B. Oliva-Urcia

Climate controls on rainfall isotopes and their effects on cave drip water and speleothem growth: the case of Molinos cave (Teruel, NE Spain)

AbstractnThe interpretation of stable isotopes in speleothems in terms of past temperature variability or precipitation rates requires a comprehensive understanding of the climatic factors and processes that influence the δ18O signal in the way through the atmosphere to the cave, where carbonate precipitates acquiring its final isotopic composition. This study presents for the first time in the Iberia Peninsula an integrated analysis of the isotopic composition of rainfall (δ18Op) during 2010–2012xa0years and, through a detailed monitoring survey, the transference of the primary isotopic signal throughout the soil and epikarst into the Molinos cave (Teruel, NE Spain). Both air temperature and amount of precipitation have an important effect on δ18Op values, clearly imprinting a seasonal variability modulated by an amount effect when rainfall events are more frequent or intense. Air mass history and atmospheric circulation influences are considered through the study of weather types, synoptic-scale climate patterns and large-scale atmospheric circulation indexes (North Atlantic Oscillation and Western Mediterranean Oscillation) revealing a dominant source effect on δ18Op values in this region where tropical North Atlantic and Western Mediterranean are the two moisture source regions. A delay of 2–3xa0months occurs between the dripwater oxygen isotopic composition (δ18Od) respect to δ18Op values as a consequence of large residence time in the epikarst. Limited calcite precipitates are found from winter to spring when δ18Od values are less negative and dripwater rates are constant. This study suggests that NE Iberian δ18Ocalcite proxy records are best interpreted as reflecting a combination of parameters, not just paleotemperature or paleorainfall and, if extending present-day situation towards the recent past, a biased signal towards winter values should be expected in Molinos speleothem records.

Multidisciplinary approach to constrain kinematics of fault zones at shallow depths: a case study from the Cameros–Demanda thrust (North Spain)

Thrusting at shallow depths often precludes analysis by means of structural indicators effective in other geological contexts (e.g., mylonites, sheath folds, shear bands). In this paper, a combination of techniques (including structural analysis, magnetic methods, as anisotropy of magnetic susceptibility and paleomagnetism, and paleothermometry) is used to define thrusting conditions, deformation, and transport directions in the Cameros–Demanda thrust (North Spain). Three outcrops were analyzed along this intraplate, large-scale major structure having 150xa0km of outcropping length, 30xa0km of maximum horizontal displacement, and 5xa0km of vertical throw. Results obtained by means of the different techniques are compared with data derived from cross sections and stratigraphic analysis. Mixed-layer illite–smectite and vitrinite reflectance indicating deep diagenetic conditions and mature stage of hydrocarbon generation suggests shallow depths during deformation, thus confirming that the protolith for most of the fault rocks is the footwall of the main thrust. Kinematic indicators (foliation, S/C structures, and slickenside striations) indicate altogether a dominant NNW movement of the hanging wall in the western zone and NE in the eastern zone of the thrust, thus implying strain partitioning between different branches of the main thrust. The study of AMS in fault rocks (nearly 400 samples of fault gouge, breccia, and microbreccia) indicates that the strike of magnetic foliation is oblique to the transport direction and that the magnetic lineation parallelizes the projection of the transport direction onto the kmax/kint plane in sites with strong shear deformation. Paleomagnetism applied to fault rocks indicates the existence of remagnetizations linked to thrusting, in spite of the shallow depth for deformation, and a strong deformation or scattering of the magnetic remanence vectors in the fault zone. The application of the described techniques and consistency of results indicate that the proposed multidisciplinary approach is useful when dealing with thrusts at shallow crustal levels.

New magnetostratigraphic dating of the Palaeogene syntectonic sediments of the west-central Pyrenees: tectonostratigraphic implications

Abstract New magnetostratigraphic results from a 3300 m-thick section across the syntectonic fluvial sediments of the Campodarbe Formation (Upper Eocene–Oligocene) in the Ebro foreland basin (NE Spain) are presented. The new data allow the top of the Campodarbe Formation to be correlated to Chron 7r (Chattian), younger than previously stated (C10r), therefore shifting the age of significant palaeogeographical changes in the foreland basin. The deformation in the southern front produces the cannibalization in the piggyback basin of 1300 m of sediments spanning c. 3.7 Myr. Average accumulation rates are lower in the Ebro foreland basin than in the piggyback basin and decrease from 35 to 27 cm kyr−1 by the time the San Felices thrust sheet activity decelerates (at c. 28 Myr). Shifts of accumulation rates result from accommodation space changes, which occur locally and are linked to the activity of the San Felices thrust, while the sediment supply occurs at orogenic scale (source of sediments is c. 200 km to the NE). Finally, sequence boundaries previously considered isochronous in the continental record of the Cenozoic Pyrenean basins are revealed to be 1.8–1 Myr older in the piggyback basin than in the Ebro foreland basin.

Tethyan versus Iberian extension during the Cretaceous period in the eastern Iberian Peninsula: insights from magnetic fabrics

This work investigates how anisotropy of magnetic susceptibility (AMS) recorded the strain related to the Early Cretaceous extensional processes in synrift sediments of the Maestrat basin (eastern Spain). Forty-two sites, distributed throughout the Lower Cretaceous sequence with dominant gentle dips, were sampled. Minerals contributing to the AMS are mainly phyllosilicates. The parallelism between magnetic and sedimentary foliation seems to indicate that a primary (synsedimentary and early diagenetic) magnetic fabric was preserved at 84% of sites. Consequently, preferred orientations of magnetic lineations are interpreted to record the effect of extensional processes coeval with sedimentation and diagenesis during this period. At these 35 sites, two main magnetic lineation orientations are found, delimiting two large domains: a NE–SW orientation prevailing in the NW sector of the basin (parallel to the extension direction of the Iberian basin), and NW–SE to NNW–SSE orientations to the SE (parallel to the extension direction controlling the western Tethys margin). Directional variability demonstrates that the Maestrat basin is located at the boundary between two domains (Iberian and Tethyan) undergoing different plate-scale extensional processes. The subsequent Cenozoic tectonic inversion affected the synsedimentary magnetic fabrics at only a few sites at the borders of the basin, where compressive features are more developed.

Last deglaciation and Holocene environmental change at high altitude in the Pyrenees: the geochemical and paleomagnetic record from Marboré Lake (N Spain)

Sedimentological, geochemical and magnetic data in a ~xa07-m sequence from Marboré Lake (2612xa0m asl, central Pyrenees) provide information about environmental variability since the last glacier retreat (14.6xa0calxa0ka BP) in high-altitude Pyrenean environments. The sediment sequence is composed of millimeter- to centimeter-thick rhythmites made of finer greyish laminae and coarser-grain, carbonate-bearing laminae arranged in varied patterns throughout the sequence. Finer laminae are interpreted as deposition during periods of predominantly ice-covered conditions, whereas coarser, carbonate-bearing sediments reflect periods of higher runoff. The age model, based on 13 14C dates and a reservoir effect assessed with 210Pb and 137Cs, is coherent with known synchronous vegetation changes across the Pyrenees. Warmer intervals such as GI-1 (14.6–12.8xa0calxa0ka BP, Bølling/Allerød period), 10.4–8.2xa0calxa0ka BP in the Early Holocene, 7.5–5.2xa0calxa0ka BP in the Mid Holocene and the Medieval Climate Anomaly (AD 900–1300), are characterized by peaks in productivity and higher carbonate preservation. Deposition during colder periods such as GS-1 (12.8–11.7xa0calxa0ka BP), the Neoglacial (ca. 5.2–3.5xa0calxa0ka BP) and the Little Ice Age (last 400xa0years) show an increase in finer laminae. The presence of magnetite throughout the whole section suggests that Marboré Lake maintained predominantly oxic conditions since its formation. Changes in magnetic properties and the increase in magnetite from 3.5xa0calxa0ka BP to present, however, indicate a more oxic environment at the lake bottom during the last few millennia. The occurrence of Pb concentration peaks in sediments of Roman and modern age demonstrates the global distribution of heavy metal deposition, even into high-mountain lakes.

Virtual Directions in Paleomagnetism: A Global and Rapid Approach to Evaluate the NRM Components

We introduce a method and software to process demagnetization data for a rapid and integrative estimation of characteristic remanent magnetization (ChRM) components. The virtual directions (VIDI) of a paleomagnetic site are “all” possible directions that can be calculated from a given demagnetization routine of “n” steps (being m the number of specimens in the site). If the ChRM can be defined for a site, it will be represented in the VIDI set. Directions can be calculated for successive steps using principal component analysis, both anchored to the origin (resultant virtual directions RVD; m * (n2+n)/2) and not anchored (difference virtual directions DVD; m * (n2-n)/2). The number of directions per specimen (n2) is very large and will enhance all ChRM components with noisy regions where two components were fitted together (mixing their unblocking intervals). In the same way, resultant and difference virtual circles (RVC, DVC) are calculated. Virtual directions and circles are a global and objective approach to unravel different natural remanent magnetization (NRM) components for a paleomagnetic site without any assumption. To better constrain the stable components, some filters can be applied, such as establishing an upper boundary to the MAD, removing samples with anomalous intensities, or stating a minimum number of demagnetization steps (objective filters) or selecting a given unblocking interval (subjective but based on the expertise). On the other hand, the VPD program also allows the application of standard approaches (classic PCA fitting of directions a circles) and other ancillary methods (stacking routine, linearity spectrum analysis) giving an objective, global and robust idea of the demagnetization structure with minimal assumptions. Application of the VIDI method to natural cases (outcrops in the Pyrenees and u-channel data from a Roman dam infill in northern Spain) and their comparison to other approaches (classic end-point, demagnetization circle analysis, stacking routine and linearity spectrum analysis) allows validation of this technique. The VIDI is a global approach and it is especially useful for large data sets and rapid estimation of the NRM components.

Palaeomagnetism in fold and thrust belts: use with caution

Abstract The application of palaeomagnetism in fold and thrust belts is a unique way to obtain kinematic information regarding the evolution of these systems. However, since many potential problems can affect the reliability of palaeomagnetic datasets and their interpretations, such data should be used with caution. In this paper, we thoroughly review the sources of error from palaeomagnetism with a particular focus on deciphering vertical-axis rotations and the assumptions behind the method. Recent investigations have demonstrated that the age of the magnetization and syn-folding results from the fold test must also be carefully examined: factors such as internal deformation, deficient isolation of components (i.e. overlapping) or incorrect restoration procedures may produce apparent syn-folding results. In fact, the restoration procedure used to return the palaeomagnetic signal to the palaeogeographic coordinate system may itself inhibit accurate estimations of vertical-axis rotations when complex deformation histories induce different, non-coaxial, deformation axes. We recommend the auxiliary use of the inclination v. dip diagram as an efficient tool for identifying many errors. Finally, to determine accurate vertical axis rotations, the reference direction should honour standard reliability criteria and would ideally be measured within the undeformed foreland of the thrust system. In this paper, we review five decades of palaeomagnetic research in fold and thrust belts by concentrating on maximizing standard reliability criteria procedures to reduce uncertainty and increase confidence when applying palaeomagnetic data to unravel the tectonic evolution of fold and thrust belts.

Petrophysical properties in the Iberian Range and surrounding areas (NE Spain): 1-density

ABSTRACT We introduce the first map of density data in Northeastern Spain which can help in the interpretation of gravimetric surveying. The background map is a simplified version of the Geode continuous geological cartography (scale 1:200.000) of the Iberian Range and Ebro basin. These maps are synthetic and homogeneous maps based on previous 1:50,000 scale geological maps (MAGNA). The map uses the ETRS89 datum and UTM coordinates (30T northern zone) and covers an area of 140,000 sq km. The compiled data shown in the map come from previous papers of the region (≈ 700 points) as well as from more than 800 additional points developed in the course of an exploratory project focused on the underground characterization of a potential CO2 reservoir in the so-called ‘Linking Zone. The new data accomplish some basic criteria; they are accurately georeferenced and lithology, stratigraphic age and other technical details about the measurements (e.g. means and error) and methods are fully displayed.

Paleomagnetism from Deception Island (South Shetlands archipelago, Antarctica), new insights into the interpretation of the volcanic evolution using a geomagnetic model

AbstractnDeception Island shows the most recent exposed active volcanism in the northern boundary of the Bransfield Trough. The succession of the volcanic sequence in the island is broadly divided into pre- and post-caldera collapse units although a well-constrained chronological identification of the well-defined successive volcanic episodes is still needed. A new paleomagnetic investigation was carried out on 157 samples grouped in 20 sites from the volcanic deposits of Deception Island (South Shetlands archipelago, Antarctic Peninsula region) distributed in: (1) volcanic breccia (3 sites) and lavas (2 sites) prior to the caldera collapse; (2) lavas emplaced after the caldera collapse (10 sites); and (3) dikes cutting pre- and the lowermost post-caldera collapse units (5 sites). The information revealed by paleomagnetism provides new data about the evolution of the multi-episodic volcanic edifice of this Quaternary volcano, suggesting that the present-day position of the volcanic materials is close to their original emplacement position. The new data have been combined with previous paleomagnetic results in order to tentatively propose an age when comparing the paleomagnetic data with a global geomagnetic model. Despite the uncertainties in the use of averaged paleomagnetic data per volcanic units, the new data in combination with tephra occurrences noted elsewhere in the region suggest that the pre-caldera units (F1 and F2) erupted before 12,000xa0year BC, the caldera collapse took place at about 8300xa0year BC, and post-caldera units S1 and S2 are younger than 2000xa0year BC.

Introduction: Palaeomagnetism in fold and thrust belts: new perspectives

E. L. PUEYO1*, F. CIFELLI2, A. J. SUSSMAN3 & B. OLIVA-URCIA4 Instituto Geológico y Minero de España, Unidad de Zaragoza c/Manuel Lasala 44, 98, 50006 Zaragoza, Spain Dipartimento Scienze, Università degli Studi di Roma TRE, Largo San Leonardo Murialdo 1, 00146 Rome, Italy Earth and Environmental Sciences Division, MS-D452, Los Alamos National Laboratory, Los Alamos, NM 87545, USA Departamento Geologı́a y Geoquı́mica Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco C/Francisco Tomás y Valiente, 7, M-06, 6 planta, 28049 Madrid, Spain