Carolin Ulbrich

Rugate filter for light-trapping in solar cells

We suggest a design for a coating that could be applied on top of any solar cell having at least one diffusing surface. This coating acts as an angle and wavelength selective filter, which increases the average path length and absorptance at long wavelengths without altering the solar cell performance at short wavelengths. The filter design is based on a continuous variation of the refractive index in order to minimize undesired reflection losses. Numerical procedures are used to optimize the filter for a 10 microm thick monocrystalline silicon solar cell, which lifts the efficiency above the Auger limit for unconcentrated illumination. The feasibility to fabricate such filters is also discussed, considering a finite available refractive index range.

Enhanced light trapping in thin-film solar cells by a directionally selective filter

A directionally selective multilayer filter is applied to a hydrogenated amorphous silicon solar cell to improve the light trapping. The filter prevents non-absorbed long-wavelength photons from leaving the cell under oblique angles leading to an enhancement of the total optical path length for weakly absorbed light within the device by a factor of kappa(r) = 3.5. Parasitic absorption in the contact layers limits the effective path length improvement for the photovoltaic quantum efficiency to a factor of kappa(EQE) = 1.5. The total short-circuit current density increases by DeltaJ(sc) = 0.2 mAcm(-2) due to the directional selectivity of the Bragg-like filter.

Matching of Silicon Thin-Film Tandem Solar Cells for Maximum Power Output

We present a meaningful characterization method for tandem solar cells. The experimental method allows for optimizing the output power instead of the current. Furthermore, it enables the extraction of the approximate AM1.5g efficiency when working with noncalibrated spectra. Current matching of tandem solar cells under short-circuit condition maximizes the output current but is disadvantageous for the overall fill factor and as a consequence does not imply an optimization of the output power of the device. We apply the matching condition to the maximum power output; that is, a stack of solar cells is power matched if the power output of each subcell is maximal at equal subcell currents. The new measurement procedure uses additional light-emitting diodes as bias light in the characterization of tandem solar cells. Using a characterized reference tandem solar cell, such as a hydrogenated amorphous/microcrystalline silicon tandem, it is possible to extract the AM1.5g efficiency from tandems of the same technology also under noncalibrated spectra.

Advancing tandem solar cells by spectrally selective multilayer intermediate reflectors

Thin-film silicon tandem solar cells are composed of an amorphous silicon top cell and a microcrystalline silicon bottom cell, stacked and connected in series. In order to match the photocurrents of the top cell and the bottom cell, a proper photon management is required. Up to date, single-layer intermediate reflectors of limited spectral selectivity are applied to match the photocurrents of the top and the bottom cell. In this paper, we design and prototype multilayer intermediate reflectors based on aluminum doped zinc oxide and doped microcrystalline silicon oxide with a spectrally selective reflectance allowing for improved current matching and an overall increase of the charge carrier generation. The intermediate reflectors are successfully integrated into state-of-the-art tandem solar cells resulting in an increase of overall short-circuit current density by 0.7 mA/cm(2) in comparison to a tandem solar cell with the standard single-layer intermediate reflector.

Directionally selective light trapping in a germanium solar cell

Restricting the angular range in which a photovoltaic system emits light, is a promising but rather unexplored approach to enhance conversion efficiency. In this paper we analyze and discuss the effect of a directionally selective filter on the absorption of light and the generation of charge carriers in a germanium solar cell. A directionally selective filter transmits photons of perpendicular incidence and reflects photons under oblique incidence in a given spectral range. To investigate its effect on light trapping, we perform reflection and quantum efficiency measurements. The reflection measurements show that a wavelength dependent absorption enhancement is induced by the application of the directionally selective filter. We calculate a maximum absorption enhancement of 45% at λ ≈ 
1900 nm. We show that the absorption enhancement is caused by light trapping of non-absorbed and scattered light and is not due to a suppression of radiative processes. A trapping of photons generated by radiative recombination could not be detected. Measurements of the quantum efficiency confirm the results of the reflection measurements. The generation of charge carriers is increased by up to 33% at λ ≈1900 nm. A comparison of path length enhancement factors calculated from reflection and quantum efficiency measurements indicates a low parasitic absorption in the solar cell device.

Directional selectivity and light-trapping in solar cells

The Yablonovitch limit for light trapping in solar cells with Lambertian surfaces can be increased using angle selective absorbers thereby exploiting the limited incidence angle of solar radiation. We simulate the efficiency gain or loss caused by an angular and energy selective filter on top of the absorber, compared to a Lambertian and a flat absorber. Additionally, we introduce two possible implementations of such a filter, a Rugate stack and inverted opal layers.

Spectrally selective intermediate reflectors for tandem thin-film silicon solar cells

Thin–film silicon tandem solar cells consist of an amorphous silicon top cell and a microcrystalline silicon bottom cell stacked in series. In order to match the photocurrents of the top cell and the bottom cell, a proper photon management is essential. In this regard, we present the conceptual design and optical simulations of an intermediate reflector consisting of a stack of microcrystalline silicon oxide layers of different, alternating refractive indices. In contrast to 1–layer intermediate reflectors, the spectral and directional selectivity of these intermediate reflectors result in a gain for the top cell current while simultaneously increasing the charge carrier generation in the bottom cell.

3D photonic crystals for photon management in solar cells

Summary form only given. Photon management is a key element to optimize the optical and electro-optical performance of solar cells. Photon management concepts and the potential of 3D photonic crystals for photon management in solar cells are discussed.

Degradation of tandem solar cells: Separating matching effects from Staebler-Wronski Effect using the Power-Matching-Method

In thin-film tandem solar cells the sub cells are usually connected in series. The inherent current-limitation needs to be considered when optimizing the efficiency, but furthermore leads to challenges when comparing the sub cells performances of differently matched tandem cells. We have introduced the Power-Matching-Method that characterizes the device not only under one standard spectrum but under various spectral distributions. By this method, the same tandem cell can be characterized under various matching conditions. Based on simulations, we demonstrate a convenient way to compare differently matched tandem solar cells. Moreover, our simulations show that the method allows distinguishing between matching effects and changes in the sub-cells properties, e.g. changes due to the Staebler-Wronski-Effect.

Inverted-opal photonic crystals for ultra light-trapping in solar cells

We investigated a three dimensional inverted opal having the potential to notably increase light-trapping in solar cells. The 3D photonic crystal top layer is an angle- and direction-selective filter, which decreases the acceptance cone of the solar cell. Numerical optimisation methods are used to verify the optical and electrical properties for a large angluar and energy spectrum for a system consisting of an inverted opal on top of a thin crystalline silicon solar cell. It is numerically shown that an inverted opal grown in the Τ - Xdirection might fulfill the requirement for such a filter. An estimate for the theoretically achievable efficiency for nonconcentrated light is presented that do show an enchanced efficiency near the electronic band edge of the absorber. The fabrication of first opals grown in Τ - Xdirection is presented and discussed with respect to the quality and large scale fabrication.