Carl Manning
York University
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Journal of The Chemical Society-perkin Transactions 1 | 1977
Michael Bellas; Derek Bryce-Smith; Michael T. Clarke; Andrew Gilbert; Garune Klunkin; Stefan Krestonosich; Carl Manning; S. Wilson
Primary, secondary, and tertiary aliphatic amines undergo photoaddition to benzene via photoexcitation of benzene to the S1 state. Primary amines give products of 1,2-, 1,3-, and 1,4-addition of the N–H bond, although the 1,3-adducts are derived from secondary photoreactions of the 1,2-adducts by way of hexa-1,3,5-triene intermediates. Secondary amines react similarly, but give only 1,2- and 1,4-adducts. The photoadditions of tertiary amines involve an α-C–H bond in the amine and occur 1,4- to the benzene ring, but little addition occurs in the absence of methanol or other proton donors. The mechanisms of these reactions have been investigated, and the findings are discussed : charge-transfer processes and both polar and radical intermediates appear to be involved.
Journal of Organic Chemistry | 1981
Carl Manning; Michael R. McClory; John J. McCullough
Angewandte Chemie | 1974
Jack Y. Wong; Carl Manning; Clifford C. Leznoff
Canadian Journal of Chemistry | 1974
Clifford C. Leznoff; Wolfgang Lilie; Carl Manning
Angewandte Chemie | 1974
Jack Y. Wong; Carl Manning; Clifford C. Leznoff
Canadian Journal of Chemistry | 1975
Carl Manning; Clifford C. Leznoff
ChemInform | 1981
Carl Manning; Michael R. McClory; John J. McCullough
ChemInform | 1979
John J. McCullough; Carl Manning
ChemInform | 1978
M. Bellas; Derek Bryce-Smith; M. T. Clarke; Andrew Gilbert; G. Klunkin; S. Krestonosich; Carl Manning; S. Wilson
ChemInform | 1975
Carl Manning; Clifford C. Leznoff