Burcak Ebin

Production and characterization of ZnO nanoparticles and porous particles by ultrasonic spray pyrolysis using a zinc nitrate precursor

ZnO nanoparticles and porous particles were produced by an ultrasonic spray pyrolysis method using a zinc nitrate precursor at various temperatures under air atmosphere. The effects of reaction temperature on the size and morphology of ZnO particles were investigated. The samples were characterized by energy dispersive spectroscopy, X-ray diffraction, transmission electron microscopy, and scanning electron microscopy. ZnO particles were obtained in a hexagonal crystal structure and the crystallite shapes changed from spherical to hexagonal by elevating the reaction temperature. The crystallite size grew by increasing the temperature, in spite of reducing the residence time in the heated zone. ZnO nanoparticles were obtained at the lowest reaction temperature and ZnO porous particles, formed by aggregation of ZnO nanoparticles due to effective sintering, were prepared at higher temperatures. The results showed that the properties of ZnO particles can be controlled by changing the reaction temperature in the ultrasonic spray pyrolysis method.

Production of nanocrystalline silver particles by hydrogen reduction of silver nitrate aerosol droplets

Nanocrystalline silver particles were produced by hydrogen reduction of silver nitrate aerosol droplets formed by high frequency ultrasonic generator. The dependences of the particle size, morphology and crystallite size on the precursor concentration and the reaction temperature were investigated. Ultrasonic spray pyrolysis process was combined with hydrogen reduction to research the effects on the silver particle production. Nanocrystalline silver particles including slight oxide structure were prepared at temperature as low as 200 °C from silver nitrate under hydrogen atmosphere. X-ray diffraction (XRD) studies showed that pure silver particles were obtained above 200 °C reaction temperature. The crystallite sizes of the samples ranged from 29 to 47 nm. The results indicate that the crystallite sizes hardly ever depended on the reaction temperature. Crystallites slightly enlarged by increasing precursor concentration. SEM observations showed that particles were obtained in spherical morphology with particle sizes between

Production and characterization of submicron hematite (α−Fe2O3) particles by ultrasonic spray pyrolysis method

The ultrasonic spray pyrolysis (USP) method has been used to prepare submicron hematite (α−Fe2O3) particles using two different industrial pickling solutions of iron chloride (41 g/L FeCl2 and 54 g/L FeCl3) Particles were obtained by thermal decomposition of generated aerosols from precursor solutions using 1.7 MHz ultrasonic atomizer. Reaction temperature was set up at 800 °C and aerosol droplets were carried into the heated zone by 0.7 L/min air flow rate. X-Ray Diffraction (XRD) studies were used to determine the crystal structure and crystallite size of the particles. Results indicate that patterns correspond to hematite phase with rhombohedral crystal structure (space group: R3c). The crystallite sizes of particles prepared from FeCl2 and FeCl3 solutions that were calculated from Scherrer equation are 59 and 33 nm, respectively. Scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) investigations give detailed information about particle size, morphology and composition. SEM micr...

Reduction and characterizations of iron particles: influence of reduction parameters

Iron particles have some applications as electromagnetic devices in magnetic recording and data storage technology due to their small sizes and high data storage capacity. The devices can be advanced by improving the properties of existing materials according to the production parameters. Thus, the influences of reduction parameters on the properties of iron particles were studied. The iron particles were reduced from superparamagnetic iron oxide nanoparticles by altering reduction parameters under hydrogen atmosphere at high (400xa0°C) temperature. The structural analysis of the films was carried out using the X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM) techniques. The XRD data revealed that the crystal textures changed for the particles reduced at each parameter. And, the crystal structure turns from the cubic spinel structure of magnetite and body centered cubic (bcc) structure of iron to the bcc iron as the reduction time increases from 15 to 240xa0min. Then, the similar structure change can be seen for the samples reduced at increasing hydrogen flow rates. The HRTEM studies revealed that the surface morphology of the films strongly depend on the flow rate. Finally, magnetite peaks weaken and then disappear as the precursor mass decreases to the lowest value. The average crystallite sizes were found to be consistent with changing crystal structure. Furthermore, the magnetic characteristics studied by a vibrating sample magnetometer were observed to be affected by the parameters. Besides, magnetic differences may arise from the variation of crystal structure and crystal sizes caused by individual reduction parameters of reduction time, hydrogen flow rate and precursor mass.

Direct production of nanostructured copper-nickel (Cu-Ni) alloy particles

Copper-Nickel (CuNi) nanostructured alloy particles were produced by Ultrasonic Spray Pyrolysis and Hydrogen Reduction Method (USP-HR) from high purity copper and nickel nitrate aqueous solutions. The effect of the precursor solution in the range of 0.1 and 0.5 mol/L on the morphology and crystallite size of CuNi nanoparticles were investigated under 2 h running time, 700 °C operating temperature and 0.5 L/min H2 flow rate. Particle size, morphology, composition and crystallite structure were characterized by Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and X-Ray Diffraction (XRD). Particle characterization studies show that nanostructured alloy particles have cubic crystal structure and they are in submicron size range with spherical morphology. The crystallite sizes of the particles calculated with Scherrer formula are 40 and 34 nm and average particles sizes observed from the SEM images are 300 and 510 nm for each experiment respectively.