroMAC and LOPAP measurements showed very good agreement. Then, in a second experiment, ambient air with HONO concentrations below 250 ppt was sampled. While NitroMAC showed its capability of measuring HONO in moderate and highly polluted environments, the intercomparison results in ambient air highlighted that corrections must be made for minor interferences when low concentrations are measured.

Case Study and Climatological Analysis of Upper-Tropospheric Jet Stream and Stratosphere–Troposphere Exchanges Using VHF Profilers and Radionuclide Measurements in France

AbstractThe authors present a climatological analysis of tropospheric horizontal wind profiles and jet stream events using long series of wind profiles from two VHF profilers located in France: Lannemezan (2001–14) and Opme (1999–2014). A case study of jet stream and stratospheric intrusion of air into the troposphere that occurred in January 2013 is first described and demonstrates the capability of the VHF profilers to detect jet stream events. The climatology study over the two sites reveals the strongest values of seasonal wind during winter (21.4 m s−1 at 8.7-km height at Opme; 25.1 m s−1 at 9.6-km height at Lannemezan). A methodology based on the automatic detection of maximum winds on a decadal series of hourly wind profiles allows the detection of jet stream events and establishes its climatology for each site. A frequency analysis of jet stream events of westerly winds over 50 m s−1 presents a clear seasonality at the two sites, with a maximum in winter (3.5%–9.7% of hourly profiles) and a minimu...

The influence of synoptic circulations and local processes on temperature anomalies at three French observatories.

The relative contribution of the synoptic-scale circulations to local and mesoscale processes was quantified in terms of the variability of middle latitude temperature anomalies from 2003 to 2013 using meteorological variables collected from three French observatories and reanalyses. Four weather regimes were defined from sea level pressure anomalies using National Center for Environmental Prediction (NCEP) reanalyses with a K-means algorithm. No correlation was found between daily temperature anomalies and weather regimes, and the variability of temperature anomalies within each regime was large. It was therefore not possible to evaluate the effect of large scales on temperature anomalies by this method. An alternative approach was found with the use of the analogues method: the principle being that for each day of the considered time series, a set of days which had a similar large-scale 500 hPa geopotential height field within a fixed domain were considered. The observed temperature anomalies were then compared to those observed during the analogue days: the closer the two types of series, the greater the mark of the large scale. This method highlights a widely predominant influence of the large-scale atmospheric circulation on the temperature anomalies. It showed a potentially larger influence of the Mediterranean Sea and orographic flow on the two southern observatories. Low-level cloud radiative effects substantially modulated the variability of the daily temperature anomalies.

Regional Modeling of Aerosol Chemical Composition at the Puy de Dôme (France)

Organic aerosols (OA) represent a large fraction (from 20 to 90 %) of the submicron particulate mass and it is mainly composed of secondary organic aerosols (SOA). Despite the ubiquity of OA in the atmosphere, there are still large uncertainties in understanding the formation pathways of SOA. Consequently, OA sources and physico-chemical transformations during their transport are poorly represented in chemistry-transport models and large gaps still remain between simulated and measured OA concentrations. The ability of the WRF-CHEM model to reproduce the organic aerosol mass concentration originated from anthropogenic or/and biogenic emissions is evaluated. From this perspective, simulations for two contrasted air masses are performed with WFR-Chem using the Volatility Basis Set (VBS) approach dedicated to the formation of SOA. Simulations results are compared to aerosol measurements performed at the puy de Dome station with a compact Time-of-Flight Aerosol Mass Spectrometer for two episodes in autumn 2008 and in summer 2010. Moreover, measurements of both anthropogenic and biogenic VOCs are used to access the capacity of the WRF-Chem model to correctly simulate the concentrations levels of the gas precursors of the SOA.