Ayman Bassil

Controlled laser heating of carbon nanotubes

We investigate laser heating of double wall carbon nanotubes deposited on surfaces and immerged in liquids as a function of laser wavelength. Observing the Raman spectrum we find that laser heating of agglomerated double wall carbon nanotubes is six times larger at 488nm than at 647nm. The wavelength dependence of the Raman G band is linear in the visible spectral range. The frequency shift of the Raman G band obtained in methanol as a function of temperature is close to what is observed for graphite.

Spectroscopic detection of carbon nanotube interaction with amphiphilic molecules in epoxy resin composites

Incorporation of carbon nanotubes into epoxy resin composites has the effect of increasing electrical conductivity at low percolation levels. An amphiphilic molecule such as palmitic acid has been used to increase the surface contact area and to improve the dispersion of the carbon nanotube bundles in the prepolymer. The chemical environment of the dispersed nanotubes has been probed using vibrational Raman spectroscopy. Spectroscopic Raman maps on sample surfaces (60×60μm2) with ratios of nanotubes to palmitic acid varying from 1:2 to 2:1 by weight, have been recorded to test the uniformity of the dispersion. Substantial spatial inhomogeneities have been observed in the G-band shift and an additional spectral band at 1450cm−1. The 1450cm−1 band has been attributed to the CH3 group of the amphiphilic molecules adsorbed onto the nanotube surface. The maps are correlated with the measured electrical conductivity values. The highest conductivity has been observed for the best dispersed nanotubes and nanotube...

Laser Induced Modifications of Carbon Nanotube Composite Surfaces

Carbon nanotubes epoxy composites have been processed with high power laser pulses and micro-machined with a single crystal diamond tool. The effect of the dispersion of the carbon nanotubes (CNTs, 0.4 wt %) in the epoxy resin and carbon nanotube interaction with the composite matrix have been probed using spectroscopic Raman mapping. While the micro-machined surface maintains a good electrical conductivity after machining, the surface is poorly conductive after laser ablation. Laser processing (power 150 J/pulse, 1064 nm) transforms the surface of the carbon nanotube nanocomposite up to a distance of 25 µm. AFM images show that the diamond machined surface reduces the composite surface roughness.

Enhanced Raman signal of CH 3 on carbon nanotubes

ABSTRACTWe find that functionalized SWCNT and DWCNTs (mainly double wall carbon nanotubes) in composites, DWCNTs under hydrostatic pressure and blue illuminated DWCNTs in methanol show the same up shift of the Raman G band and the appearance of a new band at 1455cm−1. This is attributed to the interaction of the CH3 group of the amphiphilic molecule in composites or the CH3 group of alcohol with the outer tube of DWCNTs and indicates that laser heating of DWCNTs in methanol can induce the chemical adsorption of CH3 onto the CNT (carbon nanotube) surface.