Carlos Henrique de Brito Cruz

Spectral narrowing in the propagation of chirped pulses in single-mode fibers.

A theoretical study of the nonlinear propagation of picosecond chirped pulses in single-mode fibers is presented. We show that, under appropriate conditions, spectral narrowing-rather than broadening, as is generally believed-is induced, owing to the interplay of self-phase-modulation and dispersion. For downchirped pulses at a wavelength of 0.9 microm and a peak power as low as 0.1 W, substantial spectral narrowing occurs.

Two-photon absorption in CdTe quantum dots

We report measurements of frequency degenerate and nondegenerate two-photon absorption (2PA) spectra of CdTe quantum dots, QDs, in glass matrices and compare them with 2PA in bulk CdTe. We find that the 2PA is strongly dependent on the size of the QDs becoming smaller with decreasing size, even when normalizing to the volume of the dots. We adapt a simple degenerate 2PA model, based on the effective mass approximation, to nondegenerate 2PA, and this model correctly describes the experimental data for 2-photon energies up to ~ 1.4Eg. This suggests that, once the spectrum for one size of quantum dot is known, the model can be used for predicting the degenerate and nondegenerate 2PA spectra of different sized QDs of the same semiconductor.

Towards practical liquid and gas sensing with photonic crystal fibres: side access to the fibre microstructure and single-mode liquid-core fibre

Photonic crystal fibres (PCFs) have important applications in sensing the optical properties of fluids. To this end, the material should be inserted into the fibre holes in order to interact with the propagating field. When dealing with liquids, it is particularly interesting to exclusively insert the sample into the core of a hollow-core PCF, which then guides light through the liquid via total internal reflection. Nevertheless, there is still a series of issues to be addressed before fluid sensing with PCFs becomes practical. The work described here proposes and demonstrates possible solutions for two of these issues: (a) how to insert the sample through a lateral access to the fibre longitudinal holes so that the fibre tips are free for optical handling and accessing and (b) in the case of a liquid-core PCF, how to reduce the number of propagating modes.

Analytical results for a Bessel function times Legendre polynomials class integrals

When treating problems of vector diffraction in electromagnetic theory, the evaluation of the integral involving Bessel and associated Legendre functions is necessary. Here we present the analytical result for this integral that will make numerical quadrature techniques or localized approximations unnecessary. The solution is presented using the properties of the Bessel and associated Legendre functions.

Exact partial wave expansion of optical beams with respect to an arbitrary origin

Using an analytical expression for an integral involving Bessel and Legendre functions, we succeed in obtaining the partial wave decomposition of a general optical beam at an arbitrary location relative to the origin. We also showed that solid angle integration will eliminate the radial dependence of the expansion coefficients. The beam shape coefficients obtained are given by an exact expression in terms of single or double integrals. These integrals can be evaluated numerically on a short time scale. We present the results for the case of a linear-polarized Gaussian beam.

Size effects on the phonon spectra of quantum dots in CdTe‐doped glasses

We studied the confinement effects on the phonon spectra of CdTe quantum dots by means of resonant Raman scattering measurements. The spectra show clearly longitudinal optical phonons, surface phonons and some of their overtone combinations. We show that the scattering due to surface phonons increases as the quantum dot size decreases. The results are obtained by tuning the laser excitation energy to resonance for quantum dots of different sizes inside the broad size distribution in CdTe‐doped glasses.

A global conversation about energy from biomass: the continental conventions of the global sustainable bioenergy project

The global sustainable bioenergy (GSB) project was formed in 2009 with the goal of providing guidance with respect to the feasibility and desirability of sustainable, bioenergy-intensive futures. Stage 1 of this project held conventions with a largely common format on each of the worlds continents, was completed in 2010, and is described in this paper. Attended by over 400 persons, the five continental conventions featured presentations, breakout sessions, and drafting of resolutions that were unanimously passed by attendees. The resolutions highlight the potential of bioenergy to make a large energy supply contribution while honouring other priorities, acknowledge the breadth and complexity of bioenergy applications as well as the need to take a systemic approach, and attest to substantial intra- and inter-continental diversity with respect to needs, opportunities, constraints and current practice relevant to bioenergy. The following interim recommendations based on stage 1 GSB activities are offered: — Realize that it may be more productive, and also more correct, to view the seemingly divergent assessments of bioenergy as answers to two different questions rather than the same question. Viewed in this light, there is considerably more scope for reconciliation than might first be apparent, and it is possible to be informed rather than paralysed by divergent assessments. — Develop established and advanced bioenergy technologies such that each contributes to the others success. That is, support and deploy in the near-term meritorious, established technologies in ways that enhance rather than impede deployment of advanced technologies, and support and deploy advanced technologies in ways that expand rather than contract opportunities for early adopters and investors. — Be clear in formulating policies what mix of objectives are being targeted, measure the results of these policies against these objectives and beware of unintended consequences. — Undertake further exploration of land efficiency levers and visions for multiply-beneficial bioenergy deployment. This should be unconstrained by current practices, since we cannot hope to achieve a sustainable and a secure future by continuing the practices that have led to the unsustainable and insecure present. It should also be approached from a global perspective, based on the best science available, and consider the diverse realities, constraints, needs and opportunities extant in different regions of the world. The future trajectory of the GSB project is also briefly considered.

Efficient Biexciton Interaction in Perovskite Quantum Dots Under Weak and Strong Confinement

Cesium lead halide perovskite quantum dots (PQDs) have emerged as a promising new platform for lighting applications. However, to date, light emitting diodes (LED) based on these materials exhibit limited efficiencies. One hypothesized limiting factor is fast nonradiative multiexciton Auger recombination. Using ultrafast spectroscopic techniques, we investigate multicarrier interaction and recombination mechanisms in cesium lead halide PQDs. By mapping the dependence of the biexciton Auger lifetime and the biexciton binding energy on nanomaterial size and composition, we find unusually strong Coulomb interactions among multiexcitons in PQDs. This results in weakly emissive biexcitons and trions, and accounts for low light emission efficiencies. We observe that, for strong confinement, the biexciton lifetime depends linearly on the PQD volume. This dependence becomes sublinear in the weak confinement regime as the PQD size increases beyond the Bohr radius. We demonstrate that Auger recombination is faster in PQDs compared to CdSe nanoparticles having the same volume, suggesting a stronger Coulombic interaction in the PQDs. We confirm this by demonstrating an increased biexciton binding energy, which reaches a maximum of about 100 meV, fully three times larger than in CdSe quantum dots. The biexciton shift can lead to low-threshold optical gain in these materials. These findings also suggest that materials engineering to reduce Coulombic interaction in cesium lead halide PQDs could improve prospects for high efficiency optoelectronic devices. Core-shell structures, in particular type-II nanostructures, which are known to reduce the bandedge Coulomb interaction in CdSe/CdS, could beneficially be applied to PQDs with the goal of increasing their potential in lighting applications.

International collaborations between research universities: experiences and best practices

The world science scenario has observed, in recent years, an important transformation. With the advent of fairly complete publication databases and the improvement of the Internet a number of world university rankings were created, with a clear bias towards research universities. Also, a new field of scientometrics has been developed, and recent studies have clearly demonstrated that the impact of a publication increases if it is written by authors of more than one country. A general overview of the research collaboration landscape is presented, considering the advantages and problems of international cooperation and the role of research universities. In particular, the case of Ibero-America is explained, with a detailed focus on Brazil. Some interesting practices that have been introduced to improve the degree of internationalization of Brazilian science are shown and discussed.

Single-design-parameter microstructured optical fiber for chromatic dispersion tailoring and evanescent field enhancement

A microstructured optical fiber with a single design parameter is proposed and demonstrated. In such a structure three thin, long glass webs join in the fiber center, forming its core. By changing the web thickness it is possible to tune the zero-dispersion wavelength from approximately 0.7 to >2.0 microm while keeping a tiny core area and single-mode guidance. Supercontinuum generation is shown in a silica fiber with a web thickness of 850 nm. The small core area and the massive hole area also make the structure very attractive for the sensing and study of fluids.