Caroline M. Isaacs

Influence of rock composition on kinetics of silica phase changes in the Monterey Formation, Santa Barbara area, California

The diatomaceous deposits of the Monterey Formation along the Santa Barbara coast were subjected to temperatures and burial depths that increased westward after deposition. As a result, the silica phase in originally similar, laterally equivalent strata generally changed westward from biogenous opal-A to diagenetic opal-CT to diagenetic quartz. In individual beds at the same stratigraphic level, however, silica phases changed at various temperatures, producing a transformation—or kinetic—sequence related to variations in the ratio of silica to detrital minerals. Compared to silica in rocks with minor detrital minerals, in rocks with progressively more abundant detrital minerals: (1) opal-CT formed progressively later, (2) the initial d-spacing of opal-CT was progressively smaller, and (3) quartz formed progressively earlier. Comparison of associated calcareous, dolomitic, and carbonate-free rocks with equal silica/detrital ratios shows that carbonates did not significantly affect rates of silica diagenesis in the vast majority of rocks. In carbonate-bearing rocks with silica/detrital ratios ≥8, however, some (2% to 10%) quartz formed early in diagenesis, probably prior to opal-CT formation. In addition, atypical quartz cherts formed locally in carbonate-bearing strata by pore filling and replacement early in diagenesis, possibly before widespread opal-CT formation.

Minor elements in Quaternary sediment from the Sea of Japan: a record of surface-water productivity and intermediate-water redox conditions

Sediment of Quaternary age from Oki Ridge (903 m depth) in the Sea of Japan (∼3500 m deep) records six episodes of high accumulation rates of Cd, Cr, Cu, Mo, Ni, U, V, and Zn. The high rates correspond to periods of sulfate reduction in the water column at the intermediate depth of Oki Ridge; the intervening low values correspond to periods of denitrification and oxygen respiration. The maxima have a period of 41 k.y., the youngest having an age of 1.10 Ma. The 41 k.y. cycle is similar to the cycle of δ 18 O values of open-ocean plankton of the same age. The similarity between the cycles of minor-element accumulation in Sea of Japan sediment and δ 18 O values of Atlantic Ocean foraminifera indicates that redox changes in the water column of the Sea of Japan during the Quaternary, forced by major shifts in water-column advection and minor shifts in photic-zone productivity, reflect global events.

An evaluation of temperature scales for silica diagenesis in diatomaceous sequences including a new approach based on the Miocene Monterey Formation, California

Geologic relations indicate that silica phases transformed in the Monterey Formation in two zones that persist over a narrow depth/temperature range and do not stratigraphically overlap. The wide and overlapping range of reported temperatures of these transformations is mainly a result of the many uncertainties inherent in the different methods used to estimate temperature and does not indicate that phases transform throughout these ranges. Our approach to a reliable temperature scale for silica diagenesis combines as empirical zonation of silica phases with temperature calibration from a sequence at maximum temperature and depth of burial.

Instability of bottom‐water redox conditions during accumulation of Quaternary sediment in the Japan Sea

The concentrations of Cd, Cr, Cu, Mo, Ni, Sb, U, V, and Zn were measured in early Quaternary sediment (1.32 to 1.08 Ma) from the Oki Ridge in the Japan Sea. The elements were partitioned between a detrital fraction, composed of terrigenous and volcaniclastic aluminosilicate debris, and a marine fraction, composed of biogenic and hydrogenous debris derived from seawater. The most important factors controlling minor-element accumulation rates in the marine fraction were (1) primary productivity in the photic zone, which largely controlled the flux of particulate organic-matter-bound minor elements settling through the water column and onto the seafloor, and (2) bottom-water redox, which determined the suite of elements that accumulated directly from seawater. This marine fraction of minor elements on Oki Ridge recorded six periods of high minor-element abundance. Assuming a constant bulk sediment accumulation rate, each period lasted roughly 5,000 to 10,000 years with a 41,000-year cycle. Accumulation rates of individual elements such as Cd, Mo, and U suggest sulfate-reducing conditions were established in the bottom water during the 10,000-year periods; accumulation rates of Cr and V during the intervening periods are indicative of less reducing, denitrifying conditions. Interelement ratios, for example, Cu:Mo, V:Cr, and Sb:Mo, further reflect bottom-water instability, such that bottom-water redox actually varied from sulfate reducing to denitrifying during the periods of highest minor-element accumulation rates; it varied from denitrifying to oxidizing during the intervening periods. Sediment lithology supports these interpretations of the minor-element distributions; the sediment is finely laminated for several of the periods represented by Cd, Mo, and U maxima and weakly laminated to bioturbated for the intervening periods. The geochemistry of this sediment demonstrates the unambiguous signal of Mo, principally, but of several other minor elements as well in recording sulfate-reducing conditions in bottom water. The forcing function that altered their accumulation, that is, that altered primary productivity and bottom water redox conditions, is problematic. Currently held opinion suggests that O2 depletion was most strongly developed during glacial advances. Low sea level during such times is interpreted to have enhanced primary productivity and restricted bottom-water advection.

Abundance versus rates of accumulation in fine-grained strata of the Miocene Santa Barbara basin, California

Although best known as a deposit rich in silica and organic matter, the Miocene Monterey Formation actually had long-term rates of silica and organic Matter accumulation equal to or lower than values in the underlying and overlying detritus-rich formations in the Santa Barbara coastal area. The factor Mainly influencing the composition of the Monterey Formation in this area was the slow accumulation of terrigenous debris. In contrast, with greater than average silica abundance within the Monterey Formation probably resulted from rapid short-term silica accumulation (of hundreds to tens of thousands years duration) rather than from especially slow accumulation of diluting debris.