Becky E. Strauss

Long-term changes in precipitation recorded by magnetic minerals in speleothems

Speleothems are important paleoclimate archives. Researchers typically compile measurements of stable isotopic ratios dated using high precision U-Th radiometric techniques to reconstruct regional and global climate. Magnetic material incorporated within speleothems can provide an independent means of connecting large-scale climatic changes with their impact on more localized processes in soils overlying cave systems. Under certain environmental conditions, pedogenic processes can produce magnetite nanoparticles. Enhancement of pedogenic magnetite in soil profiles depends strongly on local precipitation. Pedogenic magnetite can be subsequently transferred via drip-waters into underlying cave-systems and incorporated into speleothems as they grow. Here, we employ high-resolution magnetic methods to analyze a well-dated stalagmite from Buckeye Creek Cave, West Virginia (USA), and find that changes in magnetite concentration follow both changes in stable isotopes measured in the same stalagmite and global climate proxies. We interpret the changes in magnetite concentration as reflecting variations in local pedogenic processes, controlled by changes in regional precipitation. This record demonstrates how magnetic measurements on speleothems can constrain interpretations of speleothem climate proxies.

Age and paleoenvironmental reconstruction of partially remagnetized lacustrine sedimentary rocks (Oligocene Aktoprak basin, central Anatolia, Turkey)

The age and paleoenvironmental record of lacustrine deposits in the Aktoprak basin of south-central Turkey provides information about the evolution of topography, including the timing of development of an orographic rain shadow caused by uplift of the mountain ranges fringing the Central Anatolian Plateau. New magnetostratigraphy-based age estimates, in combination with existing biostratigraphic ages, suggest that the partially remagnetized Kurtulmus Tepe section of the basin is Chattian (Upper Oligocene). The mean carbon and oxygen stable isotope ratios (δ18O= 24.6 ± 2.0 ‰, δ13C= −4.9 ± 1.1‰) are largely constant through the section and indicative of a subtropical, open freshwater lake. These isotopic values are also similar to those of the Chattian Mut basin to the south, on the Mediterranean side of the modern orographic barrier (Tauride Mountains), and indicate absence of an orographic barrier during Late Oligocene basin deposition. Post-depositional partial remagnetization occurred after tilting of the basin sequence and was mineralogically controlled, affecting grey, carbonate-rich rocks (average %CaCO3= 82), whereas interlayered pink carbonate-poor rocks (average %CaCO3= 38) carry a primary, pretilt magnetization. The pink rocks are rich in clay minerals that may have reduced the permeability of these rocks that carry a primary magnetization, concentrating basinal fluid flow in the carbonate-rich grey layers and leading to the removal and reprecipitation of magnetic minerals. The normal and reverse polarities recorded by the remagnetized rocks suggest that remagnetization occurred over a protracted period of time.

The effects of 10 to >160 GPa shock on the magnetic properties of basalt and diabase

Hypervelocity impacts within the solar system affect both the magnetic remanence and bulk magnetic properties of planetary materials. Spherical shock experiments are a novel way to simulate shock events that enable materials to reach high shock pressures with a variable pressure profile across a single sample (ranging between ∼10 and >160 GPa). Here we present spherical shock experiments on basaltic lava flow and diabase dike samples from the Osler Volcanic Group whose ferromagnetic mineralogy is dominated by pseudo-single-domain (titano)magnetite. Our experiments reveal shock-induced changes in rock magnetic properties including a significant increase in remanent coercivity. Electron and magnetic force microscopy support the interpretation that this coercivity increase is the result of grain fracturing and associated domain wall pinning in multidomain grains. We introduce a method to discriminate between mechanical and thermal effects of shock on magnetic properties. Our approach involves conducting vacuum-heating experiments on untreated specimens and comparing the hysteresis properties of heated and shocked specimens. First order reversal curve (FORC) experiments on untreated, heated and shocked specimens demonstrate that shock and heating effects are fundamentally different for these samples: shock has a magnetic hardening effect that does not alter the intrinsic shape of FORC distributions, while heating alters the magnetic mineralogy as evident from significant changes in the shape of FORC contours. These experiments contextualize paleomagnetic and rock magnetic data of naturally shocked materials from terrestrial and extraterrestrial impact craters. This article is protected by copyright. All rights reserved.

Magnetic mineralogy of the Mercurian lithosphere

Mercury and Earth are the only inner solar system planets with active, internally generated dynamo magnetic fields. The MESSENGER mission recently detected magnetic fields on Mercury that are consistent with lithospheric magnetization. We investigate the physical and chemical environment of Mercurys lithosphere, past and present, to establish the conditions under which magnetization may have been acquired and modified. Three factors are particularly crucial to the determination of crustal composition and iron mineralogy: redox conditions in the planets crust and mantle, the iron content of the lithosphere, and, for any remanent magnetization, the temperature profile of the lithosphere and its evolution over time. We explore potential mechanisms for remanence acquisition and alteration on Mercury, whose surface environment is both hot and highly reducing. The long-term thermal history of Mercurys crust plays an important role in the longevity of any remanent crustal magnetization, which may be subject to remagnetization through thermal, viscous, and shock mechanisms. This thermal and compositional framework is used both to constrain plausible candidate minerals that could carry magnetic remanence on Mercury and to evaluate their capacity to acquire and retain sufficient magnetization to be detectable from satellite orbit. We propose that iron metal and its alloys are likely to be the dominant contributors to induced and remanent magnetization in Mercurys lithosphere, with additional contributions from iron silicides, sulfides, and carbides.