B. Minster

Interannual variation of water isotopologues at Vostok indicates a contribution from stratospheric water vapor

Combined measurements of water isotopologues of a snow pit at Vostok over the past 60 y reveal a unique signature that cannot be explained only by climatic features as usually done. Comparisons of the data using a general circulation model and a simpler isotopic distillation model reveal a stratospheric signature in the 17O-excess record at Vostok. Our data and theoretical considerations indicate that mass-independent fractionation imprints the isotopic signature of stratospheric water vapor, which may allow for a distinction between stratospheric and tropospheric influences at remote East Antarctic sites.

Climate variability features of the last interglacial in the East Antarctic EPICA Dome C ice core

Whereas millennial to submillennial climate variability has been identified during the current interglacial period, past interglacial variability features remain poorly explored because of lacking data at sufficient temporal resolutions. Here we present new deuterium data from the EPICA Dome C ice core, documenting at decadal resolution temperature changes occurring over the East Antarctic plateau during the warmer-than-today last interglacial. Expanding previous evidence of instabilities during the last interglacial, multicentennial subevents are identified and labeled for the first time in a past interglacial context. A variance analysis further reveals two major climatic features. First, an increase in variability is detected prior to the glacial inception, as already observed at the end of Marine Isotopic Stage 11 in the same core. Second, the overall variance level is systematically higher during the last interglacial than during the current one, suggesting that a warmer East Antarctic climate may also be more variable.

A Newly Designed Analytical Line to Examine Fluid Inclusion Isotopic Compositions in a Variety of Carbonate Samples

δ 18 O and δD of fluid inclusions in carbonates provide insights into temperatures and fluid chemical compositions prevailing during the carbonate precipitation, however, various analytical restrictions limit a wider application of this proxy. This paper presents a new fluid inclusions isotopic analytical line coupled to an online cavity ring‐down spectrometer that increased the analytical productivity up to 10 carbonate samples per working day. This efficiency allowed for the first time to assess the reliability a large set of water samples with size ranging from 0.1 to 1 µL. Good reproducibility (±0.5‰ for δ 18 O and ± 2‰ δD; 1σ) is obtained for water quantity superior or equal to 0.3 μL and no evidence of memory effect is found. The line is further tested using two types of natural carbonates: (1) modern speleothems samples from caves for which δ 18 O and δD values of drip water were measured and (2) diagenetic carbonates for which the δ 18 O of the parent water were independently back‐calculated from carbonate clumped isotope Δ 47 measurements. Speleothem fluid inclusion values despite falling close to the Global Meteoritic Water Line are not always representative of the isotopic composition of the parent drip water. Results on diagenetic cements show that the δ 18 O water values measured in fluid inclusions agree, within 1%, with the δ 18 O water independently derived from Δ 47 measurements. Overall, this study confirms the reliability and accuracy of the developed analytical line for carbonate fluid inclusion analyses with a good reproducibility obtained for water quantity above 0.3 μL.