C.L. Sones

Photodarkening in Yb-doped aluminosilicate fibers induced by 488 nm irradiation

Photodarkening of Yb-doped aluminosilicate fibers by continuous wave 488 nm irradiation was investigated. The irradiation induced significant excess loss in the UV-visible spectroscopy (VIS) region in Yb-doped aluminosilicate fibers while pure aluminosilicate fibers showed negligible induced loss. Ultraviolet-VIS-near infrared spectroscopy revealed an absorption peak at 220 nm in unexposed Yb-doped aluminosilicate fiber preforms. The observed peak was attributed to Yb-associated oxygen deficiency centers (ODCs) and proposed as a precursor of the photodarkening. The proposed model was supported by measurements on oxygen loaded Yb-doped aluminosilicate fibers. In these, the photodarkening could be significantly reduced, which we attribute to a smaller number of ODCs following oxygen loading.

Surface domain engineering in congruent lithium niobate single crystals: A route to submicron periodic poling

We describe a technique for surface domain engineering in congruent lithium niobate single crystals. The method is based on conventional electric-field poling, but involves an intentional overpoling step that inverts all the material apart from a thin surface region directly below the patterned photoresist. The surface poled structures show good domain uniformity, and the technique has so far been applied to produce domain periods as small as ∼1 μm. The technique is fully compatible with nonlinear optical integrated devices based on waveguide structures.

Nanoscale surface domain formation on the +z face of lithium niobate by pulsed ultraviolet laser illumination

Single-crystal congruent lithium niobate samples have been illuminated on the +z crystal face by pulsed ultraviolet laser wavelengths below (248 nm) and around (298-329 nm) the absorption edge. Following exposure, etching with hydrofluoric acid reveals highly regular precise domain-like features of widths ~150-300 nm, exhibiting distinct three-fold symmetry. Examination of illuminated unetched areas by scanning force microscopy shows a corresponding contrast in piezoelectric response. These observations indicate the formation of nanoscale ferroelectric surface domains, whose depth has been measured via focused ion beam milling to be ~2 micron. We envisage this direct optical poling technique as a viable route to precision domain-engineered structures for waveguide and other surface applications.

Precision nanoscale domain engineering of lithium niobate via UV laser induced inhibition of poling

Continuous wave ultraviolet (UV) laser irradiation at lambda=244 nm on the +z face of undoped and MgO doped congruent lithium niobate single crystals has been observed to inhibit ferroelectric domain inversion. The inhibition occurs directly beneath the illuminated regions, in a depth greater than 100 nm during subsequent electric field poling of the crystal. Domain inhibition was confirmed by both differential domain etching and piezoresponse force microscopy. This effect allows the formation of arbitrarily shaped domains in lithium niobate and forms the basis of a high spatial resolution micro-structuring approach when followed by chemical etching.

Light-induced order-of-magnitude decrease in the electric field for domain nucleation in MgO-doped lithium niobate crystals

We report an order-of-magnitude reduction in the electric field required for domain nucleation in 1 mol % MgO-doped near-stoichiometric and 5 mol % MgO-doped congruently grown lithium niobate crystals induced by illumination from a focused continuous wave laser beam at wavelengths of 514, 488, and 457 nm. A smaller decrease of 31% is also observed for undoped congruently grown crystals. The effect is independent of the visible wavelengths explored. Light-controlled domain patterning is also demonstrated.

First-order quasi-phase-matched blue light generation in surface-poled Ti-indiffused lithium niobate waveguides

We demonstrate efficient first-order quasi-phase-matched second-harmonic generation in a surface periodically poled Ti:indiffused lithium niobate waveguide; 6 mW of continuous-wave blue radiation (=412.6 nm) was produced showing the potential of surface domain inversion for efficient nonlinear waveguide interactions.

Direct-writing of inverted domains in lithium niobate using a continuous wave ultra violet laser

The inversion of ferroelectric domains in lithium niobate by a scanning focused ultra-violet laser beam (lambda = 244 nm) is demonstrated. The resulting domain patterns are interrogated using piezoresponse force microscopy and by chemical etching in hydrofluoric acid. Direct ultra-violet laser poling was observed in un-doped congruent, iron doped congruent and titanium in-diffused congruent lithium niobate single crystals. A model is proposed to explain the mechanism of domain inversion.

Fabrication of piezoelectric micro-cantilevers in domain-engineered LiNbO3 single crystals

We report on a novel route for fabrication of micro-cantilevers in ferroelectric single-crystal lithium niobate (LiNbO3). Using the sequential techniques of photolithographic patterning, electric field poling, direct bonding and domain-oriented differential etching, free-standing cantilevers of dimensions 50 μm × 50 μm × 5 mm in the x, z and y crystallographic directions, respectively, have been fabricated.

Determination of Refractive Indices From the Mode Profiles of UV-Written Channel Waveguides in

We report on a method for the simultaneous determination of refractive index profiles and mode indices from the measured near-field intensity profiles of optical waveguides. This method has been applied to UV-written single-mode optical waveguides in LiNbO3 for the optimization of the writing conditions. The results for the waveguides written with light of the wavelengths 275, 300.3, 302, and 305 nm for different writing powers and scan speeds reveal that for optimum writing conditions a maximum possible refractive index change of ~0.0026 can be achieved at a value of 632.8 nm transmitting wavelength. The computation process used in the presented technique may also become useful to extract absolute refractive index values of any slowly varying graded index waveguide.

{\hbox {LiNbO}}_{3}

Given that a ferroelectric domain is generally a three dimensional entity, the determination of its area as well as its depth is mandatory for full characterization. Piezoresponse force microscopy (PFM) is known for its ability to map the lateral dimensions of ferroelectric domains with high accuracy. However, no depth profile information has been readily available so far. Here, we have used ferroelectric domains of known depth profile to determine the dependence of the PFM response on the depth of the domain, and thus effectively the depth resolution of PFM detection.