Carol J. Cotterill

A 500 year sediment lake record of anthropogenic and natural inputs to Windermere (English Lake District) using double-spike lead isotopes, radiochronology, and sediment microanalysis

A high-resolution record of pollution is preserved in recent sediments from Windermere, the largest lake in the English Lake District. Data derived from X-ray core scanning (validated against wavelength dispersive X-ray fluorescence), radiochronological techniques ((210)Pb and (137)Cs) and ultrahigh precision, double-spike mass spectrometry for lead isotopes are combined to decipher the anthropogenic inputs to the lake. The sediment record suggests that while most element concentrations have been stable, there has been a significant increase in lead, zinc, and copper concentrations since the 1930s. Lead isotope down-core variations identify three major contributory sources of anthropogenic (industrial) lead, comprising gasoline lead, coal combustion lead (most likely source is coal-fired steam ships), and lead derived from Carboniferous Pb-Zn mineralization (mining activities). Periods of metal workings do not correlate with peaks in heavy metals due to the trapping efficiency of up-system lakes in the catchment. Heavy metal increases could be due to flood-induced metal inwash after the cessation of mining and the weathering of bedrock in the catchment. The combination of sediment analysis techniques used provides new insights into the pollutant depositional history of Windermere and could be similarly applied to other lake systems to determine the timing and scale of anthropogenic inputs.

Lake bed geomorphology and sedimentary processes in glacial lake Windermere, UK

A 1:10,000 map of the geomorphological features and sedimentary processes shaping the landscape is presented for Windermere, the largest lake in the English Lake District. High-resolution multibeam bathymetry and backscatter data, lake bed photography and sediment samples reveal a complex landform record, and have been used to identify nine sub-basins separated by steps, ridges and isolated topographic highs probably related to the retreat of the British and Irish Ice Sheet. Debris flows and anthropogenic features are superimposed on the general bathymetric framework formed since the Last Glacial Maximum. Five distinct lake bed facies are identified through ground-truthing, and are used to describe the sedimentology of the lake revealing a dominance of gyttja. Coarser sediments are found in lake-marginal shallow waters, where the morphology is shaped by dredging scars and circular dredging deposits. Post-glacial slope failure and modern sedimentary processes such as debris flows have further shaped the lake bed and removed the surface drape of gyttja, exposing an underlying facies of Pre-Holocene finely laminated mud.

Alteration Heterogeneities in Peridotites Exhumed on the Southern Wall of the Atlantis Massif (IODP Expedition 357)

Serpentinized and metasomatized peridotites intruded by gabbros and dolerites have been drilled on the southern wall of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) during International Ocean Discovery Program (IODP) Expedition 357. They occur in seven holes from five sites making up an east-west trending, spreading-parallel profile that crosscuts this exhumed detachment footwall. Here we have taken advantage of this sampling to study heterogeneities of alteration at scales less than a kilometer. We combine textural and mineralogical observations made on 77 samples with in situ major and trace element analyses in primary and serpentine minerals to provide a conceptual model for the development of alteration heterogeneities at the Atlantis Massif. Textural sequences and mineralogical assemblages reveal a transition between an initial pervasive phase of serpentinization and subsequent serpentinization and metasomatism focused along localized pathways preferentially used by hydrothermal fluids. We propose that these localized pathways are interconnected and form 100 m- to 1 km-sized cells in the detachment footwall. This change in fluid pathway distribution is accompanied by variable trace element enrichments in the serpentine textures: deep, syn-serpentinization fluid-peridotite interactions are considered the source of Cu, Zn, As, and Sb enrichments, whereas U and Sr enrichments are interpreted as markers of later, shallower fluid-serpentinized peridotite interaction. Alteration of gabbros and dolerites emplaced in the peridotite at different lithospheric levels leads to the development of amphibole, chlorite and, or, talc-bearing textures as well as enrichments in LREE, Nb, Y, Th, Ta in the serpentine textures of the surrounding peridotites. Combining these observations, we propose a model that places the drill holes in a conceptual frame involving mafic intrusions in the peridotites and heterogeneities during progressive alteration and emplacement on the seafloor.

Windermere Multibeam Bathymetry Data

Multibeam Bathymetry Data was collected by the British Geological Survey in September 2010 in association with the University of Southampton in both the north and south basins of Windermere in the English Lake District. Data was analysed by Helen Miller and Jonathan Bull from the University of Southampton as well as Carol Cotterill from the British Geological Survey. The data is freely available for download and it would be appropriate to cite the following reference when using the data: Miller, Helen, Bull, Jonathan M., Cotterill, Carol J., Dix, Justin K., Winfield, Ian J., Kemp, Alan E.S. and Pearce, Richard B. (2013) Lake bed geomorphology and sedimentary processes in glacial lake Windermere, UK. Journal of Maps, 9, (2), 299-312. (doi:10.1080/17445647.2013.780986). The data is not appropriate for navigational use. Further information on the survey is available at: http://www.bgs.ac.uk/research/highlights/2013/lakeWindermere.html A pdf map of the multibeam data is available for download, and the data can be downloaded here at 1 m and 5 m resolutions from the north and south basins of Windermere.

Palaeoseismology from microfabric and geochemical analysis of lacustrine sediments, Windermere, UK

Lake sediments commonly contain detrital layers that record events such as floods or earthquakes, but these may be disturbed or partially destroyed by bioturbation. Here we use a novel combination of techniques to relate microscopic sediment fabric features to processes at the lake basin scale. X-radiography and micro-X-ray fluorescence analysis of cores are complemented by back-scattered electron imagery and energy-dispersive X-ray microanalysis of resin-embedded sediment. Together, the microfabric and geochemical methods enable the identification of clay layer mass transport deposits despite bioturbational mixing of the original end-members. Two cores with robust radionuclide chronologies contain correlative clay layers dated to 1979 (1974–1982) and 1979–1980 (1973–1986), respectively. These clay layers probably represent the distal turbidite generated by a major mass flow deposit identified from multi-beam swath bathymetry and sediment grab sampling. A probable trigger for the mass flow and associated turbidity current is the 4.7 ML 1979 Carlisle earthquake. The lake basin slope was probably preconditioned for failure by increased sedimentary biogenic gas production and sediment in-wash as a result of anthropogenic activities, coupled with sediment disruption and dredging. This study highlights the effectiveness of microstratigraphic techniques in the recognition and characterization of event layers in sediments where bioturbative disruption has occurred.

How understanding past landscapes might inform present-day site investigations: a case study from Dogger Bank, southern central North Sea

The integration of geophysical and geotechnical datasets acquired during a site survey for the Dogger Bank wind farm has enabled a new litho- and seismo-stratigraphy to be established. Although previously believed to be a relatively simple “layer-cake”, the data reveal that the sedimentary sequence within the foundation zone includes a complex series of buried landscapes with implications for both foundation siting and design. The most significant is a Weichselian glacially derived landscape dominated by a large thrust-block moraine complex buried beneath a thin Holocene sequence. This glacial landscape profoundly affects the structure and physical properties of sediments within the foundation zone due to locally intense glaciotectonic deformation and the occurrence of sub-aerially desiccated horizons recording fluctuating palaeo-climatic conditions. Understanding these landscapes, coupled with the geophysical and geotechnical data, enables the development of a predictive “geo-model” that may be used to target areas of uncertainty, reducing the requirement for boreholes (over Cone Penetration Tests) at every potential foundation location.

Modern Pollution Signals in Sediments from Windermere, NW England, Determined by Micro-XRF and Lead Isotope Analysis

High resolution geochemical (Itrax micro-XRF and wavelength dispersive XRF) data, radiochronology (210Pb and 137Cs analyses) and ultra-high precision double-spike lead isotope measurements from lacustrine sediment cores are used in combination with historical research of former mining landscapes to investigate modern pollution signals in sediments from Windermere, the largest lake in the English Lake District. The sediment record suggests that while most element concentrations have been stable, there has been a significant increase since the 1930s in lead, zinc and copper concentrations. Double-spike lead isotope measurements reveal a mixture of natural lead, and three major contributory sources of anthropogenic (industrial) lead, comprising gasoline lead, coal combustion lead (from coal-fired steam ships) and lead derived from Carboniferous Pb–Zn mineralisation (mining activities). A number of up-system sediment traps have limited the amount of mining related heavy metals entering Windermere, and as a result, periods of metal workings do not correlate with peaks in heavy metals. Increases could also be due to flood-induced metal inwash or weathering of bedrock in the catchment. Application of these non-destructive and high precision analytical techniques provides new insights into the pollutant depositional history of Windermere.