Bruno Wilhelm

Long-term relationships among pesticide applications, mobility, and soil erosion in a vineyard watershed

Significance A record of lake sediment spanning approximately 100 years allowed us to reconstruct the long-term succession of herbicide, fungicide, and insecticide treatments in a vineyard catchment in France. This record of pesticide deposition is consistent with the historical onset and banning of these chemical substances by French and European environmental agencies. We also present evidence of the effects of postemergence herbicides, such as glyphosate, on soil erosion and evidence of the release of banned remnant pesticides, such as dichlorodiphenyltrichloroethane (DDT), that are stored in vineyard soil back into the environment. These results indicate that the sink–source dynamics of pesticides, which are crucial in ecotoxicological risk assessment, should take into account the effects of a changing environment on pesticide storage. Agricultural pesticide use has increased worldwide during the last several decades, but the long-term fate, storage, and transfer dynamics of pesticides in a changing environment are poorly understood. Many pesticides have been progressively banned, but in numerous cases, these molecules are stable and may persist in soils, sediments, and ice. Many studies have addressed the question of their possible remobilization as a result of global change. In this article, we present a retro-observation approach based on lake sediment records to monitor micropollutants and to evaluate the long-term succession and diffuse transfer of herbicides, fungicides, and insecticide treatments in a vineyard catchment in France. The sediment allows for a reliable reconstruction of past pesticide use through time, validated by the historical introduction, use, and banning of these organic and inorganic pesticides in local vineyards. Our results also revealed how changes in these practices affect storage conditions and, consequently, the pesticides transfer dynamics. For example, the use of postemergence herbicides (glyphosate), which induce an increase in soil erosion, led to a release of a banned remnant pesticide (dichlorodiphenyltrichloroethane, DDT), which had been previously stored in vineyard soil, back into the environment. Management strategies of ecotoxicological risk would be well served by recognition of the diversity of compounds stored in various environmental sinks, such as agriculture soil, and their capability to become sources when environmental conditions change.

Sediments of Lake Vens (SW European Alps, France) record large-magnitude earthquake events

We studied sediment cores from Lake Vens (2,327xa0mxa0asl), in the Tinée Valley of the SW Alps, to test the paleoseismic archive potential of the lake sediments in this particularly earthquake-sensitive area. The historical earthquake catalogue shows that moderate to strong earthquakes, with intensities of IX–X, have impacted the Southern Alps during the last millennium. Sedimentological (X-ray images, grain size distribution) and geochemical (major elements and organic matter) analyses show that Lake Vens sediments consist of a terrigenous, silty material (minerals and organic matter) sourced from the watershed and diatom frustules. A combination of X-ray images, grain-size distribution, major elements and magnetic properties shows the presence of six homogenite-type deposits interbedded in the sedimentary background. These sedimentological features are ascribed to sediment reworking and grain sorting caused by earthquake-generated seiches. The presence of microfaults that cross-cut the sediment supports the hypothesis of seismic deposits in this system. A preliminary sediment chronology is provided by 210Pb measurement and AMS 14C ages. According to the chronology, the most recent homogenite events are attributable to damaging historic earthquakes in AD 1887 (Ligure) and 1564 (Roquebillière). Hence, the Lake Vens sediment recorded large-magnitude earthquakes in the region and permits a preliminary estimate of recurrence time for such events of ~400xa0years.

Quantified sensitivity of small lake sediments to record historic earthquakes: Implications for paleoseismology: LAKE SENSITIVITY TO RECORD EARTHQUAKES

Seismic hazard assessment is a critical but challenging issue for modern societies. A key parameter to be estimated is the recurrence interval of damaging earthquakes. This requires the establishment of earthquake records long enough to be relevant, i.e., far longer than historical observations. We study how lake sediments can be used for this purpose and explore conditions that enable lake sediments to record earthquakes. This was achieved (i) through the compilation of eight lake-sediment sequences from the European Alps to reconstruct chronicles of mass movement deposits and (ii) through the comparison of these chronicles with the well-documented earthquake history. This allowed 24 occurrences of mass movements to be identified, of which 21 were most probably triggered by an earthquake. However, the number of earthquake-induced deposits varies between lakes of a same region, suggesting variable thresholds of the lake sequences to record earthquake shaking. These thresholds have been quantified by linking the mass movement occurrences in a single lake to both intensity and distance of the triggering earthquakes. This method offers a quantitative approach to estimate locations and intensities of past earthquake epicenters. Finally, we explored which lake characteristics could explain the various sensitivities. Our results suggest that sedimentation rate should be larger than 0.5u2009mmu2009yr−1 so that a given lake records earthquakes in moderately active seismotectonic regions. We also postulate that an increasing sedimentation rate may imply an increasing sensitivity to earthquake shaking. Hence, further paleoseismological studies should control carefully that no significant change in sedimentation rates occurs within a record, which could falsify the assessment of earthquake recurrence intervals.