Brice Vincent

Effect of ultrasonication and dispersion stability on the cluster size of alumina nanoscale particles in aqueous solutions

This study deals with the deagglomeration of nanoparticles in low concentration suspensions in water, protic polar solvent for polymers such as poly(vinyl alcohol) (PVA). The influence of the main parameters of ultrasonication such as time, power and irradiation modes (continuous, pulsed) on the cluster size of aluminium oxide nanoparticles 1 mg/ml in aqueous solutions was investigated. Power-law dependence of size reduction on ultrasonic time was observed. The study indicated an optimum power input, i.e. at higher vibration amplitude the break up of nanoparticle clusters was no better and there was a risk of reagglomeration occurring during a long ultrasonication. Under optimal conditions, continuous and pulsed irradiations showed almost the same efficiency of deagglomeration over a given time. This result provides alternative operating conditions for attaining the smallest size of the alumina aggregates in suspension. The influence of stabilization on the cluster size was also studied. Alumina nanoparticles were stabilized by electrostatic forces against reagglomeration without the need for dispersants, and the enhancement of dispersion stability using electrostatic, steric effects had no significant effect on the aggregate size. On the contrary, the adsorption of high molecular weight polyelectrolytes onto the particle surface could lead to reagglomeration due to material bridges between particle surfaces and even flocculation.

Structural and optical properties of rare-earth-doped Y2O3 waveguides grown by pulsed-laser deposition

Crystalline rare-earth-doped yttrium oxide thin films were grown by pulsed-laser deposition (PLD) on SiO2/Si substrates. The structural and morphological features of these films were studied, as a function of the growth conditions (temperature from 200 to 800 °C and oxygen pressure from 10−6 to 0.5 mbar), by using Rutherford backscattering spectroscopy, x-ray diffraction, and atomic force microscopy. The related optical properties were investigated by m-lines spectroscopy at 633 nm and 1.3 μm. The optimal conditions were found to be a temperature and a pressure of 700 °C and 10−6 mbar, respectively. In that case, the Y2O3 films are stoichiometric with controlled erbium and europium rates, and present a well-crystallized, (111) textured cubic phase and a low surface roughness of about 10 A. Moreover, the PLD films show good waveguiding properties with a high refractive index (1.92 at 633 nm), a step-index structure, and low optical losses around 1 dB/cm in the near infrared region, promising for a planar a...

Dispersion of nanoparticles: from organic solvents to polymer solutions.

This work is devoted to a systematic study of nanoparticle dispersion by ultrasonication in different solutions: from organic solvents to polymer solutions. The cluster size of nanoparticles at different concentrations in both organic solvents and polymer solutions were directly characterized by Dynamic Light Scattering to study the effect of solid concentration, surfactant and polymer on the dispersion. It reveals that in stabilized suspensions, the smallest attainable size or aggregate size of nanoparticles is independent of solvent type and solid content over the tested range. Furthermore, nanoparticles in simple solvent and in polymer solutions had the similar evolution of cluster size and almost the same final size, which could be very helpful to optimize the dispersion of nanofillers in polymer solutions and nanocomposites. It is also shown that, with appropriate sonication amplitudes, the dispersion procedure developed for very dilute suspensions could be transferred to higher concentration suspensions or even to polymer suspensions.

Preparation and characterization of P(VDF-TrFE)/Al 2 O 3 nanocomposite

Hybrid nanocomposites based on crystalline nanoparticles dispersed in polymer matrix have been widely studied in the past few years because of the ability of these materials to combine the properties of organic polymer and inorganic nanoparticles. The aim of this work is to tune the mechanical properties of a piezoelectric polymer by adding nanoparticles to the matrix. In this paper, alumina nanoparticles were dispersed in the copolymer P(VDF-TrFE), which exhibits high piezoelectric coefficient after polarization under high electric field without needing stretching during the polarization process. Transmission electron microscopy and scanning electron microscopy demonstrate the high rate of welldispersed nanoparticles with 10% of alumina nanoparticles added to the matrix. Piezoelectric measurements indicate that P(VDF-TrFE) may be filled by up to 10 wt% of alumina while retaining its high piezoelectric properties and increasing its elastic constant by more than 20%, measured by Brillouin spectroscopy. This work opens a wide range of applications using nanoparticles with nonlinear optical, pyroelectric, magnetic, or ferroelectric properties.

Electrospun poly(vinylidene fluoride-trifluoroethylene)/zinc oxide nanocomposite tissue engineering scaffolds with enhanced cell adhesion and blood vessel formation

Piezoelectric materials that generate electrical signals in response to mechanical strain can be used in tissue engineering to stimulate cell proliferation. Poly (vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)), a piezoelectric polymer, is widely used in biomaterial applications. We hypothesized that incorporation of zinc oxide (ZnO )nanoparticles into the P(VDF-TrFE) matrix could promote adhesion, migration, and proliferation of cells, as well as blood vessel formation (angiogenesis). In this study, we fabricated and comprehensively characterized a novel electrospun P(VDF-TrFE)/ZnO nanocomposite tissue engineering scaffold. We analyzed the morphological features of the polymeric matrix by scanning electron microscopy, and utilized Fourier transform infrared spectroscopy, X-ray diffraction, and differential scanning calorimetry to examine changes in the crystalline phases of the copolymer due to addition of the nanoparticles. We detected no or minimal adverse effects of the biomaterials with regard to blood compatibility in vitro, biocompatibility, and cytotoxicity, indicating that P(VDF-TrFE)/ZnO nanocomposite scaffolds are suitable for tissue engineering applications. Interestingly, human mesenchymal stem cells (hMSCs) and human umbilical vein endothelial cells cultured on the nanocomposite scaffolds exhibited higher cell viability, adhesion, and proliferation compared to cells cultured on tissue culture plates or neat P(VDF-TrFE) scaffolds. Nanocomposite scaffolds implanted into rats with or without hMSCs did not elicit immunological responses, as assessed by macroscopic analysis and histology. Importantly, nanocomposite scaffolds promoted angiogenesis, which was increased in scaffolds pre-seeded with hMSCs. Overall, our results highlight the potential of these novel P(VDF-TrFE)/ZnO nanocomposites for use in tissue engineering, due to their biocompatibility and ability to promote cell adhesion and angiogenesis.

Channel waveguides in Ca4GdO(BO3)3 fabricated by He+ implantation for blue-light generation.

Blue light at 405 nm is generated by frequency doubling of a Ti:sapphire tunable laser in He(+)-implanted channel waveguides in gadolinium calcium oxoborate crystal. A conversion efficiency of approximately 2% W(-1) cm(-2) is achieved between TM00 fundamental and TE01 harmonic modes.

Phononic crystals based on LiNbO 3 realized using domain inversion by electron-beam irradiation

We report in this paper about the realization of domain inversion in z-cut lithium niobate by electron beam irradiation in order to perform phononic crystals. The fabrication of these phononic crystals on z-cut LiNbO3, which is, in our case, a periodic repetition of voids and LiNbO3, was achieved by domain inversion followed by wet etching, taking advantage of the large difference in etching rate between z+ and z- faces. A pertinent choice of irradiation conditions such as accelerating voltage, beam current, and charge density was determined and optimized. Two-dimensional structures at the micrometer scale were then realized on z-cut LiNbO3. We demonstrate the achievement of hexagons with diameters between 2 mum and 18 mum, with a very important depth close to 30 mum, which depends on the etching time and the hole size. The obtained structures, which exhibit a filling fraction varying from 1% to 64%, were characterized before etching by polarizing microscope to visualize the inverted domains. After HF etching, scanning electron microscopy was used to observe the obtained phononic structures. Taking into account the obtained filling fraction values and the size of created hexagons, the frequency band gap of these structures is expected at a range of 200 to 350 MHz. As expected in this frequency range, we have proven experimentally the existence of the phononic band gap on z-cut LiNbO3 by combination of a realized phononic crystal with a surface acoustic wave (SAW) device.

Brillouin microscopy on microwave-induced phonons in LiNbO3

High-performance Brillouin microscopy is proposed as a powerful technique to characterize the lobe of microwave-induced acoustic phonons generated by interdigital finger electrodes in a LiNbO3 device. The generation efficiency is compared with the intensity of thermal phonons of the same wave vector and polarization.

Preparation and characterization of P(VDF-TrFE)/Al 2 0 3 nanocomposite

Hybrid nanocomposites based on crystalline nanoparticles dispersed in polymer matrix has been widely studied in the past few years because of the ability of these materials to combine both properties of organic polymer and inorganic nanoparticles. The aim of this work is to tune mechanical properties of piezoelectric polymer by adding nanoparticles to the matrix. In this paper alumina nanoparticles were dispersed in the copolymer P(VDF-TrFE) which exhibits high piezoelectric coefficient after polarization under high electric field without needing stretching during the polarization process‥ Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) demonstrate the high rate of well-dispersed nanoparticles. with ten percent of alumina nanoparticles added in the matrix. Piezoelectric measurements indicate that P(VDF-TrFE) may be filled up to 10 wt.% of alumina while keeping high piezoelectric properties and increasing of more than 10% the acoustic wave velocity of the material, measured by Brillouin spectroscopy. This work opens a wide range of applications using nanoparticles with nonlinear optical, pyroelectric, magnetic or ferroelectric properties.

Mapping of microwave-induced phonons by μ-Brillouin spectroscopy: hypersons in ZnO on silicon

High performance Brillouin microscopy has been used as a versatile method in order to characterize the spatial distribution of piezoelectrically induced acoustic fields excited at microwave frequencies in a ZnO film deposited on silicon. Filtering properties and acoustic field distribution emitted by inter-digital transducers as well as propagation losses are investigated by μ-Brillouin spectroscopy. It turns out that the acoustic field intensity decreases dramatically outside the immediate excitation area situated below the inter-digital finger structure.