B.E. Cohen

New single crystal 40Ar/39Ar ages improve time scale for deposition of the Omo Group, Omo-Turkana Basin, East Africa

Six tuffaceous beds within the Omo Group of the Omo–Turkana Basin have been dated using the 40Ar/39Ar single crystal total fusion method on anorthoclase, yielding eruption ages. The Omo Group constitutes up to 800 m of subaerially exposed sediments surrounding Lake Turkana within the East African Rift system in northern Kenya and southern Ethiopia. Rhyolitic explosive eruptions produced tuffs and pumice clasts that are considered to have been deposited shortly after eruption. The new age data on feldspars from the pumice clasts range from 4.02 ± 0.04 Ma for the Naibar Tuff of the Koobi Fora Formation to 1.53 ± 0.02 Ma for Tuff K of the Shungura Formation. The Orange Tuff in the KBS Member of the Koobi Fora Formation was dated at 1.76 ± 0.03 Ma, providing good control in this part of the sequence where formerly there was a >200 ka gap. Data are consistent with earlier measurements and significantly improve age resolution within the Omo Group, which has yielded many vertebrate fossils, including hominin fossils comprising a number of species. We suggest new age estimates for a limited number of hominin specimens. Supplementary material: Eleven tables and nine figures are available at www.geolsoc.org.uk/SUP18506.

Rapid change in drift of the Australian plate records collision with Ontong Java plateau

The subduction of oceanic plateaux, which contain extraordinarily thick basaltic crust and are the marine counterparts of continental flood-basalt provinces, is an important factor in many current models of plate motion and provides a potential mechanism for triggering plate reorganization. To evaluate such models, it is essential to decipher the history of the collision between the largest and thickest of the world’s oceanic plateaux, the Ontong Java plateau, and the Australian plate, but this has been hindered by poor constraints for the arrival of the plateau at the Melanesian trench. Here we present 40Ar–39Ar geochronological data on hotspot volcanoes in eastern Australian that reveal a strong link between collision of the Greenland-sized Ontong Java plateau with the Melanesian arc and motion of the Australian plate. The new ages define a short-lived period of reduced northward plate motion between 26 and 23 Myr ago, coincident with an eastward offset in the contemporaneous tracks of seamount chains in the Tasman Sea east of Australia. These features record a brief westward deflection of the Australian plate as the plateau entered and choked the Melanesian trench 26 Myr ago. From 23 Myr ago, Australia returned to a rapid northerly trajectory at roughly the same time that southwest-directed subduction began along the Trobriand trough. The timing and brevity of this collisional event correlate well with offsets in hotspot seamount tracks on the Pacific plate, including the archetypal Hawaiian chain, and thus provide strong evidence that immense oceanic plateaux, like the Ontong Java, can contribute to initiating rapid change in plate boundaries and motions on a global scale.

Geochronology of the Australian Cenozoic: a history of tectonic and igneous activity, weathering, erosion, and sedimentation*

The development and application of geochronological tools suitable for dating Cenozoic rocks and processes have been instrumental to our understanding of the modern history of Australia. Geochronology reveals a dynamic continent that traced a long and rapid trajectory from a position adjacent to Antarctica in the early Cenozoic to its present position near the tropics. The average travel velocity along this path is revealed by the age of hotspot volcanoes, derived by the K–Ar method, and is complemented by measured geomagnetic pole positions on dated igneous rocks and sedimentary deposits. K–Ar dating of volcanic rocks also provided constraints on rates of landscape evolution before and after volcanism and the timing and pattern of dispersion of life—including human inhabitation. K–Ar geochronological results reveal a history of faunal and floral evolution suggestive of a continent undergoing progressive cooling and dehydration with a few brief warm and humid excursions. In contrast, 40Ar/39Ar, SHRIMP U–Pb, fission-track thermochronology, luminescence techniques, and cosmogenic-isotope methods have played relatively minor roles in reconstructing the chronology of Cenozoic volcanism in Australia. Integrated application of these techniques will be critical to providing more precise constraints on the volcanic history of the continent and its climatic and biological evolution. While Cenozoic volcanism, uplift, and denudation were active along the eastern and southeastern margins, a significant part of Australia west of the Tasman Line remained relatively quiescent. The history of this part of the continent is marked by slow and subdued uplift and subsidence, with subtle displacements along major continental structures, and occasional invasion by shallow seas. Despite the general absence of Cenozoic igneous rocks west of the Tasman Line, Australia (east and west) is blanketed by Cenozoic sedimentary covers and weathering profiles. If we consider weathering as a fourth rock-forming process (in addition to igneous, metamorphic and sedimentary), Australia has one of the most complete Cenozoic rock covers of any continent. Retrieving information recorded in these weathering profiles is essential for unravelling its Cenozoic history. Paleomagnetic studies, calibrated δ18O curves, and weathering geochronology by K–Ar, 40Ar/39Ar, and (U–Th)/He provide insights into the imprint of climatic events and tectonic processes and illustrate the importance of erosion and weathering to the formation or enrichment of ore and mineral deposits. Except for diamondiferous lamproites of Western Australia and sapphire-rich volcanic rocks in eastern Australia, all other Cenozoic ore and mineral deposits in Australia are related to weathering and erosion. The widespread weathered blanket in Australia suggests low Cenozoic erosion rates. Numerical constraints on chronology and erosion rates are derived from the cooling and denudation histories retrieved from apatite and zircon fission-track and, more recently, (U–Th–Sm)/He thermochronology and cosmogenic isotope studies. Geochronological studies of veneers of sediments, lake and cave deposits, marine carbonates, organic matter and groundwaters provide information on sediment provenance, subtle tectonic movements, and the Australian Cenozoic climatic history. These studies reveal a continent sensitive to global climatic cycles and subject to active, but subtle, tectonism and erosion. This record shows that Australia suffered periods of extreme aridity during cyclical glaciation at high latitudes and precise dating of carbonate sediments and speleothems reveals the exact timing and duration of these glacial and interglacial periods. Cosmogenic isotopes also provide constraints on the age and migration paths of Australias limited and finite groundwater resources. Lastly, age information extracted from surficial deposits reveals a protracted history of human occupation.

40Ar/39Ar constraints on the timing and origin of Miocene leucitite volcanism in southeastern Australia

Laser incremental-heating 40Ar/39Ar geochronology of seven leucitites from southeastern Australia indicates that leucite-bearing lavas in individual geographic clusters were erupted in one million years or less. The eruption ages range from 17.9 ± 0.3 Ma (2σ) at El Capitan in northern-central New South Wales to 8.9 ± 0.2 Ma (2σ) at Cosgrove in northern Victoria. The 40Ar/39Ar results demonstrate that the southward migration of leucite-bearing lavas was near-contemporaneous with age-progressive central-volcano magmatism in southeastern Australia. As such, the 40Ar/39Ar results are consistent with a hotspot-related origin for the leucitites. However, the question of whether single or multiple hotspots are required to explain these volcanic chains, which are separated by a distance of about 300 km, awaits a more complete geochronological picture of the onset, duration and migration of leucitite and central-volcano magmatism in eastern Australia.

40Ar/39Ar constraints on the timing of Oligocene intraplate volcanism in southeast Queensland ∗

Laser 40Ar/39Ar analyses were undertaken on Oligocene bimodal intraplate volcanic rocks from five volcanic areas spanning 320 km along a north-northeast-trending belt in southeast Queensland. Sixty-one mineral grains and groundmass fragments from 21 samples were analysed by incremental heating, while 99 mineral grains from 10 samples were analysed by total fusion. Fourteen samples are from localities dated previously by the K – Ar method. The 40Ar/39Ar ages are reproducible among different aliquots from the same sample and different samples from the same location, and correlate with latitude, ranging from 30.6 ± 0.3 Ma on Fraser Island in the north (25°S) to 25.8 ± 0.2 Ma at Flinders Peak in the south (27.7°S). This age progression is not evident from K – Ar ages compiled for the same region. The decrease of 40Ar/39Ar ages with latitude is consistent with previous suggestions for a hotspot origin for east Australian central volcanoes and yields an Australian Plate velocity, relative to the postulated fixed hotspot reference frame, of 71 (+7, −4) mm/y at an azimuth of N10°E for the period of ca 31 – 26 Ma. This velocity agrees within error with the values of about 65 ± 3 mm/y obtained from previously reported K – Ar analyses of east Australian central volcano provinces active in the last 35 million years. These results demonstrate that the improved accuracy and precision of the 40Ar/39Ar method permit resolution of age versus latitude relationships for narrower time windows, which may potentially provide constraints on changing plate velocities with time. This improved temporal resolution may also contribute to resolving current debate over the existence and the stationary versus mutable position of postulated mantle plumes and hotspots.

A pulse of mid-Pleistocene rift volcanism in Ethiopia at the dawn of modern humans

The Ethiopian Rift Valley hosts the longest record of human co-existence with volcanoes on Earth, however, current understanding of the magnitude and timing of large explosive eruptions in this region is poor. Detailed records of volcanism are essential for interpreting the palaeoenvironments occupied by our hominin ancestors; and also for evaluating the volcanic hazards posed to the 10 million people currently living within this active rift zone. Here we use new geochronological evidence to suggest that a 200 km-long segment of rift experienced a major pulse of explosive volcanic activity between 320 and 170 ka. During this period, at least four distinct volcanic centres underwent large-volume (>10 km3) caldera-forming eruptions, and eruptive fluxes were elevated five times above the average eruption rate for the past 700 ka. We propose that such pulses of episodic silicic volcanism would have drastically remodelled landscapes and ecosystems occupied by early hominin populations.

Taking the pulse of Mars via dating of a plume-fed volcano

Mars hosts the solar system’s largest volcanoes. Although their size and impact crater density indicate continued activity over billions of years, their formation rates are poorly understood. Here we quantify the growth rate of a Martian volcano by 40Ar/39Ar and cosmogenic exposure dating of six nakhlites, meteorites that were ejected from Mars by a single impact event at 10.7 ± 0.8 Ma (2σ). We find that the nakhlites sample a layered volcanic sequence with at least four discrete eruptive events spanning 93 ± 12 Ma (1416 ± 7 Ma to 1322 ± 10 Ma (2σ)). A non-radiogenic trapped 40Ar/36Ar value of 1511 ± 74 (2σ) provides a precise and robust constraint for the mid-Amazonian Martian atmosphere. Our data show that the nakhlite-source volcano grew at a rate of ca. 0.4–0.7 m Ma−1—three orders of magnitude slower than comparable volcanoes on Earth, and necessitating that Mars was far more volcanically active earlier in its history.Mars hosts the solar system’s largest volcanoes, but their formation rates remain poorly constrained. Here, the authors have measured the crystallization and ejection ages of meteorites from a Martian volcano and find that its growth rate was much slower than analogous volcanoes on Earth.

Chronology of martian breccia NWA 7034 and the formation of the martian crustal dichotomy

The metamorphic history of martian meteorite NWA 7034 suggests that the martian crustal dichotomy may have formed within 100 million years of planetary formation. Martian meteorite Northwest Africa (NWA) 7034 and its paired stones are the only brecciated regolith samples from Mars with compositions that are representative of the average martian crust. These samples therefore provide a unique opportunity to constrain the processes of metamorphism and alteration in the martian crust, which we have investigated via U-Pu/Xe, 40Ar/39Ar, and U-Th-Sm/He chronometry. U-Pu/Xe ages are comparable to previously reported Sm-Nd and U-Pb ages obtained from NWA 7034 and confirm an ancient (>4.3 billion years) age for the source lithology. After almost 3000 million years (Ma) of quiescence, the source terrain experienced several hundred million years of thermal metamorphism recorded by the K-Ar system that appears to have varied both spatially and temporally. Such protracted metamorphism is consistent with plume-related magmatism and suggests that the source terrain covered an areal extent comparable to plume-fed edifices (hundreds of square kilometers). The retention of such expansive, ancient volcanic terrains in the southern highlands over billions of years suggests that formation of the martian crustal dichotomy, a topographic and geophysical divide between the heavily cratered southern highlands and smoother plains of the northern lowlands, likely predates emplacement of the NWA 7034 source terrain—that is, it formed within the first ~100 Ma of planetary formation.

Aqueous alteration of the Martian meteorite Northwest Africa 817: Probing fluid–rock interaction at the nakhlite launch site

The nakhlite meteorites characteristically contain iddingsite, a hydrous iron–magnesium silicate that formed by aqueous alteration on Mars. Iddingsite is most abundant in Northwest Africa (NWA) 817, and alteration products in this meteorite also have the lowest deuterium/hydrogen ratio of any nakhlite. Taken together, these distinctive properties could be interpreted to show that NWA 817 was altered under different physico‐chemical conditions than the other nakhlites and by liquid water from a separate reservoir. Here this interpretation is tested through a petrographic, mineralogical, chemical, and isotopic study of NWA 817. We find that its iddingsite occurs as olivine‐hosted veins of nanocrystalline smectite and Fe‐oxyhydroxide. Strong similarities in the mineralogy of iddingsite between NWA 817 and other nakhlites suggest that these meteorites were altered under comparable physico‐chemical conditions, with the Fe‐rich composition of NWA 817 olivine grains rendering them especially susceptible to aqueous alteration. Analyses of NWA 817 bulk samples by stepwise pyrolysis confirm that its iddingsite has unusually low deuterium/hydrogen ratios, but owing to terrestrial weathering of this meteorite, the hydrogen isotopic data cannot be used with confidence to infer the origin of Martian aqueous solutions. NWA 817 was most probably altered along with the other nakhlites over a short time period and in a common aqueous system. One interpretation of a correlation between the eruption ages of three of the nakhlites and the chemical composition of their iddingsite is that water originated from close to the surface of Mars and flowed through the nakhlite lava pile under the influence of gravity.

Naturaliste Plateau: constraints on the timing and evolution of the Kerguelen Large Igneous province and its role in Gondwana breakup

ABSTRACT Volcanism associated with the Kerguelen Large Igneous Province is found scattered in southwestern Australia (the ca 136 to ca 130 Ma Bunbury Basalts, and ca 124 Ma Wallaby Plateau), India (ca 118 Ma Rajmahal Traps and Cona Basalts), and Tibet (the ca 132 Ma Comei Basalts), but apart from the ∼70 000 km2 Wallaby Plateau, these examples are spatially and volumetrically minor. Here, we report dredge, geochronological and geochemical results from the ∼90 000 km2 Naturaliste Plateau, located ∼170 to ∼500 km southwest of Australia. Dredged lavas and intrusive rocks range from mafic to felsic compositions, and prior geophysical analyses indicate these units comprise much of the plateau substrate. 40Ar/39Ar plagioclase ages from mafic units and U–Pb zircon ages from silicic rocks indicate magmatic emplacement from 130.6 ± 1.2 to 129.4 ± 1.3 Ma for mafic rocks and 131.8 ± 3.9 to 128.2 ± 2.3 Ma for silicic rocks (2σ). These Cretaceous Naturaliste magmas incorporated a significant component of continental crust, with relatively high 87Sr/86Sr (up to 0.78), high 207Pb/204 Pb ratios (15.5–15.6), low 143Nd/144Nd (0.511–0.512) and primitive-mantle normalised Th/Nb of 11.3 and La/Nb of 3.97. These geochemical results are consistent with the plateau being underlain by continental basement, as indicated by prior interpretations of seismic and gravity data, corroborated by dredging of Mesoproterozoic granites and gneisses on the southern plateau flank. The Cretaceous Naturaliste Plateau igneous rocks have signatures indicative of extraction from a depleted mantle, with trace-element and isotopic values that overlap with Kerguelen Plateau lavas reflect crustal contamination. Our chemical and geochronological results therefore show the Naturaliste Plateau contains evidence of an extensive igneous event representing some of the earliest voluminous Kerguelen hotspot magmas. Prior work reports that contemporaneous correlative volcanic sequences underlie the nearby Mentelle Basin, and the Enderby Basin and Princess Elizabeth Trough in the Antarctic. When combined, the igneous rocks in the Naturaliste, Mentelle, Wallaby, Enderby, Princess Elizabeth, Bunbury and Comei-Cona areas form a 136–124 Ma Large Igneous Province covering >244 000 km2.