C. Taltavull

Influence of the chloride ion concentration on the corrosion of high-purity Mg, ZE41 and AZ91 in buffered Hank's solution

This research studied the influence of the chloride ion concentration on the corrosion behaviour of high-purity magnesium (Mg) and two Mg alloys in Hank’s solution, using hydrogen evolution and weight loss. A buffer based on CO2 and NaHCO3 was used to maintain the pH constant. The corrosion behaviour was governed by a partially protective surface film, and film breakdown by the chloride ions. The carbonated calcium phosphate layer that formed in Hank’s solution was important in determining the protective properties of the surface film.

Characterization of the Corrosion Behavior of a Mg Alloy in Chloride Solution

The influence of the microconstituent phases in the first stages of the corrosion process of the AZ91D Mg-Al alloy in a 3.5 wt% sodium chloride (NaCl) solution was studied at different immersion ti...

Evaluation of failure micromechanisms of advanced thermal spray coatings by in-situ experiment

Identification of failure mechanisms of thermal spray coatings by means of traditional fractography of failed parts is often troublesome. Reason for this is a highly inhomogeneous character of the coating microstructure and harsh in-service conditions which may hinder evidentiary fractographic marks. In this study, failure evolution of advanced thermal barrier coating (TBC) prepared by plasma spraying was studied in-situ at high magnification in a scanning electron microscope under well-defined laboratory conditions of three-point bending (3PB).

Relationship between Laser Parameters - Microstructural Modification - Mechanical Properties of Laser Surface Melted Magnesium Alloy AZ91D

Laser surface melting is a high-energy surface treatment that allows modification of the microstructure and surface properties of Mg alloys. In the present work, a high-power diode laser has been used to study the microstructural and mechanical modifications that occur when laser surface treatments are applied to the surface of the AZ91D Mg alloy. Laser-beam power in a range of 375-600 W and laser scanning speeds of 45-60-90 mms-1 has been used to develop a range of laser surface melting treatments. By controlling the laser parameters, two types of surface modifications can be obtained. Complete laser surface melting takes place at high laser input energies whilst at low laser input energies, selective laser surface melting occurs with modification of only one phase in the microstructure of the alloy; the other phase remained unaffected. In terms of mechanical properties, the microstructural modifications introduced by the laser surface treatment implied a hardness homogenization along the melted region.