Awni T. Batayneh

Status of trace metals in surface seawater of the Gulf of Aqaba, Saudi Arabia

The Gulf of Aqaba (GoA) is of significant ecological value with unique ecosystems that host one of the most diverse coral communities in the world. However, these marine environments and biodiversity have been threatened by growing human activities. We investigated the levels and distributions of trace metals in surface seawater across the eastern coast of the Saudi GoA. Zn, Cu, Fe, B and Se in addition to total dissolved solids and seawater temperature exhibited decreasing trends northwards. While Mn, Cd, As and Pb showed higher average levels in the northern GoA. Metal input in waters is dependent on the adjacent geologic materials. The spatial variability of metals in water is also related to wave action, prevailing wind direction, and atmospheric dry deposition from adjacent arid lands. Also, water discharged from thermal desalination plants, mineral dust from fertilizer and cement factories are potential contributors of metals to seawater water, particularly, in the northern GoA.

Hydrochemical Facies and Ionic Ratios of the Coastal Groundwater Aquifer of Saudi Gulf of Aqaba: Implication for Seawater Intrusion

ABSTRACT Batayneh, A.; Zaman, H.; Zumlot, T.; Ghrefat, H.; Mogren, S.; Nazzal, Y.; Elawadi, E.; Qaisy, S.; Bahkaly, I., and Al-Taani, A., 2014. Hydrochemical facies and ionic ratios of the coastal groundwater aquifer of Saudi Gulf of Aqaba: implication for seawater intrusion. It is now fairly documented that major ion chemistry of the groundwater can be used to determine an interaction between the groundwater and saline water in the costal aquifers, and that there exists a relationship between total dissolved solids and Cl−, Na+, Mg2+, and concentrations of groundwater. This hypothesis is tested on an aquifer located along the Saudi Gulf of Aqaba coast (Red Sea). Groundwater samples collected from 23 locations show the abundance of ions in the order of: Ca2+ > Na+ > Mg2+ > K+ = Cl− > > > . The Piper trilinear diagram reveals two dominant clusters, i.e. the Ca2+–Cl−– facies and the Na+–Cl−– facies. Besides the major chemical compositions, ionic ratios ( /Cl−, Na+/Ca2+, Na+/Cl−, Ca2+/Cl−, Mg2+/Cl−, K+/Cl−, /Cl−, Ca2+/Mg2+, Ca2+/ , and Ca2+/ ) are used to evaluate the effects of saline water intrusions. Factor analysis of the studied samples demonstrates that changes in the groundwater composition are primarily controlled by mineral dissolution, human activities, weathering of marine sediments, evaporation/salinization of groundwater, and the residence time of water. An attempt has been made to identify hydrochemical processes accompanied with the current intrusion of seawater through the use of ionic exchanges. Following this procedure, about 7.97% mixing rate of seawater intrusion has been estimated for the month of March 2012. Furthermore, the seawater mixing index has also been applied, which resulted in a range of values from 0.395 to 7.922. These results determine 13 of 23 groundwater samples (57%) as saline, with electrical conductivity > 3000 μS/cm.

Evaluating the potential of sediments in Ziqlab Reservoir (northwest Jordan) for soil replacement and amendment

Abstract Surface sediments of Ziqlab Reservoir, northwest Jordan, were evaluated to characterize trace element distributions and sources related to various physicochemical variables. Trace element distribution is determined by texture, parent material in the catchment, and anthropogenic activities. The suitability of reservoir sediment for replacing or amending soil was assessed by comparing sediment characteristics to natural soils. Results suggest that the sandy facies can be used as artificial soils, whereas clayey facies can be utilized as fertilizer for poor quality soils in Jordan. The fine-grained sediment fraction is associated with (1) high abundance of clay minerals with high cation exchange capacity and available micronutrients; (2) occurrence of kaolinite, montmorillonite–illite, vermiculite, and smectite; and (3) optimal pH values for availability of most micronutrients. Among the trace elements measured, total nickel and cadmium slightly exceeded recommended safe levels for soils, but the high concentrations may decline when sediments are exposed to air. If removal of the bottom sediments of Ziqlab Reservoir becomes economically feasible, it would extend the reservoir lifespan, improve water quality, compensate for soil scarcity in some regions, and enhance soil productivity.

Use of Geoelectrical Technique for Detecting Subsurface Fresh and Saline Water: A Case Study of the Eastern Gulf of Aqaba Coastal Aquifer, Jordan

Abstract Geoelectrical measurements using the vertical electrical sounding method were conducted on the eastern Gulf of Aqaba (GOA) coast in Jordan. The objectives of the study were (i) to map the Quaternary sediments in areas where little is known about the subsurface geology and to infer shallow geological structure, and (ii) to identify formations that may present fresh aquifer waters, and subsequently to estimate the relationship between groundwater resources and geological structures. Data collected at 47 locations were interpreted first with curve-matching techniques, using theoretically calculated master curves. The initial earth models were double-checked and reinterpreted using a one-dimensional inversion program in order to obtain final earth models. Resistivity measurements show three zones with different resistivity values, corresponding to three different bearing formations: (i) a water-bearing formation in the west containing GOA saltwater; (ii) a transition zone of alternate layers of silt, sand, clay, and clayey sand; and (iii) strata saturated with fresh groundwater in the east and disturbed by the presence of clay and clayey sand horizons.

Environmental Assessment of the Gulf of Aqaba Coastal Surface Waters, Saudi Arabia

ABSTRACT Batayneh, A.; Elawade, E.; Zaman, H.; Al-Taani, A.A.; Nazzal, Y., and Ghrefat, H., 2014. Environmental assessment of the Gulf of Aqaba coastal surface waters, Saudi Arabia. A research project on the Saudi Gulf of Aqaba was initiated in January 2012 to evaluate, protect, and develop a proper management plan for sustainable use of water resources in the coastal region. Within the framework of this project, a total of 85 surface water samples was collected and investigated to document the surface distribution of the hydrographical parameters (including water temperature, salinity, density, hydrogen ion concentration, and dissolved oxygen) as well as concentration of the nutrient salts (ammonium, nitrite, nitrate, phosphate, and silicate). The results show no thermocline or thermal pollution in the studied water and that they are mostly well oxygenated. In addition, no significant variations in the pH and salinity values have been observed. Relatively low levels of nitrogen, phosphorus (in the dissolved and total forms), and reactive silicate are observed. Inorganic nitrogen is found in the order of NO3-N > NO2-N > NH4-N. On the basis of the relatively low level of nutrient salts, the Gulf of Aqaba coastal water is classified as oligotrophic to mesotrophic in nature, and the study area is not yet seriously affected by contamination in spite of rapid population growth and fast infrastructural/recreational development during the past decade.

Integrated resistivity and water chemistry for evaluation of groundwater quality of the Gulf of Aqaba coastal area in Saudi Arabia

The most productive lands in the coastal area of Saudi Gulf of Aqaba lie in Wadi Humeidah, where irrigation relies predominantly on groundwater. Crop yields have been lately reduced due to increased salinity of groundwater and have led to abandonment of some wells adjacent to the Gulf area. Geophysical and geochemical investigations were combined to assess seawater-contaminated zones in the shallow coastal groundwater aquifer and to identify subsurface geologic formation. The prevalence of Ca2+, Na+, Cl– and SO42– suggests that weathering of surrounding rocks is potentially the major source of ions. Characterization of aquifer conditions up to a depth of 60 m showed that the groundwater aquifer is composed of three zones with vertically different resistivity values. The surface layer with resistivity of 30–1000 ohm-m, represents the alluvial sand and gravel. The second layer with lower resistivity values ranging from 0.6 to 70 ohm-m, indicates saline-to-brackish-to-slightly fresh water saturated rocks. The third layer extending up to a depth of 60 m is dominated by resistivity values of several hundred to several thousand ohm-meters, reflecting the basement rocks. While the groundwater is generally brackish, the salinity content varied spatially with TDS values that decreased in the northeast direction. The variations in TDS are related to multiple sources and primarily dependent on dissolution of saltbearing sediments, exploitation rate, over-irrigation with salty water, aquifer-bearing strata and the location of wells. Groundwater aquifers in the vicinity of the coastline were found to have been impacted by saline water. The central east area has a type of groundwater that is relatively less brackish.

A combined hydrochemical-statistical analysis of Saq aquifer, northwestern part of the Kingdom of Saudi Arabia

The present study includes detailed hydrochemical assessment of groundwater resources of Saq aquifer. The Saq aquifer covers a large area (about 375,000 km2) and lies in the arid region with low annual rainfall and extremely high evaporation. In the study area, groundwater serves as the major source for agricultural activity and for domestic usages. A total of 295 groundwater samples collected and were analyzed for physico-chemical parameters such as hydrogen ion concentration (pH), total dissolved solids (TDS) and electrical conductivity (EC), sodium (Na+), potassium (K+), magnesium (Mg2+), and calcium (Ca2+), bicarbonate (HCO3) chloride (Cl−), sulfate (SO42−) and nitrate (NO3). The goal and challenge for the statistical overview was to delineate chemical distributions in a complex, heterogeneous set of data spanning over a large geographic range. After de-clustering to create a uniform spatial sample distribution with 295 samples, histograms and quantile-quantile (Q-Q) plots were employed to delineate subpopulations that have coherent chemical affinities. The elements showing significantly higher positive correlation are: TDS with EC; Ca with EC, TDS; Mg and EC, TDS, Ca, K; Cl and EC, TDS, Mg, Na, Ca; SO4 and EC, TDS, Ca, Cl, Na, Mg. The distribution of major ions in the groundwater is Na+ > Ca++ > Mg++ > K+ and Cl− > SO4−2>HCO3−>NO3−. Ionic abundance plot of alkalis with Ca and Mg is suggestive of mix type trends of concentrations as evident by moderate correlation (r = 0.57). About 60% of the total samples have alkalis abundance and rests have more Ca + Mg concentrations than alkalis. Taking both results of cluster tree and geochemical features of variables into consideration, the authors classify the elements into two major groups, the first includes TDS, Na, EC, Cl, Ca, SO4, and Mg, where the relationship within the group are strong. The second group includes K, HCO3, pH, and NO3. This group has close relationship with group 1 demonstrate that, the increase in the concentration to some elements could be the same. Some of the analyzed parameters approach a normal distribution, as both their skewnesses and kurtoses reach close to “0”. The study revealed that, all of the element pairs exhibit positive relations.

Major ion chemistry and weathering processes in the Midyan Basin, northwestern Saudi Arabia

Chemical characteristics of 72 groundwater samples collected from Midyan Basin have been studied to evaluate major ion chemistry together with the geochemical and weathering processes controlling the water composition. Water chemistry of the study area is mainly dominated by Na, Ca, SO4, and Cl. The molar ratios of (Ca + Mg)/total cations, (Na + K)/total cations, (Ca + Mg)/(Na + K), (Ca + Mg)/(HCO3 + SO4), (Ca + Mg)/HCO3, and Na/Cl reveal that water chemistry of the Midyan Basin is controlled by evaporite dissolution (gypsum and/or anhydrite, and halite), silicate weathering, and minor contribution of carbonate weathering. The studied groundwater samples are largely undersaturated with respect to dolomite, gypsum, and anhydrite. These waters are capable of dissolving more of these minerals under suitable physicochemical conditions.

Structural interpretation of the Ifal Basin in north-western Saudi Arabia from aeromagnetic data: hydrogeological and environmental implications

The Ifal (Midyan) Basin is one of the well defined basins along the Red Sea coast, north-western Saudi Arabia. Location, geometry, thick sedimentary cover and structural framework qualify this basin for groundwater, oil and mineral occurrences. In spite of being studied by two airborne magnetic surveys during 1962 and 1983, structural interpretation of the area from a magnetic perspective, and its uses for hydrogeological and environmental investigations, has not been attempted. This work thus presents interpretation of the aeromagnetic data for basement depth estimation and tectonic framework delineation, which both have a role in controlling groundwater flow and accumulation in the Ifal Basin. A maximum depth of 3.5 km is estimated for the basement surface by this study. In addition, several faulted and tilted blocks, perpendicularly dissected by NE-trending faults, are delineated within the structural framework of the study area. It is also observed that the studied basin is bounded by NW- and NE-trending faults. All these multi-directional faults/fracture systems in the Ifal Basin could be considered as conduits for groundwater accumulation, but with a possibility of environmental contamination from the surrounding soils and rock bodies.

Lineament characterization and their tectonic significance using gravity data and field studies in the Al-Jufr area, southeastern Jordan plateau

Lineaments in the southeastern Jordan plateau are mapped using gravity data and field studies in order to understand the tectonic origin of these lineaments, especially in relation to the Dead Sea transform (DST) and the Red Sea opening. Four sets trending E-W, NW-SE, NE-SW, and N-S are identified in gravity data. Field studies generally reveal similar orientations. Field and gravity studies indicate that most of the lineaments are extensional features that correspond to normal faults. Most of these were subsequently reactivated into strike-slip shear fractures. The NW-SE and N-S lineaments represent dilatational fractures. The N-S trending lineaments are the oldest. The E-W lineaments form conjugate shear fractures and are younger than the N-S lineaments. These conjugate shear fractures are also older than other set of conjugate shear fractures oriented NE-SW. The evolution of all these fractures is attributed to the DST and the Red Sea spreading. Kinematic and dynamic analysis of the two, older and younger, pairs of conjugate strike-slip fractures revealed, respectively, broadly NW-SE and N-S oriented transpressional stress (σ1) with corresponding transtensional stress (σ3) oriented NE-SW and E-W.