Carl C. Nesbitt

In situ immobilization of heavy metals associated with uranium leach mines by bacterial sulfate reduction

Abstract Laboratory experiments with mixed populations of sulfate-reducing bactreria were shown to mediate the removal of milligrams/liter concentrations of uranium, selenium, arsenic and vanadium from aqueous solution via reduction, precipitation and adsorption. Results of laboratory experiments with active sulfidogenic biomass suggest that injection of sulfate and a source of carbon could enhance anaerobic microbial activity in and around uranium leach mines leading to in situ immobilization contaminating metals.

Flow Injection Analysis of MWC Fly Ash Leaching Characteristics

Abstract A completely mixed batch reactor leaching method utilizing flow injection analysis (the CMBR-FIA method) was developed to study the lead leaching characteristics of municipal waste combustor fly ash. Flow injection analysis (FIA) coupled with atomic absorption spectrophotometry enabled the determination of lead concentrations at one minute intervals. The pH and oxidation-reduction potential of the solution were continuously monitored to characterize the leaching conditions. Automatic titration was used to alter the solution pH to defined endpoints. The CMBR-FIA method offers the ability to immediately observe alterations to the leaching solution, and grants the freedom to study a number of parameters concurrently. The CMBR-FIA method is a rapid and reliable means to investigate leaching characteristics. This paper describes the method and demonstrates its use to monitor the leaching of lead from municipal solid waste combustor fly ash as a function of pH. Soluble lead concentrations are shown to ...

SOIL PARTICLE SIZE ANALYSIS USING X-RAY ABSORPTION

Low strain dynamic shear modulus property is generally used to subclassify soil strata, determine elastic settlements under geotechnical structures, and characterize the dynamic nature of soils. Several methods to interpret the dynamic shear modulus of sands from in situ friction cone test results have been developed. These methods used calibration chamber test data of clean sands. Therefore, these methods are not valid for interpreting the shear modulus of cemented sands. Introduced here is an interpretation method to estimate the shear modulus of cemented sand. Thirty-seven friction cone penetration tests (CPTs) were conducted on artificially cemented sand specimens of relative densities ranging from 45 percent to 85 percent and confining pressures ranging from 100 to 300 kPa in a laboratory stress-straincontrolled calibration chamber. Cementation levels of 1 and 2 percent were used in preparing cemented specimens. Resonant column tests were also conducted on the same sand with identical cementation lev...