Beatrix Udvardi

Effects of Particle Size on the Attenuated Total Reflection Spectrum of Minerals

This study focuses on particle size effect on monomineralic powders recorded using attenuated total reflection Fourier transform infrared (ATR FT-IR) spectroscopy. Six particle size fractions of quartz, feldspar, calcite, and dolomite were prepared (<2, 2–4, 4–8, 8–16, 16–32, and 32–63 µm). It is found that the width, intensity, and area of bands in the ATR FT-IR spectra of minerals have explicit dependence on the particle size. As particle size increases, the intensity and area of IR bands usually decrease while the width of bands increases. The band positions usually shifted to higher wavenumbers with decreasing particle size. Infrared spectra of minerals are the most intensive in the particle size fraction of 2–4 µm. However, if the particle size is very small (<2 µm), due to the wavelength and penetration depth of the IR light, intensity decreases. Therefore, the quantity of very fine-grained minerals may be underestimated compared to the coarser phases. A nonlinear regression analysis of the data indicated that the average coefficients and indices of the power trend line equation imply a very simplistic relationship between median particle diameter and absorbance at a given wavenumber. It is concluded that when powder samples with substantially different particle size are compared, as in regression analysis for modal predictions using ATR FT-IR, it is also important to report the grain size distribution or surface area of samples. The band area of water (3000–3620 cm–1) is similar in each mineral fraction, except for the particles below 2 µm. It indicates that the finest particles could have disproportionately more water adsorbed on their larger surface area. Thus, these higher wavenumbers of the ATR FT-IR spectra may be more sensitive to this spectral interference if the number of particles below 2 µm is considerable. It is also concluded that at least a proportion of the moisture could be very adhesive to the particles due to the band shift towards lower wavenumbers in the IR range of 3000–3620 cm–1.

Origin and weathering of landslide material in a loess area: a geochemical study of the Kulcs landslide, Hungary

Geochemical characteristics of sediments are responses to physical and chemical alteration in landslides. However, consequences of in situ interactions associated with landslides are difficult to distinguish from those related to long-term weathering in young soft sediments such as loess. In this study, geochemical characteristics of the Kulcs landslide in Hungary are studied to identify the provenance of the loess–paleosol–red clay sequence and geochemical signatures that can potentially be attributed to the effects of landsliding. Results indicate that sliding is largely initiated by the lithological changes within the landslide body. Sediments above the sliding zone closely resemble the non-slipped Pleistocene old loess deposits from Hungary. It is also confirmed that the sliding zone develops in old paleosols in the loess sequence and red clays at its base which are all characterized by the enrichment of Al, K, Na, H2O and considerable depletion in Ca and Mg associated with carbonates. Altogether, these geochemical characteristics indicate that chemical weathering trend of unconsolidated landslide sediments is slightly modified by the redistribution of carbonates and decomposition of plagioclase. It is assumed that the distribution of Mn and Ba is modified by the water–sediment interaction in the landslide.