Binbin Fan

Facile synthesis of 3D plum candy-like ZnCo2O4 microspheres as a high-performance anode for lithium ion batteries

In this paper, 3D plum candy-like ZnCo2O4 microspheres (3D plum candy-like ZCO MSs) with nanoscale building blocks were synthesized by an ultrasonic spray pyrolysis technology and evaluated as anode materials for high-performance lithium ion batteries (LIBs). The uniform ZnCo2O4 microspheres exhibit plum candy-like architectures and are built from a large amount of interconnected nanoparticles with a diameter of approximately 38 nm. Owing to the unique hierarchical porous structure, the 3D plum candy-like ZCO MSs exhibit many advantageous properties such as their ability to facilitate the transport of Li+ and electrolytes by shortening the diffusion ways, to accommodate the mechanical stress and volume change associated with the Li+ insertion/extraction processes, and to improve the contact area between electrode and electrolyte, which are beneficial to improve the electrochemical performance. As a consequence, the ZnCo2O4 nanomaterials exhibit excellent cycling performance with a discharge capacity of 1030 mA h g−1 after 110 cycles at 200 mA g−1 and superior rate capability (769 mA h g−1 at 2000 mA g−1). In virtue of the simple synthesis method and excellent electrochemical performance, 3D porous ZCO MSs have huge potential as anode materials for the next-generation LIBs.

Molybdenum disulfide nanosheet embedded three-dimensional vertically aligned carbon nanotube arrays for extremely-excellent cycling stability lithium-ion anodes

Molybdenum disulfide (MoS2) nanosheets embedded in three-dimensional (3D) vertically aligned carbon nanotube arrays (VACNTs) have been fabricated via a simple nebulization-assisted hydrothermal method. The MoS2/VACNTs possess a highly ordered and uniformly oriented 3D structure with MoS2 nanosheets adhering strictly to the surface of VACNTs. When evaluated as lithium-ion anode materials, so-obtained MoS2/VACNTs composites containing 52 wt% MoS2 exhibit superb electrochemical performances, including high capacity (1078 mA h g−1 at 100 mA g−1 after 1st cycle), good rate capability (789 mA h g−1 at 2000 mA g−1 after 20 cycles), and extremely-excellent cycling stability, for the MoS2/VACNTs electrode can still deliver a discharge capacity of 512 mA h g−1 after 1000 cycles at 5000 mA g−1, compared with pristine MoS2 (negligible discharge capacity at the 70th cycle). Such high electrical properties can mainly be attributed to the unique well-directed pore-morphology which provides low-resistant shortest diffusion pathways upon the high-conductive VACNTs to accelerate ion/electron movement. Moreover, the elastic spare-space inside/outside VACNTs as a buffer factor effectively restrains large volumetric change from MoS2 during the charge/discharge process. It can be determined that such a structure is attractive to achieve extremely-excellent cycling stability lithium-ion anodes.

Capacity-increasing robust porous SiO2/Si/graphene/C microspheres as an anode for Li-ion batteries

Robust porous SiO2/Si/graphene/C microspheres have been successfully synthesized by a simple two-step process of ultrasonic spraying and partial magnesiothermic reduction. The 3-D porous microspheres consist of Si/SiO2 nanoparticles (around 5–10 nm) covered by a layer of carbon and connected by graphene. We explored the electrochemical properties of the porous microspheres as an anode for lithium ion batteries (LIBs). In SiO2/Si/graphene/C microspheres, numerous pores could leave enough room for volume expansion and contraction of silicon during lithiation and delithiation, and provide large space voids for electrolyte reserves. Meanwhile, graphene plays a role in reinforcing the porous structure. The prepared sample shows superior cyclability with a discharge capacity of 1104.9 mA h g−1 in the second cycle and 1141.6 mA h g−1 over 200 cycles at a current density of 0.1 mA cm−2. The capacity retention is more than 100%, making it very promising as a future LIBs anode.

Compact-Nanobox Engineering of Transition Metal Oxides with Enhanced Initial Coulombic Efficiency for Lithium-Ion Battery Anodes

A novel strategy is proposed to construct a compact-nanobox (CNB) structure composed of irregular nanograins (average diameter ≈ 10 nm), aiming to confine the electrode-electrolyte contact area and enhance initial Coulombic efficiency (ICE) of transition metal oxide (TMO) anodes. To demonstrate the validity of this attempt, CoO-CNB is taken as an example which is synthesized via a carbothermic reduction method. Benefiting from the compact configuration, electrolyte can only contact the outer surface of the nanobox, keeping the inner CoO nanograins untouched. Therefore, the solid electrolyte interphase (SEI) formation is reduced. Furthermore, the internal cavity leaves enough room for volume variation upon lithiation and delithiation, resulting in superior mechanical stability of the CNB structure and less generation of fresh SEI. Consequently, the SEI remains stable and spatially confined without degradation, and hence, the CoO-CNB electrode delivers an enhanced ICE of 82.2%, which is among the highest values reported for TMO-based anodes in lithium-ion batteries. In addition, the CoO-CNB electrode also demonstrates excellent cyclability with a reversible capacity of 811.6 mA h g-1 (90.4% capacity retention after 100 cycles). These findings open up a new way to design high-ICE electrodes and boost the practical application of TMO anodes.