Bradley J. McDonald

An in situ technique for (U–Th–Sm)/He and U–Pb double dating

We report on a new laser-based technique for rapid, quantitative and automated in situ double dating (U–Pb and (U–Th–Sm)/He) of minerals, for applications in geochronology, thermochronology and geochemistry. In situ laser microanalysis offers several advantages over conventional bulk crystal methods in terms of spatial resolution, productivity, and safety. This new approach/methodology utilizes an interoperable and integrated suite of analytical instruments including a 193 nm ArF excimer laser system, quadrupole ICP-MS, quadrupole helium mass spectrometry system and swappable flow-through and ultra-high vacuum analytical chambers. We describe the analytical protocols for zircon analysis including grain mounting in Teflon, parameters for parent and daughter isotopic measurement, and standard development, and provide a freeware application for determining (U–Th–Sm)/He ‘pairwise’ ages from analytical data. The in situ double dating method described is applied to the Ellendale lamproite pipe and country rocks, Western Australia and successfully replicates conventional U–Pb and (U–Th–Sm)/He age variations determined previously by conventional techniques.

The answers are blowin' in the wind: Ultra-distal ashfall zircons, indicators of Cretaceous super-eruptions in eastern Gondwana

An Early Cretaceous siliceous large igneous province (SLIP) that developed on the eastern margin of Gondwana produced some of the most voluminous siliceous volcaniclastic deposits known globally. We report U-Pb ages and trace-element and Hf-isotopic signatures of detrital zircons from the Madura Shelf (onshore Bight Basin), Western Australia. These zircons include a geochemically distinct 106 Ma component with age and Hf characteristics that match SLIP volcanics some 2300 km distant in eastern Australia. This young subpopulation shows limited grain abrasion, which contrasts with older detrital components that are stratigraphically persistent. Regional detrital zircon provenance demonstrates that sediment routing systems were disconnected in the eastern and western Bight Basin, negating terrestrial transport mechanisms as a possible vector of the zircons from the SLIP to their recovered position. Palynology indicates that the 106 Ma zircons are syn-depositional, and we interpret them as being significantly transported in an eruption plume. Given the grain size and distance from source, such distal zircon emplacement suggests previously undocumented 106 Ma super-eruptions. The 106 Ma zircons likely reflect Southern Hemisphere winter eruptions when tropospheric polar easterly winds would have been favored across southeastern Australia.

Evidence for melting mud in Earth’s mantle from extreme oxygen isotope signatures in zircon.

Evidence for melting mud in Earths mantle from extreme oxygen isotope signatures in zircon

The source of Dalradian detritus in the Buchan Block, NE Scotland: application of new tools to detrital datasets

Detrital zircons from four samples of upper Dalradian metasedimentary rocks from the Buchan Block in the NE Grampian Highlands of Scotland were analysed by laser ablation inductively coupled plasma mass spectrometry to establish their U–Pb age and trace element composition. The analysed grains (magmatic cores) mainly yield concordant ages ranging from Neoproterozoic to Eoarchaean. Kernel density plots of the data show pronounced peaks in the late Mesoproterozoic, Palaeoproterozoic and Neoarchaean eras. The data are indistinguishable from detrital zircon age spectra from Dalradian rocks elsewhere, an interpretation supported by application of a non-parametric multidimensional scaling algorithm, and are consistent with a Laurentian source. Similar to existing studies from other Dalradian rocks, the age spectra from the Buchan Block reveal an increase in the relative proportion of older detritus with time, suggesting derivation from late Mesoproterozoic (Grenville) then Palaeoproterozoic orogens before widespread exposure and denudation of their Archaean basement rocks. Application of a novel approach to estimate the most likely time of radiogenic-Pb loss indicates that some detrital zircon grains were affected by element mobility around 470–450 Ma as a result of Grampian orogenesis. Supplementary material: Laser ablation inductively coupled plasma mass spectrometry U–Pb and trace element data, a matrix showing results of Kolmogorov–Smirnov (K–S) test, cathodoluminescence imaging of zircons and selected trace element plots are available at http://doi.org/10.6084/m9.figshare.c.3153931

Otolith microchemistry: Insights into bioavailable pollutants in a man-made, urban inlet

Black bream (Acanthopagrus butcheri) were collected from an artificial inlet, Claisebrook Cove, Western Australia. Claisebrook Cove is adjacent to an historic contaminated site that was remediated during the 1990s. It was later identified as a priority area due to elevated levels of sediment contaminants including Zn, Cu, and Pb. Black bream were collected from this cove in 2005 and 2012 and their otoliths were analysed by laser ablation inductively coupled plasma mass spectrometry of the most recent growth zone. Levels of Zn and Mn, which are metabolically regulated, did not correlate with sediment contamination. However, reduction in sediment Cu levels over time coincided with reduced Cu otolith levels from 2005 to 2012. Results indicate that the elemental composition of the marginal edge of Black bream otoliths can identify bioavailable contaminants in an urban estuary and, with monitoring, can be utilized to establish long-term trends.

Geochemical and Crystallographic Study of Turbo Torquatus (Mollusca: Gastropoda) From Southwestern Australia

Shells of the marine gastropod Turbo torquatus were sampled from three different locations along the Western Australian coastline, namely Marmion Lagoon (318S), Rottnest Island (328S), and Hamelin Bay (348S). Marmion Lagoon and Rottnest Island have similar sea surface temperature ranges that are 18C warmer than Hamelin Bay, with all sites influenced by the warm southward flowing Leeuwin Current. The shells were characterized using crystallographic, spectroscopic, and geochemical analyses. Shell mineral composition varies between the three sites suggesting the influence of sea surface temperature, oxygen consumption, and/or bedrock composition on shell mineralogy and preferential incorporation and/or elemental discrimination of Mg, P, and S. Furthermore, T. torquatus was found to exert control over the incorporation of most, if not all, the elements measured here, suggesting strong biological regulation. At all levels of testing, the concentrations of Li varied significantly, which indicates that this trace element may not be a suitable environmental proxy. Variation in Sr concentration between sites and between specimens reflects combined environmental and biological controls suggesting that Sr/Ca ratios in T. torquatus cannot be used to estimate sea surface temperature without experimentally accounting for metabolic and growth effects. The mineral composition and microstructure of T. torquatus shells may help identify sea surface temperature variations on geological time scales. These findings support the previously hypothesized involvement of an active selective pathway across the calcifying mantle of T. torquatus for most, if not all, the elements measured here.