C. A. Leatherdale

Electronic transport in films of colloidal CdSe nanocrystals

We present results for electronic transport measurements on large three-dimensional arrays of CdSe nanocrystals. In response to a step in the applied voltage, we observe a power-law decay of the current over five orders of magnitude in time. Furthermore, we observe no steady-state dark current for fields up to

Optical gain and lasing in colloidal quantum dots

{10}^{6} \mathrm{V}/\mathrm{c}\mathrm{m}

Quantization of multiparticle auger rates in semiconductor quantum dots

and times as long as

On the Absorption Cross Section of CdSe Nanocrystal Quantum Dots

2\ifmmode\times\else\texttimes\fi{}{10}^{4} \mathrm{s}.

Electron and hole relaxation pathways in semiconductor quantum dots

Although the power-law form of the decay is quite general, there are quantitative variations with temperature, applied field, sample history, and the material parameters of the array. Despite evidence that the charge injected into the film during the measurement causes the decay of current, we find field scaling of the current at all times. The observation of extremely long-lived current transients suggests the importance of long-range Coulomb interactions between charges on different nanocrystals.

Blinking statistics in single semiconductor nanocrystal quantum dots

Summary form only given. Semiconductor quantum dots (QDs) promise the lowest lasing threshold for semiconductor media. Additionally, QDs in the strong confinement regime have an emission wavelength that is a pronounced function of size, adding the advantage of continuous spectral tunability simply by changing the dot radius. Lasing has previously been demonstrated for epitaxially grown III-V QDs. Large lateral dimensions and difficulties in size control limit their spectral tunability using quantum confinement effects. An alternative approach to fabricating QDs is through chemical synthesis which can produce semiconductor nanoparticles (colloidal QDs) with radii from 1 to 6 nm and with size dispersions as small as 5%. Such dots show strong quantum confinement and permit size-controlled spectral tunability over an energy range as wide as 1 eV. The combination of tunable electronic energies and chemical flexibility make colloidal QDs ideal building blocks for the bottom-up assembly of optical device structures, including optical amplifiers and lasers. However, despite more than a decade of effort, lasing in small-size colloidal nanoparticles has not been realized. To determine what hinders lasing action, we performed extensive dynamical studies of radiative and nonradiative processes in CdSe colloidal QDs.