Brian Offerle

Parameterization of Net All-Wave Radiation for Urban Areas

Abstract A simple scheme to estimate net all-wave radiation (Q*) is evaluated using annual datasets in three urban settings (Chicago, Illinois; Los Angeles, California; and Łodź, Poland). Results are compared with a regression model based on incoming solar radiation and with an urban canopy-layer model incorporating a canyon geometry radiation scheme that requires a larger set of meteorological and surface property inputs. This net all-wave radiation parameterization (NARP) is most sensitive to albedo and the effects of clouds on incoming longwave radiation. Although omitting the diurnal variation of albedo has little impact on overall model fit, its seasonal variability needs to be considered in some cases. For incoming longwave radiation, even clear-sky estimates show a large degree of scatter, and results degrade substantially if cloudy periods are included. NARP shows improvement over the regression approach. If observations of downwelling longwave radiation are included, NARP and the more complex can...

Intraurban Differences of Surface Energy Fluxes in a Central European City

Abstract Surface properties, such as roughness and vegetation, which vary both within and between urban areas, play a dominant role in determining surface–atmosphere energy exchanges. The turbulent heat flux partitioning is examined within a single urban area through measurements at four locations in Łodź, Poland, during August 2002. The dominant surface cover (land use) at the sites was grass (airport), 1–3-story detached houses with trees (residential), large 2–4-story buildings (industrial), and 3–6-story buildings (downtown). However, vegetation, buildings, and other “impervious” surface coverage vary within some of these sites on the scale of the turbulent flux measurements. Vegetation and building cover for Łodź were determined from remotely sensed data and an existing database. A source-area model was then used to develop a lookup table to estimate surface cover fractions more accurately for individual measurements. Bowen ratios show an inverse relation with increasing vegetation cover both for a s...

Urban modification of the surface energy balance in the West African Sahel : Ouagadougou, Burkina Faso

Abstract Surface–atmosphere energy exchanges in Ouagadougou, Burkina Faso, located in the West African Sahel, were investigated during February 2003. Basic knowledge of the impact of land cover changes on local climate is needed to understand and forecast the impacts of rapid urbanization predicted for the region. Previously collected data showed a large dry season urban heat island (UHI), which dramatically decreased with the onset of the rainy season and corresponding changes to the natural land cover thermal and radiative properties. Observations of local-scale energy balance fluxes were made over a residential district, and building surface temperatures were measured in three separate locations. Net all-wave radiation showed an increase with urbanization owing to the higher albedo, lower heat capacity, and thermal conductivity of the bare dry soil compared to the urbanized surface. The combination of material and geometry resulted in a decrease in albedo toward the urban center. Despite the higher alb...

Local-Scale Urban Meteorological Parameterization Scheme (LUMPS): Longwave Radiation Parameterization and Seasonality-Related Developments

Recent developments to the Local-scale Urban Meteorological Parameterization Scheme (LUMPS), a simple model able to simulate the urban energy balance, are presented. The major development is the coupling of LUMPS to the Net All-Wave Radiation Parameterization (NARP). Other enhancements include that the model now accounts for the changing availability of water at the surface, seasonal variations of active vegetation, and the anthropogenic heat flux, while maintaining the need for only commonly available meteorological observations and basic surface characteristics. The incoming component of the longwave radiation (LY) in NARP is improved through a simple relation derived using cloud cover observations from a ceilometer collected in central London, England. The new LY formulation is evaluated with two independent multiyear �

Venting of Heat and Carbon Dioxide from Urban Canyons at Night

Turbulent fluxes of carbon dioxide and sensible heat were observed in the surface layer of the weakly convective nocturnal boundary layer over the center of the city of Marseille, France, during the Experience sur Sites pour Contraindre les Modeles de Pollution Atmospherique et de Transport d’Emission (ESCOMPTE) field experiment in the summer of 2001. The data reveal intermittent events or bursts in the time series of carbon dioxide (CO2) concentration and air temperature that are superimposed upon the background values. These features relate to intermittent structures in the fluxes of CO2 and sensible heat. In Marseille, CO2 is primarily emitted into the atmosphere at street level from vehicle exhausts. In a similar way, nocturnal sensible heat fluxes are most likely to originate in the deep street canyons that are warmer than adjacent roof surfaces. Wavelet analysis is used to examine the hypothesis that CO2 concentrations can be used as a tracer to identify characteristics of the venting of pollutants and heat from street canyons into the above-roof nocturnal urban boundary layer. Wavelet analysis is shown to be effective in the identification and analysis of significant events and coherent structures within the turbulent time series. Late in the evening, there is a strong correlation between the burst structures observed in the air temperature and CO2 time series. Evidence suggests that the localized increases of temperature and CO2 observed above roof level in the urban boundary layer (UBL) are related to intermittent venting of sensible heat from the warmer urban canopy layer (UCL). However, later in the night, local advection of CO2 in the UBL, combined with reduced traffic emissions in the UCL, limit the value of CO2 as a tracer of convective plumes in the UBL.

Emission measurements of alkenes, alkanes, SO2, and NO2 from stationary sources in Southeast Texas over a 5 year period using SOF and mobile DOAS

A mobile platform for flux measurements of VOCs (alkanes and alkenes), SO2, and NO2 emissions using the Solar Occultation Flux (SOF) method and mobile differential optical absorption spectroscopy (DOAS) was used in four different studies to measure industrial emissions. The studies were carried out in several large conglomerates of oil refineries and petrochemical industries in Southeast and East Texas in 2006, 2009, 2011, and 2012. The measured alkane emissions from the Houston Ship Channel (HSC) have been fairly stable between 2006 and 2011, averaging about 11,500kg/h, while the alkene emissions have shown greater variations. The ethene and propene emissions measured from the HSC were 1511kg/h and 878kg/h, respectively, in 2006, while dropping to roughly 600kg/h for both species in 2009 and 2011. The results were compared to annual inventory emissions, showing that measured VOC emissions were typically 5-15 times higher, while for SO2 and NO2 the ratio was typically 0.5-2. AP-42 emission factors were used to estimate meteorological effects on alkane emissions from tanks, showing that these emissions may have been up to 35-45% higher during the studies than the annual average. A more focused study of alkene emissions from a petrochemical complex in Longview in 2012 identified two upset episodes, and the elevation of the total emissions during the measurement period due to the upsets was estimated to be approximately 20%. Both meteorological and upset effects were small compared to the factor of 5-15, suggesting that VOC emissions are systematically and substantially underestimated in current emission inventories.

Quantitative measurements and modeling of industrial formaldehyde emissions in the Greater Houston area during campaigns in 2009 and 2011

A sensitive Mobile differential optical absorption spectroscopy (DOAS) system with real-time evaluation capability and HCHO detection limit of 3 ppb over 100 m has been developed. The system was operated together with a Solar Occultation Flux system for large-scale vertical flux measurements of HCHO, NO2, SO2, and VOCs in the Houston-Galveston-Brazoria area during two studies, in 2009 (Study of Houston Atmospheric Radical Precursors campaign) and in 2011 (Air Quality Research Program study). Both in 2009 and 2011, HCHO plumes from five separate local sources in Texas City, Mont Belvieu, and Houston Ship Channel (HSC) were repeatedly detected using Mobile DOAS with emissions varying between 6 and 40 kg/h. In many cases significant alkene emissions were detected simultaneously with the HCHO plumes. Furthermore, in 2011 two additional sources were observed in Texas City and in HSC, with 10 kg/h and 31 kg/h HCHO, respectively. A plume chemistry model was applied to 13 cases to investigate whether the detected HCHO was emitted directly from the industries or was produced by photochemical degradation of VOCs. The model results showed that on average 90% of the detected HCHO was of primary origin and the photochemical production contributed more than 10% in only three cases. Based on the repeatability, it is likely that the most significant HCHO sources in the area are included in this study with an overall emission of 120 kg/h. On a regional scale, this emission is small compared to the secondary HCHO formed from oxidation of reactive VOCs emitted from the same industries, estimated to be an order of magnitude higher.