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Textile Research Journal | 1976

Shrinkproofing Wool by Means of Polythiols

T. D. Brown; M. Rushforth; T. Shaw; Bryan Dobinson; D. J. R. Massy; Walter Wilson; Kenneth Winterbottom

Several types of polythiol resin were applied to wool fabric from organic solvent or aqueous emulsion and cured at room temperature to give shrink resistance. The most successful polythiols were those containing polyether structures and thiol functionality greater than two. Reaction of one of these polythiols with oxygen gas was demonstrated and is believed to be the means whereby the polythiols cure on the wool surface, forming disulfide crosslinks. Organic and inorganic bases, organic peroxides and hydroperoxides, and heavy metal compounds were effective catalysts. The influence of structural differences in the polythiols on the shrink resistance is discussed.


Archive | 1971

CURABLE MIXTURES OF EPOXIDE RESINS AND POLYMERCAPTANS

Bryan Dobinson; Bernard Peter Stark; E. W. Young


Archive | 1973

Method for bonding surfaces together using a mixture of an epoxide resin, a poly(aminoamide) and blocked isocyanate prepolymer

Christopher Michael Andrews; Bryan Dobinson; Edward W. Garnish; Bernard Peter Stark; Robert G. Wilson


Archive | 1992

Glycidyl ether from alcohol and epichlorohydrin

Christopher Michael Andrews; Bryan Dobinson; William Martin Rolfe; Michael Robert Thoseby


Archive | 1972

MERCAPTOALKANOIC ACID ESTERS OF POLYOXYPOLYOLS

Bryan Dobinson; Bernard Peter Stark; Eric Whichell Young


Archive | 1970

TREATMENT OF KERATINOUS FIBERS AND FABRICS

Thomas Desmond Brown; Bryan Dobinson; Michael Rushforth; Walter Wilson; Kenneth Winterbottom


Archive | 1990

Polyimide-forming compositions

Bryan Dobinson; Mark Richard Dr. Southcott


Archive | 1984

Preparation of N-glycidyl compounds

Bryan Dobinson; Michael Robert Thoseby


Archive | 1970

TREATMENT OF KERATINOUS FIBRES AND FABRICS WITH POLYTHIOLS

Bryan Dobinson; Kenneth Winterbottom


Archive | 1991

Tetra-N-glycedyl compound and its hardenable mixtures

Bryan Dobinson; Michael Robert Thoseby

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