C. Belton

New light from hybrid inorganic-organic emitters

We present the highlights of a research programme on hybrid inorganic?organic light emitters. These devices combine recent developments in III?V nitride technology (including UV emitting micro-arrays and specifically tailored quantum wells) with conjugated polymers to access the entire visible spectrum. Two types of devices are studied, those based on down conversion of the quantum well emission by radiative transfer and those based on non-radiative resonant energy transfer. The spectral and operating characteristics of the devices are described in detail. Selectable colour micro-arrays and bar emitters are demonstrated. The nature of the non-radiative energy transfer process has also been studied and we find transfer efficiencies of up to 43% at 15?K, with a 1/R2 dependence on the distance between quantum well and polymer layer, suggesting a plane?plane interaction. The relative importance of the non-radiative resonant energy transfer process increases with temperature to be up to 20 times more efficient, at 300?K, than the radiative transfer process.

Well‐Defined and Monodisperse Linear and Star‐Shaped Quaterfluorene‐DPP Molecules: the Significance of Conjugation and Dimensionality

The synthesis of three new 1,4-diketo-3,6-diphenyl-pyrrolo[3,4-c]pyrrole (DPP) macromolecules appended with two or four quaterfluorene arms is reported. The compounds absorb mainly through the oligofluorene units and emit through the DPP core. Optical gain has been observed for Linear-c, a two-armed structure in which the quaterfluorene units are conjugated through the core unit.

White light emission via cascade Förster energy transfer in (Ga, In)N quantum well/polymer blend hybrid structures.

We have studied the room-temperature non-radiative energy transfer processes in hybrid structures composed of (Ga, In)N/GaN single quantum wells and semiconducting polymer blend films placed in nanometre-scale proximity. The blends consist of three polyfluorene materials with concentrations adjusted so that they emit white light. Power-dependent photoluminescence (PL) measurements are used to investigate the process of energy transfer from the quantum wells to the different components of the polymer blend. We show that energy distribution among the hybrid structures involves competition between nanoscale range non-radiative energy transfer processes from the inorganic well to the polymer components and within the blend itself.

Dip-pen patterning of poly(9,9-dioctylfluorene) chain-conformation-based nano-photonic elements

Metamaterials are a promising new class of materials, in which sub-wavelength physical structures, rather than variations in chemical composition, can be used to modify the nature of their interaction with electromagnetic radiation. Here we show that a metamaterials approach, using a discrete physical geometry (conformation) of the segments of a polymer chain as the vector for a substantial refractive index change, can be used to enable visible wavelength, conjugated polymer photonic elements. In particular, we demonstrate that a novel form of dip-pen nanolithography provides an effective means to pattern the so-called β-phase conformation in poly(9,9-dioctylfluorene) thin films. This can be done on length scales ≤500 nm, as required to fabricate a variety of such elements, two of which are theoretically modelled using complex photonic dispersion calculations.

Hybrid inorganic/organic microstructured light-emitting diodes produced using photocurable polymer blends

Light-emitting diodes (LEDs) in the form of a one-dimensional array of microstripes emitting at 370nm were fabricated from AlInGaN inorganic semiconductor. These microlight sources were then used to “directly write” microstructures in photocurable blends of organic light-emitting polymers (LEPs) spin coated onto the LED surface. In this way, thin microstripes of LEP as narrow as 50μm have been fabricated and integrated with the micro-LEDs. These “self-aligned” polymer microstripes serve as wavelength downconverters under further excitation by the UV micro-LEDs, producing hybrid inorganic/organic microstructured LEDs.

Patterning and integration of polyfluorene polymers on micro-pixellated uV alInGaN light-emitting diodes

The integration of polyfluorene polymer micro-pixels onto GaN-based micropixellated UV Light Emitting Diodes is demonstrated. Polymer down-converted visible emission from these hybrid organic/inorganic electroluminescent micro-arrays is achieved.

Efficient Forster transfer mediated by excitons in InGaN/GaN quantum well/polyfluorene heterostructures

We report on novel InGaN/GaN quantum well/polyfluorene heterostructures where efficient Forster energy transfer from the well to the organic layer occurs. We show that Mott‐Wannier excitons dominate the quantum well luminescence in the quantum wells in the 77 to at least 225 K range and are responsible for the efficient energy channeling to the polyfluorene films.