Barbara M. Martiny

Tertiary arc-magmatism of the Sierra Madre del Sur, Mexico, and its transition to the volcanic activity of the Trans-Mexican Volcanic Belt

The Tertiary magmatic rocks of the Sierra Madre del Sur (SMS) are broadly distributed south of the Trans-Mexican Volcanic Belt (TMVB) and extend to the southern continental margin of Mexico. They represent magmatic activity that originated at a time characterized by significant changes in the plate interactions in this region as a result of the formation of the Caribbean plate and the southeastward displacement of the Chortis block along the continental margin of southwestern Mexico. The change from SMS magmatism to an E‐W trending TMVB volcanism in Miocene time reflects the tectonic evolution of southwestern Mexico during these episodes of plate tectonic rearrangement. The distribution and petrographic characteristics of the magmatic rocks of the SMS define two belts of NW orientation. The first is represented by the nearly continuous coastal plutonic belt (CPB), which consists of batholiths and stocks of predominantly felsic composition. The second belt is inland of the first and consists of discontinuously distributed volcanic fields with piles of andesitic to rhyolitic flows, as well as epiclastic and pyroclastic materials. These two belts were emplaced along a continental crust segment constituted by a mosaic of basements with recognizable petrologic and isotopic diAerences. These basements originated during diAerent tectono-thermal events developed from the Proterozoic to the Mesozoic. Major and trace element data of the SMS magmatic rocks define a clear sub-alkaline tendency. Variations in the general geochemical behavior and in the Sr and Nd isotopic ratios indicate diAerent degrees of magmatic diAerentiation and/or crustal contamination. These variations, specially in the inland Oligocene volcanic regions of Guerrero and Oaxaca states, seem to have been controlled by the particular tectonic setting at the time of magmatism. In northwestern Oaxaca greater extension related to transtensional tectonics produced less diAerentiated volcanic rocks with an apparently lower degree of crustal contamination than those of northeastern Guerrero. The geochronologic data produced by us up to now, in addition to those previously reported, indicate that the Tertiary magmatic rocks of the SMS range in age from Paleocene to Miocene. The general geochronologic patterns indicate a southeastward decrease in the age of igneous activity, rather than a gradual northeastward migration of the locus of magmatism toward the present-day TMVB. SMS magmatic rocks exposed to the west of the 1008W meridian are dominantly Late Cretaceous to Eocene, while those to the east range from Oligocene to Miocene, also following a southeastward age-decreasing trend. Paleocene and Eocene magmatic rocks of the western region of the SMS seem to keep a general NNW trend similar to that of the Tertiary magmatic rocks of the Sierra Madre Occidental (SMO). In the eastern region of the SMS the Oligocene magmatic rocks show a trend that roughly defines an ESE orientation. The change in the trend of arc magmatism may be the eAect of the landward migration of the trench, for a given longitude, as a result of the displacement of the Chortis block. The

Overbank sediments from central Mexico : an evaluation of their use in regional geochemical mapping and in studies of contamination from modern and historical mining

Abstract Overbank sediment sequences in central Mexico display vertical changes in chemistry which can be related to both anthropogenic contamination and natural geological sources and processes. They also show significant lateral chemical variation, at both local and regional levels, which makes the design of a sampling strategy for regional geochemical mapping or contamination studies difficult. This variation is particularly pronounced in drainage basins which have been contaminated by mining activity and limits the use of overbank sediment as a systematic regional geochemical mapping medium. To be used with confidence, overbank sediments require detailed studies of fluvial geomorphology and history, accompanied by accurate age dating. Active drainage sediments are a more viable alternative in areas of historical mining activity, but must be examined carefully in the light of the regional background where levels of contamination are low or the contaminants are buried within the river floodplain.

Synchronous 29-19 Ma arc hiatus, exhumation and subduction of forearc in southwestern Mexico

Abstract The geology of southwestern Mexico (102–96°W) records several synchronous events in the Late Oligocene–Early Miocene (29–19 Ma): (1) a hiatus in arc magmatism; (2) removal of a wide (c. 210 km) Upper Eocene–Lower Oligocene forearc; (3) exhumation of 13–20 km of Upper Eocene–Lower Oligocene arc along the present day coast; and (4) breakup of the Farallon Plate. Events 2 and 3 have traditionally been related to eastward displacement of the Chortís Block from a position off southwestern Mexico between 105°W and 97°W; however at 30 Ma the Chortís Block would have lain east of 95°W. We suggest that the magmatic hiatus was caused by subduction of the forearc, which replaced the mantle wedge by relatively cool crust. Assuming that the subducted block separated along the forearc–arc boundary, a likely zone of weakness due to magmatism, the subducted forearc is estimated to be wedge-shaped varying from zero to c. 90 km in thickness; however such a wedge is not apparent in seismic data across central Mexico. Given the 121 km/Ma convergence rate between 20 and 10 Ma and 67 km/Ma since 10 Ma, it is probable that any forearc has been deeply subducted. Potential causes for subduction of the forearc include collision of an oceanic plateau with the trench, and a change in plate kinematics synchronous with breakup of the Farallon Plate and initiation of the Guadalupe–Nazca spreading ridge.

Thermomechanical maturation of the continental crust and its effects on the late Eocene–early Oligocene volcanic record of the Sierra Madre del Sur Province, southern Mexico

We interpret the voluminous late Eocene–early Oligocene volcanic successions of the north-central Sierra Madre del Sur as the eruptive manifestation of a progressive thermomechanical maturation of the crust, driven by sustained igneous activity that affected the region since the early Eocene. Widespread Eocene magmatism and injection of mantle-derived melts into the crust beneath the Michoacán-Puebla area promoted the development of a hot zone extending to upper crustal levels, and the formation of a mature intracrustal magmatic system. Within this context, the intermediate siliceous compositions of the Tilzapotla, Muñeca, and Goleta explosive centres were generated through fractional crystallization, crustal contamination, and anatexis. In particular, decreasing bulk-rock Sr and Eu concentrations and Nd isotopes with increasing silica in the Tilzapotla and Muñeca suites document an evolution through low-pressure fractional crystallization of plagioclase-dominated assemblages, simultaneous with the assimilation of middle–upper crustal materials. In contrast, marked Eu, Sr, and Ba depletions coupled with high and variable Rb/Nd at constant 143Nd/144Nd in the Goleta rhyolites suggest their derivation from partial melting of biotite-bearing quartz-feldspathic lithologies. Ascent of the thermal anomaly induced by magma emplacement and accumulation at shallow depths shifted the brittle–ductile crustal transition close to the surface, and produced an ignimbrite flare-up through caldera-forming eruptions. A different petrogenetic–volcanologic scenario developed in north-western Oaxaca, where less profuse early–middle Eocene igneous activity and an ancient lower crustal basement made up of refractory granulitic lithologies inhibited the expansion of the hot zone to shallow levels, and constrained magmatic evolution at depth. Here, composite and monogenetic volcanoes with intermediate compositions were produced through high-pressure fractional crystallization and crustal contamination. Specifically, increasing La/Yb and Sm/Yb with increasing silica in the Oaxaca suite, and negative correlations of Nd isotopes with SiO2 at low Rb/Nd, suggest garnet fractionation from parental basalts, coupled with the assimilation of Rb-depleted lower crustal materials.

Ammonium geochemistry of some Mexican silver deposits

Abstract Lithogeochemical sampling in the Guanajuato, Pachuca and Tayoltita silver mining districts of Mexico has revealed the presence of significant ammonium anomalies related to mineralized veins. The anomalies can be recognised in surface as well as in mine crosscut and drill core samples and persist over depths of several hundreds of metres. Ammonium haloes are best developed in the hanging walls of major veins but anomalous concentrations are also found in footwall regions. In all three areas ammonium is an effective pathfinder for epithermal precious-metal vein-style mineralization. Comparison with data for major and trace elements (Ca, K, Mg, Na, As, Ba, Cu, P, Rb, S, Sb, Sr, Zn) shows that ammonium often forms broader haloes with a more consistent relationship to the veins than other lithogeochemical indicators. Variations in ammonium geochemistry between deposits can be related to the availability of ammonium in the epithermal system, wall-rock lithology and the nature of the vein network. The results of this study suggest that ammonium geochemistry has considerable potential as an exploration tool for precious-metal vein deposits.

Geochronology and magmatic evolution of the Huautla volcanic field: last stages of the extinct Sierra Madre del Sur igneous province of southern Mexico

The Huautla volcanic field (HVF), in the Sierra Madre del Sur (SMS), is part of an extensive record of Palaeogene magmatism reflecting subduction of the Farallon plate along the western edge of North America. Igneous activity resulting from Farallon subduction is also exposed to the north, in the Sierra Madre Occidental (SMO) and Mesa Central (MC) provinces. We present the results of a stratigraphic and K–Ar, Ar–Ar, and U–Pb geochronological study of the Huautla volcanic successions, in order to refine our knowledge on the petrologic and temporal evolution of the northern SMS and gain insights on magmatic–tectonic contrasts between the SMS and the SMO–MC provinces. The HVF is made up of lava flows and pyroclastic successions that overlie marine Cretaceous sequences and post-orogenic continental deposits of Palaeogene age. In the study area, the main Oligocene succession is pre-dated by the 36.7 million years its caldera west of the Sierra de Huautla. The HVF succession ranges in age from ∼33.6 to 28.1 Ma and comprises a lower group of andesitic–dacitic lava flows, an intermediate sequence of ignimbrites and dacitic lavas, and an upper group of andesitic units. The silicic succession comprises a crystal-poor ignimbrite unit (i.e. the Maravillas ignimbrite; 31.4 ± 0.6, 32.0 ± 0.4 Ma; ∼260 km3), overlain by a thick succession of dacitic lavas (i.e. the Agua Fría dacite; 30.5 ± 1.9, 31.0 ± 1.1 Ma). Integration of the new stratigraphic and geochronological data with prior information from other explosive centres of the north-central SMS allows us to constrain the temporal evolution of a silicic flare-up episode, indicating that it occurred between 37–32 Ma; it consisted of three major ignimbrite pulses at ∼36.5, ∼34.5, and ∼33–32 Ma and probably resulted from a progressive, mantle flux-driven thermomechanical maturation of the continental crust, as suggested in the HVF by the transition from andesitic to voluminous siliceous volcanism. The information now available for the north-central sector of the SMS also allows recognition of differences between the temporal and spatial evolution of magmatism in this region, and of that documented in the southern SMO and MC provinces, suggesting that such contrasts are probably related to local differences in configuration of the subduction system. At ∼28 Ma, the MC and southern SMO provinces experienced a trenchward migration of volcanism, associated with slab rollback; on the other hand, the broad, more stable distribution of Oligocene magmatism in the central and north oceanic plate was subducting at a low angle.

The Salado River fault: reactivation of an Early Jurassic fault in a transfer zone during Laramide deformation in southern Mexico

The Salado River fault (SRF) is a prominent structure in southern Mexico that shows evidence of reactivation at two times under different tectonic conditions. It coincides with the geological contact between a structural high characterized by Palaeozoic basement rocks to the north, and an ∼2000 m thick sequence of marine and continental rocks that accumulated in a Middle Jurassic–Cretaceous basin to the south. Rocks along the fault within a zone up to 150 m across record crystal-plastic deformation affecting the metamorphic basement of the Palaeozoic Acatlán Complex. Later brittle deformation is recorded by both the basement and the overlying Mesozoic sedimentary rocks. Regional features and structural textures at both outcrop and microscopic scale indicate two episodes of left-lateral displacement. The first took place under low-to medium-grade P-T conditions in the late Early Jurassic (180 Ma) based on the interpretation of 40Ar/39Ar ratios from muscovite within the fault zone; the second occurred under shallow conditions, when the fault served as a transfer zone between areas with differing magnitudes of shortening north and south of the fault. In the southern block, fold hinges were dragged westward during Laramide tectonic transport to the east, culminating in brittle deformation characterized by strike–slip faulting in the Mesozoic sedimentary rocks. North of the fault, folds are not well defined, and it is clear that the fold hinges observed in the southern block do not continue north of the fault. Although the orientation and kinematics of the SRF are similar to major Cainozoic shear zones in southern Mexico, our new data indicate that the fault had become inactive by the time of Oligocene volcanism.