Brane Širok

Removal of pharmaceuticals from wastewater by biological processes, hydrodynamic cavitation and UV treatment

To augment the removal of pharmaceuticals different conventional and alternative wastewater treatment processes and their combinations were investigated. We tested the efficiency of (1) two distinct laboratory scale biological processes: suspended activated sludge and attached-growth biomass, (2) a combined hydrodynamic cavitation-hydrogen peroxide process and (3) UV treatment. Five pharmaceuticals were chosen including ibuprofen, naproxen, ketoprofen, carbamazepine and diclofenac, and an active metabolite of the lipid regulating agent clofibric acid. Biological treatment efficiency was evaluated using lab-scale suspended activated sludge and moving bed biofilm flow-through reactors, which were operated under identical conditions in respect to hydraulic retention time, working volume, concentration of added pharmaceuticals and synthetic wastewater composition. The suspended activated sludge process showed poor and inconsistent removal of clofibric acid, carbamazepine and diclofenac, while ibuprofen, naproxen and ketoprofen yielded over 74% removal. Moving bed biofilm reactors were filled with two different types of carriers i.e. Kaldnes K1 and Mutag BioChip™ and resulted in higher removal efficiencies for ibuprofen and diclofenac. Augmentation and consistency in the removal of diclofenac were observed in reactors using Mutag BioChip™ carriers (85%±10%) compared to reactors using Kaldnes carriers and suspended activated sludge (74%±22% and 48%±19%, respectively). To enhance the removal of pharmaceuticals hydrodynamic cavitation with hydrogen peroxide process was evaluated and optimal conditions for removal were established regarding the duration of cavitation, amount of added hydrogen peroxide and initial pressure, all of which influence the efficiency of the process. Optimal parameters resulted in removal efficiencies between 3-70%. Coupling the attached-growth biomass biological treatment, hydrodynamic cavitation/hydrogen peroxide process and UV treatment resulted in removal efficiencies of >90% for clofibric acid and >98% for carbamazepine and diclofenac, while the remaining compounds were reduced to levels below the LOD. For ibuprofen, naproxen, ketoprofen and diclofenac the highest contribution to overall removal was attributed to biological treatment, for clofibric acid UV treatment was the most efficient, while for carbamazepine hydrodynamic cavitation/hydrogen peroxide process and UV treatment were equally efficient.

Use of hydrodynamic cavitation in (waste)water treatment.

The use of acoustic cavitation for water and wastewater treatment (cleaning) is a well known procedure. Yet, the use of hydrodynamic cavitation as a sole technique or in combination with other techniques such as ultrasound has only recently been suggested and employed. In the first part of this paper a general overview of techniques that employ hydrodynamic cavitation for cleaning of water and wastewater is presented. In the second part of the paper the focus is on our own most recent work using hydrodynamic cavitation for removal of pharmaceuticals (clofibric acid, ibuprofen, ketoprofen, naproxen, diclofenac, carbamazepine), toxic cyanobacteria (Microcystis aeruginosa), green microalgae (Chlorella vulgaris), bacteria (Legionella pneumophila) and viruses (Rotavirus) from water and wastewater. As will be shown, hydrodynamic cavitation, like acoustic, can manifest itself in many different forms each having its own distinctive properties and mechanisms. This was until now neglected, which eventually led to poor performance of the technique. We will show that a different type of hydrodynamic cavitation (different removal mechanism) is required for successful removal of different pollutants. The path to use hydrodynamic cavitation as a routine water cleaning method is still long, but recent results have already shown great potential for optimisation, which could lead to a low energy tool for water and wastewater cleaning.

A novel rotation generator of hydrodynamic cavitation for waste-activated sludge disintegration

The disintegration of raw sludge is very important for enhancement of the biogas production in anaerobic digestion process as it provides easily degradable substrate for microorganisms to perform maximum sludge treatment efficiency and stable digestion of sludge at lower costs. In the present study the disintegration was studied by using a novel rotation generator of hydrodynamic cavitation (RGHC). At the first stage the analysis of hydrodynamics of the RGHC were made with tap water, where the cavitation extent and aggressiveness was evaluated. At the second stage RGHC was used as a tool for pretreatment of a waste-activated sludge (WAS), collected from wastewater treatment plant (WWTP). In case of WAS the disintegration rate was measured, where the soluble chemical oxygen demand (SCOD) and soluble Kjeldahl nitrogen were monitored and microbiological pictures were taken. The SCOD increased from initial 45 mg/L up to 602 mg/L and 12.7% more biogas has been produced by 20 passes through RGHC. The results were obtained on a pilot bioreactor plant, volume of 400 L.

Shear-induced hydrodynamic cavitation as a tool for pharmaceutical micropollutants removal from urban wastewater

In this study, the removal of clofibric acid, ibuprofen, naproxen, ketoprofen, carbamazepine and diclofenac residues from wastewater, using a novel shear-induced cavitation generator has been systematically studied. The effects of temperature, cavitation time and H2O2 dose on removal efficiency were investigated. Optimisation (50°C; 15 min; 340 mg L(-1) of added H2O2) resulted in removal efficiencies of 47-86% in spiked deionised water samples. Treatment of actual wastewater effluents revealed that although matrix composition reduces removal efficiency, this effect can be compensated for by increasing H2O2 dose (3.4 g L(-1)) and prolonging cavitation time (30 min). Hydrodynamic cavitation has also been investigated as either a pre- or a post-treatment step to biological treatment. The results revealed a higher overall removal efficiency of recalcitrant diclofenac and carbamazepine, when hydrodynamic cavitation was used prior to as compared to post biological treatment i.e., 54% and 67% as compared to 39% and 56%, respectively. This is an important finding since diclofenac is considered as a priority substance to be included in the EU Water Framework Directive.

Occurrence of cyclophosphamide and ifosfamide in aqueous environment and their removal by biological and abiotic wastewater treatment processes

Cytostatic drug residues in the aqueous environment are of concern due to their possible adverse effects on non-target organisms. Here we report the occurrence and removal efficiency of cyclophosphamide (CP) and ifosfamide (IF) by biological and abiotic treatments including advanced oxidation processes (AOPs). Cyclophosphamide was detected in hospital wastewaters (14-22,000 ng L(-1)), wastewater treatment plant influents (19-27 ng L(-1)) and effluent (17 ng L(-1)), whereas IF was detected only in hospital wastewaters (48-6800 ng L(-1)). The highest removal efficiency during biological treatment (attached growth biomass in a flow through bioreactor) was 59 ± 15% and 35 ± 9.3% for CP and IF, respectively. Also reported are the removal efficiencies of both compounds from wastewater using hydrodynamic cavitation (HC), ozonation (O3) and/or UV, either individually or in combination with hydrogen peroxide (H2O2). Hydrodynamic cavitation did not remove CP and IF to any significant degree. The highest removal efficiencies: 99 ± 0.71% for CP and 94 ± 2.4% for IF, were achieved using UV/O3/H2O2 at 5 g L(-1) for 120 min. When combined with biological treatment, removal efficiencies were >99% for both compounds. This is the first report of combined biological and AOP treatment of CP and IF from wastewater with a removal efficiency >99%.

An Investigation of the Relationship Between Acoustic Emission, Vibration, Noise, and Cavitation Structures on a Kaplan Turbine

The goal of the study was to explain the relationship between different acoustic signals and visual appearance of cavitation. Measurements of acoustic emission, vibration, and noise were performed on a Kaplan turbine model, with only two blades, in a cavitating condition. Since a model with only two blades was used, most of the side effects were eliminated, and it was concluded that the cavitation itself is the source of the recorded signal. Results showed an interesting relationship between the extent of the cavitation and the recorded data from sensors. At a decreasing cavitation number, the recorded amplitudes from all measurements first rose, experienced a local maximum, then fell to a local minimum, and finally rose again. The cavitation was also visually observed. It was concluded from the measurements that there are distinct correlations between acoustic emission, vibration, and noise on one side and the topology, extent, and type of cavitation structures on the other side. A physical explanation for the phenomenon was introduced and included in a semi-empirical model that links the visual appearance of cavitation on the blade of the turbine to the generated noise and vibration.

Prediction of cavitation vortex dynamics in the draft tube of a francis turbine using radial basis neural networks

Application of radial basis neural networks (RBNN) for prediction of cavitation vortex dynamics in a Francis turbine draft tube is presented. The dynamics of the cavitation vortex was established by fluctuations of a void fraction in a selected region of the draft tube. The void fraction was determined by image acquisition and analysis. Pressure in the draft tube and images of the cavitation vortex were acquired simultaneously for the experiment. RBNN were used for prediction. The void fraction in the selected region of the cavitation vortex was predicted on the basis of experimentally provided pressure data. The learning set consisted of pressure – void fraction pairs. The prediction consisted in providing only the pressure. Regression coefficients r between the predicted and measured void fractions were in an interval of 0.82–0.98. A good agreement between power spectra and correlation functions of measured and predicted void fractions was shown.

Energy and Mass Transfer Phenomena in Natural Draft Cooling Towers

In this paper, the development of natural draft cooling towers diagnostics is presented. Diagnostic method is based on measurements of velocity and temperature fields of the airflow in the entire surface area of cooling tower and the raised phenomenological model of heat and mass transfer in a selected reference vertical segment of cooling tower. Velocity and temperature fields of the airflow were measured with the aid of a remote control mobile robot unit that was developed to enable measurements in an arbitrary measurement point above the spray zones over the entire cooling tower area. Topological structures of the humid air velocity profiles and temperature profiles above the spray zones were obtained at constant integral parameters of a power plant. Measurement results of temperature and mass flow characteristics of the air and water flows in a selected reference vertical segment of cooling tower are presented in the form of phenomenological dependence. Phenomenological dependence links local cooling tower efficiency, geometrical characteristics of spray elements, and air and water flow rates. In the concluding part, both methods are applied together on a selected segment of cooling tower, and local and integral cooling tower efficiency can be determined.

Hydraulic Axial Thrust in Multistage Pumps—Origins and Solutions

Axial thrust problems of multistage pumps are presented. The entire investigation has been focused on the pump design concept having all impellers in series (facing in one direction) and is valid for barrel casing type as well as for segmental type. The major part of the investigation has been experimental on one stage testing arrangement, using also Laser Doppler Anemometry (LDA) for determination of fluid rotation in the impeller side chamber. Numerical flow analysis (NFA) has been applied for some flow variants in order to verify whether a numerical approach could simulate the test results. The phenomenon of fluid rotation in side chambers and its effect on impeller hydraulic axial thrust have been determined for different leakage flow regimes. The influence of increased wear ring radial clearance on axial thrust has been analyzed together with the solutions for pump hydraulic axial thrust reduction

Design and testing of an automated system for targeted spraying in orchards

The research aims to demonstrate the basic system elements of a prototype automated orchard sprayer, which can deliver pesticide spray selectively with respect to the characteristics of the targets. The shape of the apple tree canopy was detected by a machine vision system using an RGB camera and appropriate image analysis. Information captured by RGB camera and processed by specific software was fed in real-time to a spraying arm, with three individually controlled sections, which adapt the pesticide spray flow to the canopy shape. The system allows variation in the liquid flow rate and volume of chemicals by means of controlled electric valves, whereby the amount of spray depends on the shape of the tree crowns. The current project focuses on developing the critical elements for spraying an individual tree and evaluates them in independent field experiments with the use of water sensitive papers (WSP). The demonstrated concept of precise application of pesticide sprays supports decreasing of the amount of delivered spray, thereby reducing both costs and environmental pollution.ZusammenfassungDie Untersuchungen sollen grundlegende System-Elemente des Prototyps eines automatisierten Sprühgerätes darstellen, das geeignet ist, Pflanzenschutzmittel gezielt auf Zielobjekte auszubringen. Als Entscheidungs- und Steuerungselement wurde ein „Machine-vision-system” mit RGB-Kamera und nachfolgender Bildanalyse entwickelt und eingesetzt. Die Bildinformationen wurden in Echtzeit genutzt, um die drei verstellbaren Sprüheinheiten individuell hinsichtlich Ausbringmenge entsprechend der Kronenform zu steuern. Das System ermöglicht durch elektromagnetisch gesteuerte Ventile die Ausbringmenge entsprechend der Baumkronenform anzupassen. Das Projekt konzentrirt sich auf die Enwicklung der kritischen Elemente des Sprühgerätes zum Besprühung von einzelne Silhouetten in der Baumreihe. Das vorgestellte Konzept der genauen Anwendung von Pestiziden direkt auf die Baumkronen ist geeignet, die ausgebrachte Produktmenge und damit gleichzeitig auch Kosten und Umweltbelastungen zu reduzieren.