Avery P. Yuen

A simple parallel tandem organic solar cell based on metallophthalocyanines

A simple parallel tandem solar cell based on a combination of Zn-phthalocyanine (Pc) and ClInPc has been fabricated and characterized. Compared to a traditional series tandem cell, parallel tandem cells eliminate the need for a semitransparent recombination layer, reducing the complexity of device fabrication while still providing an excellent increase in device performance. Results show a realized broadening of the spectral response and enhancement of the external quantum efficiency as a result of the complementary absorption profiles of ZnPc and ClInPc in the near infrared region. Introduction of a blended ClInPc:C60 layer is shown to more than double the power conversion efficiency of a standard ZnPc/C60 bilayer device (PCE=0.86%). The enhanced performance of the parallel tandem (PCE=1.81%) arises from an increase in both the open circuit voltage and the short circuit current.

Blend composition study of poly(3,3‴-didodecylquaterthiophene)/[6,6]-phenyl C61 butyric acid methyl ester solution processed organic solar cells

Photovoltaic devices made from blends of poly(3,3‴-didodecylquaterthiophene) (PQT-12) and [6,6]-phenyl C61 butyric acid methyl ester have been fabricated and characterized. By varying the polymer loading in the blend, an optimal power conversion efficiency (PCE) of 0.70% has been achieved for a blend consisting of 15 wt % PQT-12, which is an order of magnitude higher than the PCE for a 50 wt % blend. The apparent reason for the large difference is the fact that blends with higher PQT-12 loading are transport limited, with much larger hole-to-electron mobility ratios.