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Featured researches published by C. R. Bock.


Chemical Physics Letters | 1979

Application of electron-transfer theory to excited-state redox processes

C. R. Bock; Joseph A. Connor; Adolpho R. Gutierrez; Thomas J. Meyer; David G. Whitten; B. Patrick Sullivan; Jeffrey K. Nagle

Abstract Quenching rate constants have been obtained for oxidative electron transfer quenching of Ru(bpy) 2++ 3 by a series of nitroaromatic and bipyridinium quenchers and reductive quenching by a series of aromatic amines. The results are consistent with electron-transfer theory when competing processes which occur following the electron-transfer quenching step are taken into account. The competing processes are back-electron-transfer to give the excited state Ru(bpy) 2++ 3 and net quenching by the sum of redox-product-separation and back-electron-transfer to give Ru(bpy) 2++ 3


Journal of the American Chemical Society | 1979

Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes

C. R. Bock; J. A. Connor; A. R. Gutierrez; Thomas J. Meyer; David G. Whitten; B. P. Sullivan; Jeffrey K. Nagle


Journal of the American Chemical Society | 1974

Electron transfer quenching of the luminescent excited state of tris(2,2′-bipyridine)ruthenium(II). A flash photolysis relaxation technique for measuring the rates of very rapid electron transfer reactions [29]

C. R. Bock; Thomas J. Meyer; David G. Whitten


Journal of the American Chemical Society | 1975

Photochemistry of transition metal complexes. The mechanism and efficiency of energy conversion by electron-transfer quenching [8]

C. R. Bock; Thomas J. Meyer; David G. Whitten


Journal of the American Chemical Society | 1975

Flash photolysis evidence for metal-metal bond cleavage and loss of carbon monoxide in the photochemistry of bis[(.eta.5-cyclopentadienyl)tricarbonylmolybdenum]

Joseph L. Hughey; C. R. Bock; Thomas J. Meyer


Journal of the American Chemical Society | 1973

Photoreactions of transition metal complexes. Ligand reactivity as a probe for excited-state characterization

Phoebe P. Zarnegar; C. R. Bock; David G. Whitten


ChemInform | 1973

PHOTOREACTIONS OF TRANSITION METAL COMPLEXES, LIGAND REACTIVITY AS A PROBE FOR EXCITED-STATE CHARACTERIZATION

Phoebe P. Zarnegar; C. R. Bock; David G. Whitten


ChemInform | 1974

ELECTRON TRANSFER QUENCHING OF THE LUMINESCENT EXCITED STATE OF TRIS (2,2′-BIPYRIDINE)RUTHENIUM(II), A FLASH PHOTOLYSIS RELAXATION TECHNIQUE FOR MEASURING THE RATES OF VERY RAPID ELECTRON TRANSFER REACTIONS

C. R. Bock; Thomas J. Meyer; David G. Whitten


ChemInform | 1979

ESTIMATION OF EXCITED-STATE REDOX POTENTIALS BY ELECTRON-TRANSFER QUENCHING. APPLICATION OF ELECTRON-TRANSFER THEORY TO EXCITED-STATE REDOX PROCESSES

C. R. Bock; J. A. Connor; A. R. Gutierrez; Thomas J. Meyer; David G. Whitten; B. P. Sullivan; Jeffrey K. Nagle


ChemInform | 1975

PHOTOCHEMISTRY OF TRANSITION METAL COMPLEXES. THE MECHANISM AND EFFICIENCY OF ENERGY CONVERSION BY ELECTRON-TRANSFER QUENCHING

C. R. Bock; Thomas J. Meyer; David G. Whitten

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Thomas J. Meyer

University of North Carolina at Chapel Hill

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A. R. Gutierrez

University of North Carolina at Chapel Hill

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B. P. Sullivan

University of North Carolina at Chapel Hill

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J. A. Connor

University of North Carolina at Chapel Hill

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Joseph L. Hughey

University of North Carolina at Chapel Hill

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Adolpho R. Gutierrez

University of North Carolina at Chapel Hill

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Joseph A. Connor

University of North Carolina at Chapel Hill

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