C. Vaution

Influence of sodium dodedecylsulphate and of inorganic electrolytes on the micellar solubilization of butobarbitone in aqueous polyoxyethylene lauryl ether solutions at 293.15 k

Abstract The partition coefficient between water and the micellar phase of a barbituric acid, butobarbitone, has been determined in mixed aqueous solutions of two surfactants: sodium dodecylsulphate (SDS) and polyoxyethylene (23) lauryl ether (PEO 23). The partition coefficient of barbitone decreases when mixed micelles are formed. The effective composition of the mixed micelles is calculated from critical micelle concentration data obtained from surface-tension measurements, using the model of regular solutions. It is shown that small quantities of SDS in the mixed micelles have a large effect on the solubilization of butobarbitone; a larger quantity of POE 23 is needed to obtain the same results. This behaviour is interpreted in terms of interaction forces between the three components of the solution at the micellar surface. Inorganic salts such as Na 2 SO 4 and MgSO 4 also decrease the partition coefficient of butobarbitone in POE 23 solutions. In the former case, the variation is a linear function of the mixed electrolyte/POE 23 mole fraction. In the latter case, a larger decrease is observed that is due to the interaction of the divalent ions with oxyethylene groups at the micellar surface.

Characterization of mixed nonionic surfactant micelles by photon correlation spectroscopy and viscosity

Abstract Mixed micelles of the nonionic surfactants Brij 92 and Brij 96 were shown to be large and asymmetric. Using the relationship between the radius of gyration (from total intensity light-scattering dissymmetry measurements) and the hydrodynamic radius (from photon correlation spectroscopy) the mixed micelles are shown to have a rod-like structure, the length of which increases with temperature and on addition of salt. These rod-like micelles appear to exhibit considerable flexibility which is responsible for their measured viscosities being less than that expected from their asymmetry.