Bulent Ulug

Refraction-type sonic crystal junction diode

Unidirectional sound transmission across a junction of two square sonic crystals with different orientations and lattice constants is numerically investigated. Re-scaling and rotating the wave vectors through refractions across the air-first sonic crystal interface and the junction, respectively, facilitate coupling into the spatial modes of the second crystal. Unidirectional transmission, demonstrated through finite element method simulations, is accomplished between 10.4 kHz and 12.8 kHz. Transmission values to the right and left are greater than 60% and less than 1.0%, respectively, between 11.0 kHz and 12.4 kHz, resulting in a contrast ratio greater than 0.9.

Role of irradiation in the green synthesis of silver nanoparticles mediated by fig (Ficus carica) leaf extract

Biosynthesis of silver nanoparticles in an aqueous mixture of fig (Ficus carica) leaf extract and AgNO3 solution exposed to a set of irradiances at different wavelengths are studied. Nanoparticle formation for irradiances between 6.5 mW/cm(2) and 13.3 mW/cm(2) in the 330-550 nm wavelength range is investigated and the results are compared to those of the nanoparticles synthesized in the dark and under direct sunlight. Ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy and proton nuclear magnetic resonance spectroscopy, along with particle size analysis and transmission electron microscopy are employed for the characterization of samples and extracts. Irradiance is found to have profound influence on the reduction rates. However, size and spherical shape of the nanoparticles are persistent, irrespective of irradiance and wavelength. Irradiance is discussed to influence the particle formation and aggregation rates through the formation of free radicals in the fig extract.

Refraction-based photonic crystal diode

A system composed of air holes in a dielectric host to form two square photonic crystals, with the same orientation and lattice constant but different scatterer radii, making an interface along their body diagonals, is numerically demonstrated to facilitate unidirectional light transmission. Band structure computations are carried out via the plane wave expansion method, whereas finite-difference time-domain simulations are carried out to investigate the transient behavior. Unidirectional light transmission is achieved over two adjacent stop bands along the ΓX direction, which are circumvented in the forward direction by scaling down the wave vector and rotating the surface normal. Contrast ratios as high as 0.9 are attained within the lower stop band.

Polarization-independent waveguiding with annular photonic crystals

A linear waveguide in an annular photonic crystal composed of a square array of annular dielectric rods in air is demonstrated to guide transverse electric and transverse magnetic modes simultaneously. Overlapping of the guided bands in the full band gap of the photonic crystal is shown to be achieved through an appropriate set of geometric parameters. Results of Finite-Difference Time-Domain simulations to demonstrate polarization-independent waveguiding with low loss and wavelength-order confinement are presented. Transmission through a 90 degrees bend is also demonstrated.

Slow sound propagation in a sonic crystal linear waveguide

A linear waveguide along the [11] direction of a triangular sonic crystal, composed of aluminum cylinders in air is shown both experimentally and numerically to facilitate slow sound propagation. Supercell-based calculations through the finite element method reveal a band centered at approximately 16.0 kHz with 255 Hz span, exhibiting linear variation away from band edges, for the lattice constant and cylinder radii of 21.7 mm and 10.0 mm, respectively. The experimental setup is based on monitoring the propagation of a Gaussian-enveloped sinusoidal pulse at 16.0 kHz inside the waveguide. Numerical behavior of the Gaussian pulse is investigated by time-dependent finite-element computations. The experimental and numerical group velocities are found to be 26.7 m/s and 22.6 m/s, respectively. Being congruous with the experimental findings, numerical transient study of the system reveals significant longitudinal compression commensurate with the calculated group index.

Wide-band all-angle acoustic self-collimation by rectangular sonic crystals with elliptical bases

Self-collimation of acoustic waves in the whole angular range of ±90° in the second and third bands of a two-dimensional rectangular sonic crystal with elliptical basis is demonstrated by examining the band structure and equifrequency contours. 70% and 77% of the second and third bands are available for wide-band all-angle self-collimation spanning a bandwidth of approximately 29% and 25% of the central frequencies of the all-angle self-collimation frequency ranges, respectively. Self-collimation of waves over large distances with a small divergence of beam width in the transverse direction is demonstrated through computations based on the finite element method. The second and third bands available for self-collimation are seen to vary linearly in the vast mid-range where a small group velocity dispersion prevents temporal divergence of waves with different frequencies.

Self-collimated slow sound in sonic crystals

Self-collimated slow-sound propagation in a two-dimensional rectangular sonic crystal composed of elliptical scatterers in air is numerically demonstrated. The group velocity at the centre and the edges of the fourth acoustic band is reduced to 45 m s−1 and 30 m s−1, corresponding to 1/8 and 1/12 of the speed of sound in air, respectively. Elimination of omni-directional reflections encountered in linear waveguides and the reduction of group-velocity dispersion at the mid-band frequencies lead to preservation of pulse shape and amplitude upon traversal of the sonic crystal. Wave transmission is increased from approximately −20 to −2.5 dB, with almost an order of magnitude enhancement, via injector layers optimized through a pattern search algorithm. Self-collimating performance of the system is not degraded under oblique incidence, except for pulse broadening due to increased effective source width.

Structure of C60 - Aliphatic Diamine Adducts

Abstract Products based on C60 and aliphatic diamines are synthesized. Results indicate that C60 molecules are partially connected to one another via aliphatic diamines. It is shown that d-spaces of the products can be varied by 50% when the number of C atoms in the aliphatic diamine is varied between 2 and 12. XRD analyses indicate that d-spaces are influenced by the repulsive interactions between C60 molecules.

Guiding airborne sound through surface modes of a two-dimensional phononic crystal

Existence and guiding properties of surface modes bound to the interface between a finite two-dimensional phononic crystal and the host medium are experimentally and numerically demonstrated. Surface modes can be observed on both (1 0) and (1 1) surfaces of a square phononic crystal of steel cylinders in air. Numerical investigations of band properties and simulations of mode excitation are carried out through the finite-element method. Excited by the far field of a speaker, existence of surface modes is investigated by recording the sound field in the vicinity of the respective crystal surfaces. Both surface bands of the square phononic crystal depart from bulk bands and extend into the band gap for sufficiently high filling fractions. While such a surface band can be obtained for considerably smaller scatterer radii for the (1 0) surface, significantly higher radii around 0.49 of the lattice constant are required to obtain propagating surface modes on the (1 1) surface. Persistence of the guided surface mode along the (1 0) surface, where it diminishes in a length scale of the lattice constant in the transverse direction is demonstrated. The modes of the (1 1) surface decay faster into the air in the transverse direction. Guided modes on both surfaces propagate in a beating manner where the beat length can be determined by the wave number of the mode.

Low-concentration liquid sensing by an acoustic Mach–Zehnder interferometer in a two-dimensional phononic crystal

Mach–Zehnder interferometer formed by liquid-filled linear defect waveguides in a two-dimensional phononic crystal is numerically realized for sensing low concentrations of an analyte. The waveguides in the square phononic crystal of void cylinders in steel, as well as their T branches and sharp bends are utilized to construct interferometer arms. Sensing low concentrations of ethanol on the order of 0.1% in a binary mixture with water is achieved by replacing the contents of a number of waveguide core cells on one arm of the interferometer with the analyte. Computations are carried out through the finite-element method in an approach that takes the solid-liquid interaction at the waveguide core cells into account. Band analyses reveal linear variation of the central frequency of the transmission band within a band gap for ethanol concentrations up to 3.0%. Phase difference due to the imbalance of the sample and reference arms of the interferometer also varies linearly with ethanol concentration, leading in turn to a cosine variation of the Fourier component of the temporal interferometer response at the central input-pulse frequency. The induced phase difference in the investigated configuration becomes a and per percent increase of ethanol concentration as calculated from the band-structure and transient data, respectively. This is confirmed by transient finite-element simulations where totally destructive interference occurs for a concentration of approximately 1.5%. The proposed scheme, which can easily be adopted to other binary mixtures, offers a compact implementation requiring small amounts of analyte.