Bonnie D. Riehl

Manganese Detection with a Metal Catalyst Free Carbon Nanotube Electrode: Anodic versus Cathodic Stripping Voltammetry

Anodic stripping voltammetry (ASV) and cathodic stripping voltammetry (CSV) were used to determine Mn concentration using metal catalyst free carbon nanotube (MCFCNT) electrodes and square wave stripping voltammetry (SWSV). The MCFCNTs are synthesized using a Carbo Thermal Carbide Conversion method which results in a material that does not contain residual transition metals. Detection limits of 120 nM and 93 nM were achieved for ASV and CSV, respectively, with a deposition time of 60 s. CSV was found to be better than ASV in Mn detection in many aspects, such as limit of detection and sensitivity. The CSV method was used in pond water matrix addition measurements.

High temperature low vacuum synthesis of a freestanding three-dimensional graphene nano-ribbon foam electrode

The fabrication of a freestanding three-dimensional (3D) graphene nano-ribbon open cell foam electrode is reported based upon a facile high temperature (1700 °C) low vacuum (50 Torr) process. The graphene nano-ribbon (GNR) foam comprises on average 4 graphene layers and has an O/C ratio of 0.14; a quasi-graphene structure. This unique material is demonstrated to be electrochemically useful, with the electrochemical properties and resultant electroanalytical performance of the novel freestanding 3D GNR foam electrode reported for the first time. Electrochemical characterisation is performed via cyclic voltammetry in aqueous solutions using a range of electro-active redox probes and biologically relevant analytes, namely potassium ferrocyanide(II), hexaammineruthenium(III) chloride, uric acid (UA), acetaminophen (AP) and dopamine hydrochloride (DA). Analytical performance is evaluated and benchmarked through comparisons of the 3D GNR foam to other carbon based 3D foam electrodes, namely pristine graphene and reticulated vitreous carbon (RVC) alternatives. We show that the 3D GNR foam electrode possesses favourable heterogeneous electron transfer (HET) properties when compared to the alternative carbon based 3D foams, likely due to improved coverage of reactive edge plane like-sites/defects on its structure. In terms of the electroanalytical response of the 3D GNR foam electrode, it is found to give rise to an improved linear range and limit of detection towards some analytes; however, in certain cases the alternative carbon based 3D foams out-performed the GNR foam. These findings question the need of ‘only’ fast HET properties and suggest a compromise is required (for improved sensing capabilities to be realised) between HET speeds, the presence/absence of oxygenated species and the accessibility of the electrodes active surface area. This work offers insight to those working in the field of electrochemistry, particularly electroanalysis and those searching for new carbon based 3D foam electrode materials.

Solid carbon nanorod whiskers: application to the electrochemical sensing of biologically relevant molecules

We introduce solid carbon nanorod whiskers, a derivative of carbon nanotubes which are fabricated via a solid state methodology and are completely free from metallic impurities. We explore the electrochemical properties of these unique carbon nanostructures towards the electrochemical oxidation of NADH, dopamine and uric acid, and compare and contrast to other carbon nanomaterials/composites where appropriate. It is shown that thin layer behaviour dominates when the coverage of the nanomaterials is increased giving the false impression of electro-catalysis. The SCNR whiskers are analytically similar to other reported carbon nanotube structures and yet do not suffer from problems associated with metallic impurities, suggesting their beneficial use in many areas of electrochemistry.