Bruno Bousquet

Silver clusters embedded in glass as a perennial high capacity optical recording medium.

[∗] Dr. A. Royon , Dr. M. Bellec , G. Papon , Dr. B. Bousquet , Prof. L. Canioni Centre de Physique Moleculaire Optique et Hertzienne University of Bordeaux 351 Cours de la Liberation, 33405 Talence (France) E-mail: l.canioni@cpmoh.u-bordeaux1.fr K. Bourhis , Dr. T. Cardinal Institut de Chimie de la Matiere Condensee de Bordeaux University of Bordeaux 87 Avenue du Docteur Schweitzer, 33608 Pessac (France) Dr. Y. Deshayes Laboratoire de l ′ Integration du Materiau au Systeme University of Bordeaux 351 Cours de la Liberation, 33405 Talence (France)

Three-dimensional optical data storage using third-harmonic generation in silver zinc phosphate glass

We demonstrate the possibility of three-dimensional optical data storage inside a specific zinc phosphate glass containing silver by using third-harmonic generation (THG) imaging. Information is stored inside the glass with femtosecond laser irradiation below the refractive index modification threshold. We use the same laser for THG readout. The capability of storage with this technique is discussed.

Beat the diffraction limit in 3D direct laser writing in photosensitive glass

Three-dimensional (3D) femtosecond laser direct structuring in transparent materials is widely used for photonic applications. However, the structure size is limited by the optical diffraction. Here we report on a direct laser writing technique that produces subwavelength nanostructures independently of the experimental limiting factors. We demonstrate 3D nanostructures of arbitrary patterns with feature sizes down to 80 nm, less than one tenth of the laser processing wavelength. Its ease of implementation for novel nanostructuring, with its accompanying high precision will open new opportunities for the fabrication of nanostructures for plasmonic and photonic devices and for applications in metamaterials.

Polarization errors associated with zero-order achromatic quarter-wave plates in the whole visible spectral range

By a combination of quarter-wave plates made of different birefringent materials it is possible to produce achromatic quarter-wave plates whose degree of achromatism is dependant on the dispersions of birefringence and on the thicknesses of the individual quarter-wave plates. These waveplates are widely used in optical instrumentation and the residual errors associated with these devices can be very important in high resolution spectro-polarimetry measurements. The misalignment of optic axis in a double crystal waveplate is one of the main source of error and leads to elliptical eigenpolarization modes in the retarder and the oscillation of its orientation according to the wavelength. This paper will discuss, first, how the characteristics of a quartz-MgF2 quarter-wave plate is affected by such a misalignment. A correlation with the experiment is then achieved in order to highlight the interest of taking a possible tilt error into consideration when doing polarimetric measurements.

Chemometrics Applied to Quantitative Analysis of Ternary Mixtures by Terahertz Spectroscopy

Chemometrics was applied to qualitative and quantitative analyses of terahertz spectra obtained in transmission mode. A series of mixtures of three pure analytes, namely, citric acid, D-(-)fructose, and α-lactose monohydrate under various concentrations, was prepared as pressed pellets with polyethylene as binder. Then, terahertz absorbance spectra were recorded by terahertz time domain spectroscopy and analyzed. First, principal component analysis allowed one to correctly locate the samples into a ternary diagram. Second, quantitative analysis was achieved by partial least-squares (PLS) regression and artificial neural networks (ANN). The concentrations were predicted with values of relative mean square error lower than 0.9% for the three constituents. As a conclusion, chemometrics was demonstrated to be very efficient for the analysis of the ternary mixtures prepared for this study.

Coherent broadband pulse shaping in the mid infrared

We demonstrate broadband infrared pulse shaping by difference-frequency mixing of two visible phase-locked linearly chirped pulses in GaAs. Control of the temporal profile of the emitted field is achieved through this direct tailoring of the exciting visible intensity. The results are in agreement with a simulation with no adjustable parameter.

In Situ Semi-Quantitative Analysis of Polluted Soils by Laser-Induced Breakdown Spectroscopy (LIBS)

Time-saving, low-cost analyses of soil contamination are required to ensure fast and efficient pollution removal and remedial operations. In this work, laser-induced breakdown spectroscopy (LIBS) has been successfully applied to in situ analyses of polluted soils, providing direct semi-quantitative information about the extent of pollution. A field campaign has been carried out in Brittany (France) on a site presenting high levels of heavy metal concentrations. Results on iron as a major component as well as on lead and copper as minor components are reported. Soil samples were dried and prepared as pressed pellets to minimize the effects of moisture and density on the results. LIBS analyses were performed with a Nd:YAG laser operating at 1064 nm, 60 mJ per 10 ns pulse, at a repetition rate of 10 Hz with a diameter of 500 μm on the sample surface. Good correlations were obtained between the LIBS signals and the values of concentrations deduced from inductively coupled plasma atomic emission spectroscopy (ICP-AES). This result proves that LIBS is an efficient method for optimizing sampling operations. Indeed, “LIBS maps” were established directly on-site, providing valuable assistance in optimizing the selection of the most relevant samples for future expensive and time-consuming laboratory analysis and avoiding useless analyses of very similar samples. Finally, it is emphasized that in situ LIBS is not described here as an alternative quantitative analytical method to the usual laboratory measurements but simply as an efficient time-saving tool to optimize sampling operations and to drastically reduce the number of soil samples to be analyzed, thus reducing costs. The detection limits of 200 ppm for lead and 80 ppm for copper reported here are compatible with the thresholds of toxicity; thus, this in situ LIBS campaign was fully validated for these two elements. Consequently, further experiments are planned to extend this study to other chemical elements and other matrices of soils.

Precise measurements and analysis of linear and nonlinear optical properties of glass materials near 1.5 μm

Abstract We adapted a time resolved Mach–Zehnder interferometric technique using a synchronously pumped optical parametric oscillator to measure accurate and absolute nonlinear χ3 in the IR telecommunications domain. Results have been obtained for various metal oxide glasses. Taking into account measurements done at different wavelengths using the same set-up, dispersion of electronic nonlinearity has been studied. Thermal properties have also been measured and very low absorption coefficients of these materials have been analyzed.

Amplitude and phase measurements of femtosecond pulses shaped by use of spectral hole burning in free-base naphthalocyanine-doped films

We performed pulse-shaping and time-reversal experiments using spectral holography based on persistent spectral hole burning in free-base naphthalocyanine-doped films. We demonstrate that we can control the pulses diffracted from the hologram by shaping and then by characterizing these pulses in both amplitude and phase. A dephasing time of 29 ps (i.e., a homogeneous linewidth of 69 GHz) was measured from a photon-echo experiment in the chemically accumulated regime.

Thomson scattering from laser induced plasma in air

The laser induced plasma in air produced by 6 ns, 532 nm Nd:YAG pulses with 25 mJ energy was studied using the Thomson scattering method and plasma imaging techniques. Plasma images and Thomson scattered spectra were registered at delay times ranging from 150 ns to 1 μs after the breakdown pulses. The electron density and temperature, as determined in the core of the plasma plume, were found to decrease from 7.4 × 1017 cm−3 to about 1.03 × 1017 cm−3 and from 100 900 K to 22 700 K. The highly elevated electron temperatures are the result of plasma heating by the second, probe pulse in the Thomson scattering experiments.